Tetrahydrothiophene tris(pentafluorophenyl)borane
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In the title compound, (C4H8S)B(C6F5)3, a comparatively long boron–sulfur distance of 2.0843 (16) A is found, most probably due to the sterically demanding pentafluorophenylsubstituents. Bond distances and angles of the boron–aryl fragment are comparable to those found for uncoordinated MeB(C6F5)3− anions.