Electrochemical slurry jet micro-machining of tungsten carbide with a sodium chloride solution

Abstract Electrochemical slurry jet micro-machining (ESJM) is a new non-conventional process that couples abrasive slurry jet machining (ASJM) and electrochemical jet machining (ECJM) concurrently. A micro-jet of abrasive particles and electrolytic solution is made to impinge on the target while applying a DC potential between the jet nozzle and the workpiece. ESJM can be used to remove material that is difficult to machine through a combination of erosion, corrosion and synergistic effects. This study focuses on ESJM of tungsten carbide (WC) using a pH-neutral NaCl electrolyte rather than an alkaline solution which is more commonly used in the electrochemical processing of WC. For the studied process parameters, it was shown that the erosion due to ASJM alone was not able to erode the WC, and that the corrosion under ECJM was slow and produced unacceptably wide channels. The combined ESJM process however, was found to involve erosion of the developed oxide layer and subsequent exposure of un-corroded WC, leading to a much higher machining current density, corrosion rate, and machining localization than using ECJM alone. It was also found that the total abrasive kinetic energy, working voltage and solution concentration strongly affected the machining current density, material removal rate and aspect ratio (depth to width ratio). The results indicate that ESJM has a high potential to machine difficult-to-cut metals efficiently and economically.

[1]  B. Schnyder,et al.  Investigation of the electrochemical behaviour of WC–Co hardmetal with electrochemical and surface analytical methods , 2004 .

[2]  A. Neville,et al.  Electrochemical assessment of erosion-corrosion of commercially pure titanium and a titanium alloy in slurry impingement , 2002 .

[3]  Mohan Sen,et al.  Analysis of hole quality characteristics in the electro jet drilling process , 2005 .

[4]  C. Allen,et al.  The erosion-corrosion resistance of tungsten-carbide hard metals , 1997 .

[5]  Abishek B. Kamaraj,et al.  Pulse Electrochemical Micromachining of Tungsten Carbide , 2012 .

[6]  J. K. Spelt,et al.  The solid particle erosion of 12 metals using magnetite erodent , 2012 .

[7]  R. Wood,et al.  Solid particle erosion–corrosion behaviour of a novel HVOF nickel aluminium bronze coating for marine applications—correlation between mass loss and electrochemical measurements , 2005 .

[8]  Mahmudur Rahman,et al.  A review on the conventional and micro-electrodischarge machining of tungsten carbide , 2011 .

[9]  Robert J.K. Wood,et al.  Erosion–corrosion interactions and their effect on marine and offshore materials , 2006 .

[10]  Andreas Schubert,et al.  Microstructuring of carbide metals applying Jet Electrochemical Machining , 2013 .

[11]  J. Bannard The use of surface-active additives in electrochemical machining electrolytes , 1974 .

[12]  Pradyot Patnaik,et al.  A comprehensive guide to the hazardous properties of chemical substances , 2007 .

[13]  M. Lohrengel,et al.  Electrochemical machining of hard metals – WC/Co as example , 2014 .

[14]  Jan K. Spelt,et al.  Abrasive enhanced electrochemical slurry jet micro-machining: Comparative experiments and synergistic effects , 2014 .

[15]  J. K. Spelt,et al.  Surface roughness and erosion rate of abrasive jet micro-machined channels: Experiments and analytical model , 2013 .

[16]  J. K. Spelt,et al.  Surface evolution models for abrasive slurry jet micro-machining of channels and holes in glass , 2014 .

[17]  F. Harnisch,et al.  Electrocatalytic and corrosion behaviour of tungsten carbide in near-neutral pH electrolytes , 2009 .

[18]  Takahisa Masuzawa,et al.  Electrochemical surface finishing of tungsten carbide alloy , 1991 .

[19]  Masanori Kunieda,et al.  Research on generation of three-dimensional surface with micro-electrolyte jet machining , 2008 .

[20]  Jan K. Spelt,et al.  Characteristics of abrasive slurry jet micro-machining: A comparison with abrasive air jet micro-machining , 2013 .

[21]  I. Hussainova Some aspects of solid particle erosion of cermets , 2001 .

[22]  Kamlakar P Rajurkar,et al.  Study of Electrochemical Jet Machining Process , 1996 .

[23]  R. Rateick,et al.  Solid-particle erosion of tungsten carbide/cobalt cermet and hardened 440C stainless steel—A comparison , 2006 .