论文信息 - catena-Poly[[{2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}cadmium(II)]-di-μ2-chlorido-[dimethanolcadmium(II)]-di-μ2-chlorido-[{2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}cadmium(II)]-di-μ2-chlorido]

catena-Poly[[{2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}cadmium(II)]-di-μ2-chlorido-[dimethanolcadmium(II)]-di-μ2-chlorido-[{2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}cadmium(II)]-di-μ2-chlorido]

The structure of the title compound, [Cd3Cl6(C15H15NO2)2(CH4O)2]n, is based on a layered zigzag polymeric chain along the c axis. The CdII ions are linked by double chlorine bridges alternating between one CdCl4(CH3OH)2 and two CdCl4(C15H15NO2) octahedral coordination units. Additional intrachain N—H⋯O and O—H⋯Cl hydrogen-bond interactions stabilize this arrangement.

Guo-Liang Zhao | Hui-Duo Xian | Hua-Qiong Li | Jian-Feng Liu

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