The coal-bearing, Cenozoic As Pontes basin (northwestern Spain) : geological influence on coal characteristics

Lignite deposits in the Cenozoic As Pontes strike-slip basin (northwestern Spain) were formed as a function of specific paleoclimatic conditions and tectonic evolution of the basin. During the early evolutionary stages, the presence of active normal faults and thrusts inside the basin resulted in two subbasins with distinct differences in sedimentary records, with respect to lignite seam occurrence, thickness, area1 extent and lithotype development. In contrast, during the late evolutionary stages the basin was not split and a more homogeneous sedimentary record in terms of coal seam occurrence and lithotype characteristics developed. A total of 26 lignite samples, distributed along the basin infill, were analyzed by organic petrography and geochemistry. All are lignite B (ASTM). The lignites deposited during lower basin infill sedimentation (units 1 and 2) are dark, matrix-rich, mainly huminitic brown coals, with minor bright, liptinitic-rich coal lithotypes. The dark huminitic coals in these units show sedimentological and paleontological evidence of lacustrine influence. Persistent, relatively moderate to low Tissue Preservation Index (TPI) values and high average Gelification Index (GI) values are characteristic of these limno-telmatic coals. Lignites in the upper basin infill (Unit 4) are almost exclusively matrix-rich, huminitic brown coals. Persistent, widespread, low TPI values and variable, but low, average GI values are also characteristic of these telmatic coals. The overall coal petrological data trend (TPI, GI and widespread development or absence of liptiniteenriched lignite layers) recorded from the lower to the upper basin infill units agrees with the stratigraphic and sedimentological data, which show a trend of increasingly drier conditions. Development of bright, liptinite-enriched lignite layers was widespread during the early basin evolutionary stages and was influenced by punctuated water-table oscillations. Sedimentological, petrological and organic geochemical data point to the conclusion that, although the paleoenvironments where peat deposition took place did not undergo dramatic changes, they were affected by distinguishable

[1]  S. R. Moinelo,et al.  Utilization of flash chromatography for the fractionation of coal derived liquids , 1987 .

[2]  C. Diessel Coal Bearing Depositional Systems , 1992 .

[3]  G. Boillot,et al.  THE NORTH AND NORTH-WEST SPANISH CONTINENTAL MARGIN: A REVIEW < 1 l , 1988 .

[4]  E. Stach,et al.  Stach's Textbook of coal petrology , 1975 .

[5]  D. Postma The Occurrence and Chemical Composition of Recent Fe-Rich Mixed Carbonates in a River Bog , 1977 .

[6]  D. Murchison,et al.  Order of generation of petroleum hydrocarbons from liptinic macerals with increasing thermal maturity , 1988 .

[7]  J. Kantorowicz The Petrology and Diagenesis of Middle Jurassic Clastic Sediments, Ravenscar Group, Yorkshire , 1985 .

[8]  J. Becker-Platen,et al.  A contribution to the subdivision of the Neogene in Spain using palynology , 1992 .

[9]  M. Blumer,et al.  Hydrocarbons of marine phytoplankton , 1971 .

[10]  K. Pye,et al.  Marshrock formed by iron sulphide and siderite cementation in saltmarsh sediments , 1981, Nature.

[11]  M. Wolf,et al.  Petrographic and geochemical characterization of pale and dark brown coal from Yunnan province, China , 1994 .

[12]  H. Hagemann,et al.  The fluorescence behaviour of crude oils with respect to their thermal maturation and degradation , 1986 .

[13]  J. Brell,et al.  Relaciones entre los sedimentos neógenos de Galicia y las alteraciones de su substrato. Interpretación palaeoclimàtica , 1979 .

[14]  F. J. González-Vila,et al.  COMPOSICION QUIMICA DE LA FRACCION CEREA DEL LIGNITO DE PUENTES DE GARCIA RODRIGUEZ , 1987 .

[15]  G. Boillot,et al.  Subduction and tectonics on the continental margin off northern Spain , 1979 .

[16]  R. Patience Fossil Fuel Biomarkers, Applications and Spectra , 1986 .

[17]  H. Hagemann,et al.  New interpretations of the facies of the rhenish brown coal of West Germany , 1987 .

[18]  A. Hollerbach Grundlagen der organischen Geochemie , 1985 .