Effect of Hydrogen Bonding on the Surface Tension Properties of Binary Mixture (Acetone-Water) by Raman Spectroscopy

The structure and properties of water and aqueous solutions have always been the focus of attention. The surface tension of acetone aqueous solutions were measured by using Raman spectra in different molecule environments, and the changes of surface tension were analyzed with hydrogen bonding in the mixtures. In this case, OH stretching bands were fitted into three Gaussian components and then assigned to different hydrogen-bonded structures. Furthermore, it can be concluded that the changes of microstructure on the binary mixture solutions exhibited regularly with the additive acetone, indicating that there showed the correlation between surface tension and relative peak intensity. The results show that the strengthening of hydrogen bonding between acetone and water will gradually weaken the surface tension of the solutions. It was confirmed that there showed the relationship between the microstructure and macroscopic properties of the aqueous solutions by the basis experiment data using a spectroscopy method.

[1]  A. Kargovsky.  On temperature dependence of the valence band in the Raman spectrum of liquid water , 2006 .

[2]  Chenglin Sun,et al.  Structure of water molecules from Raman measurements of cooling different concentrations of NaOH solutions. , 2017, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[3]  Feng'en Chen,et al.  Hydrogen bonded structure of water and aqueous solutions of sodium halides: a Raman spectroscopic study , 2004 .

[4]  P. Wernet,et al.  The Structure of the First Coordination Shell in Liquid Water , 2004, Science.

[5]  Zhi‐Wu Yu,et al.  Recent progress on the structure of liquid water , 2016 .

[6]  Thomas Elsaesser,et al.  Water Dynamics in the Hydration Shells of Biomolecules , 2017, Chemical reviews.

[7]  S. Pershin,et al.  Changes in the Raman spectrum of OH stretching vibrations of water in an ultrasonic cavitation field , 2004 .

[8]  Zhao Cao,et al.  Raman spectroscopic investigation on pure D2O/H2O from 303 to 573 K: interpretation and implications for water structure , 2017 .

[9]  Pablo G. Debenedetti,et al.  Relationship between structural order and the anomalies of liquid water , 2001, Nature.

[10]  Haiwen Zhao,et al.  Understanding water structure from Raman spectra of isotopic substitution H2O/D2O up to 573 K. , 2017, Physical chemistry chemical physics : PCCP.

[11]  J. Scherer,et al.  Raman spectra and structure of water from -10 to 90.deg. , 1974 .

[12]  Gao,et al.  Using Raman Spectroscopy and ab initio Calculations to Investigate Intermolecular Hydrogen Bonds in Binary Mixture (Tetrahydrofuran+Water) , 2011 .

[13]  A. Tokmakoff.  Shining Light on the Rapidly Evolving Structure of Water , 2007, Science.

[14]  Qiang Sun.  Local statistical interpretation for water structure , 2013 .

[15]  Hajime Tanaka,et al.  Understanding water’s anomalies with locally favoured structures , 2013, Nature Communications.

[16]  D. M. Carey,et al.  Measurement of the Raman Spectrum of Liquid Water , 1996 .

[17]  Peter G. Kusalik,et al.  The Spatial Structure in Liquid Water , 1994, Science.

[18]  Rustam Z. Khaliullin,et al.  Nature of the asymmetry in the hydrogen-bond networks of hexagonal ice and liquid water. , 2014, Journal of the American Chemical Society.

[19]  R. Cataliotti,et al.  Silver nanoparticles behave as hydrophobic solutes towards the liquid water structure in the interaction shell. A Raman study in the O-H stretching region. , 2009, Physical chemistry chemical physics : PCCP.

[20]  W. Kumler.  The Effect of the Hydrogen Bond on the Dielectric Constants and Boiling Points of Organic Liquids , 1935 .

[21]  Chen Shen,et al.  Effects of hydrogen bond on the melting point of azole explosives , 2018, Journal of Molecular Structure.

[22]  M. Albertí,et al.  Tetrahedral ordering in water: Raman profiles and their temperature dependence. , 2009, The journal of physical chemistry. A.

[23]  M. Rodnikova,et al.  Some peculiarities of liquid water structure , 2003 .

[24]  R. Saykally,et al.  Response to Comment on "Energetics of Hydrogen Bond Network Rearrangements in Liquid Water" , 2005, Science.

[25]  P. Luckham,et al.  The effects of hydrogen bonding upon the viscosity of aqueous poly(vinyl alcohol) solutions , 2000 .

[26]  Qiang Sun.  The single donator-single acceptor hydrogen bonding structure in water probed by Raman spectroscopy. , 2010, The Journal of chemical physics.

[27]  M. Marchetti,et al.  Water–ice phase transition probed by Raman spectroscopy , 2011 .

[28]  F. Stillinger,et al.  Hydrogen-bond patterns in liquid water , 1973 .

[29]  G. Walrafen,et al.  Raman and Infrared Spectral Investigations of Water Structure , 1972 .

[30]  D. Risović,et al.  Comparison of Raman spectroscopic methods for the determination of supercooled and liquid water temperature , 2005 .

[31]  Samir Kumar Pal,et al.  Biological water: A critique , 2011 .

[32]  Zhizhu He,et al.  Detection of water–ice phase transition based on Raman spectrum , 2013 .

[33]  G. Walrafen,et al.  Raman Spectral Studies of the Effects of Temperature on Water Structure , 1967 .

[34]  S. Sastry.  Water structure: Order and oddities , 2001, Nature.

[35]  C. Dellago,et al.  Autoionization in Liquid Water , 2001, Science.

[36]  Greg L. Hura,et al.  Water structure from scattering experiments and simulation. , 2002, Chemical reviews.

[37]  Rémy Claverie,et al.  Experimental Study of NaCl Aqueous Solutions by Raman Spectroscopy: Towards a New Optical Sensor , 2010, Applied spectroscopy.