catena-Poly[[chlorido[(1S,2S)-cyclohexane-1,2-diamine-κ2N,N′]copper(II)]-μ3-chlorido]
暂无分享,去创建一个
In the repeat unit of the title compound, [CuCl2(C6H14N2)], there are two chiral C atoms with an S configuration. In the crystal packing, one Cl atom plays an important role, acting as a bridge linking neighboring units, forming a polymeric one-dimensional ladder-like structure. The Cu atom has an approximately square-planar primary coordination geometry, with the bridging Cl atoms forming much longer bonds in the axial positions.
[1] S. Lippard,et al. 2.4 A crystal structure of an oxaliplatin 1,2-d(GpG) intrastrand cross-link in a DNA dodecamer duplex. , 2001, Inorganic chemistry.
[2] A. Khokhar,et al. X-ray crystal structure of tetrachloro(trans-d,l-1,2-diaminocyclohexane) platinum(IV) complex: a potential anticancer agent. , 1993, Journal of inorganic biochemistry.
[3] H. Flack,et al. On enantiomorph‐polarity estimation , 1983 .