Fiber/matrix interfacial thermal conductance effect on the thermal conductivity of SiC/SiC composites

Abstract SiC/SiC composites used in fusion reactor applications are subjected to high heat fluxes and require knowledge and tailoring of their in-service thermal conductivity. Accurately predicting the thermal conductivity of SiC/SiC composites as a function of temperature will guide the design of these materials for their intended use, which will eventually include the effects of 14-MeV neutron irradiations. This paper applies an Eshelby–Mori–Tanaka approach (EMTA) to compute the thermal conductivity of unirradiated SiC/SiC composites. The homogenization procedure includes three steps. In the first step EMTA computes the homogenized thermal conductivity of the unidirectional (UD) SiC fiber embraced by its coating layer. The second step computes the thermal conductivity of the UD composite formed by the equivalent SiC fibers embedded in a SiC matrix, and finally the thermal conductivity of the as-formed SiC/SiC composite is obtained by averaging the solution for the UD composite over all possible fiber orientations using the second-order fiber orientation tensor. The EMTA predictions for the transverse thermal conductivity of several types of SiC/SiC composites with different fiber types and interfaces are compared to the predicted and experimental results by Youngblood et al. [J. Nucl. Mater. 307–311 (2002) 1120–1125, Fusion Sci. Technol. 45 (2004) 583–591, Compos. Sci. Technol. 62 (2002) 1127–1139.]

[1]  Russel H. Jones,et al.  Optimizing the transverse thermal conductivity of 2D-SiCf/SiC composites. I. Modeling , 2002 .

[2]  Timothy Abram,et al.  Thermal conductivity mapping of pyrolytic carbon and silicon carbide coatings on simulated fuel particles by time-domain thermoreflectance , 2008 .

[3]  A. Kohyama,et al.  Low Temperature Swelling in Beta-SiC Associated with Point Defect Accumulation , 2002 .

[4]  Russel H. Jones,et al.  Subcritical crack growth in CVI SiCf/SiC composites at elevated temperatures: effect of fiber creep rate , 2001 .

[5]  R. Jones,et al.  Time-dependent, environmentally assisted crack growth in nicalon-fiber-reinforced SiC composites at elevated temperatures , 1996 .

[6]  H. Okumura,et al.  Radiation induced defects in CVD-grown 3C-SiC , 1990 .

[7]  W. J. Weber,et al.  Damage accumulation and annealing in 6H–SiC irradiated with Si+ , 1998 .

[8]  C. Henager Swelling and time-dependent crack growth in SiC/SiC composites , 2007 .

[9]  R. Devanathan,et al.  Radiation damage evolution in ceramics , 2009 .

[10]  D. Hasselman,et al.  Effective Thermal Conductivity of Composites with Interfacial Thermal Barrier Resistance , 1987 .

[11]  K. Tanaka,et al.  Average stress in matrix and average elastic energy of materials with misfitting inclusions , 1973 .

[12]  A. Kohyama,et al.  Microstructural development in cubic silicon carbide during irradiation at elevated temperatures , 2006 .

[13]  A. Kohyama,et al.  Radiation swelling of SiC under neutron irradiation , 2002 .

[14]  Toshio Mura,et al.  Micromechanics of defects in solids , 1982 .

[15]  T. Yano,et al.  Neutron irradiation damage of silicon carbide , 1995 .

[16]  Russel H. Jones,et al.  Modeling the Transverse Thermal Conductivity of 2-D SiCf/SiC Composites Made with Woven Fabric , 2004 .

[17]  Russel H. Jones,et al.  Optimizing the transverse thermal conductivity of 2D-SiCf/SiC composites, II. Experimental , 2002 .

[18]  Y. Katoh,et al.  Handbook of SiC properties for fuel performance modeling , 2007 .

[19]  G. Youngblood,et al.  Defect structure and evolution in silicon carbide irradiated to 1 dpa-SiC at 1100 °C , 2003 .

[20]  Lance Lewis Snead,et al.  Thermophysical and mechanical properties of near-stoichiometric fiber CVI SiC/SiC composites after neutron irradiation at elevated temperatures , 2010 .

[21]  J. D. Eshelby The determination of the elastic field of an ellipsoidal inclusion, and related problems , 1957, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[22]  A. J. Markworth The transverse thermal conductivity of a unidirectional fibre composite with fibre-matrix debonding: a calculation based on effective-medium theory , 1993, Journal of Materials Science Letters.

[23]  Russel H. Jones,et al.  The transverse thermal conductivity of 2D-SiCf/SiC composites , 2002 .

[24]  C. Henager,et al.  Subcritical crack growth in CVI SiCf/SiC composites at elevated temperatures: dynamic crack growth model , 2001 .

[25]  S. Zinkle,et al.  Thermal conductivity degradation of ceramic materials due to low temperature, low dose neutron irradiation , 2005 .

[26]  W. Weber,et al.  Investigation of irradiation effects induced by self-ion in 6H-SiC combining RBS/C, Raman and XRD , 2012 .

[27]  Thermal expansivity and conductivity of pure and silicon-alloyed pyrocarbons , 1974 .

[28]  A. Kohyama,et al.  Recent advances in the development of SiC/SiC as a fusion structural material , 1998 .

[29]  Akira Kohyama,et al.  Current status and critical issues for development of SiC composites for fusion applications , 2007 .

[30]  W. J. Weber,et al.  Computer simulation of a 10 keV Si displacement cascade in SiC , 1998 .

[31]  R. Jones,et al.  High-temperature properties of SiC/SiC for fusion applications , 1994 .

[32]  Y. Benveniste,et al.  A new approach to the application of Mori-Tanaka's theory in composite materials , 1987 .

[33]  Lance Lewis Snead,et al.  Operating Temperature Window for SiC Ceramics and Composites for Fusion Energy Applications , 2009 .

[34]  William J. Weber,et al.  Atomic scale simulation of defect production in irradiated 3C-SiC , 2001 .

[35]  J. Bokros,et al.  Neutron-induced charges in crystallinity and thermal conductivity of pyrolytic carbons☆ , 1966 .

[36]  Hatta Hiroshi,et al.  Equivalent inclusion method for steady state heat conduction in composites , 1986 .

[37]  Y. Katoh,et al.  Stability of SiC and its composites at high neutron fluence , 2011 .

[38]  A. Kohyama,et al.  Recent advances and issues in development of silicon carbide composites for fusion applications , 2009 .

[39]  Akira Kohyama,et al.  Evaluation of neutron irradiated near-stoichiometric silicon carbide fiber composites , 2000 .

[40]  Suresh G. Advani,et al.  The Use of Tensors to Describe and Predict Fiber Orientation in Short Fiber Composites , 1987 .

[41]  F. Gao,et al.  Primary damage states produced by Si and Au recoils in SiC: A molecular dynamics and experimental investigation , 2001 .

[42]  R. H. Jones,et al.  Status and prospects for SiCSiC composite materials development for fusion applications , 1995 .

[43]  C. Henager,et al.  High temperature corrosion and crack growth of SiCSiC at variable oxygen partial pressures , 1995 .