Mechanism of surface plasmon-catalyzed reaction of fluorine phenylboronic acid

Abstract. Surface plasmon (SP)-catalyzed reactions of fluorine phenylboronic acid   [  F-PhB(OH)2  ]   to fluorine phenylboronic ester (F-PhB-E) substituted with fluorine have been investigated by surface-enhanced Raman scattering (SERS). Conversion of F-PhB(OH)2 to F-PhB-E is induced by hot electrons from SP decay. The spectral peaks of F-PhB-E of the SERS were also enumerated.

[1]  Hongxing Xu,et al.  A novel application of plasmonics: plasmon-driven surface-catalyzed reactions. , 2012, Small.

[2]  Hongxing Xu,et al.  Plasmonic scissors for molecular design. , 2013, Chemistry.

[3]  Araceli Vega,et al.  3-Aminophenylboronic acid monohydrate , 2010, Acta crystallographica. Section E, Structure reports online.

[4]  B. Cao,et al.  Fabrication and Formation Mechanism of Ag Nanoplate-Decorated Nanofiber Mats and Their Application in SERS. , 2016, Chemistry, an Asian journal.

[5]  Zhong-Qun Tian,et al.  When the signal is not from the original molecule to be detected: chemical transformation of para-aminothiophenol on Ag during the SERS measurement. , 2010, Journal of the American Chemical Society.

[6]  Y. Ozaki,et al.  Influence of substituent type and position on the adsorption mechanism of phenylboronic acids: infrared, Raman, and surface-enhanced Raman spectroscopy studies. , 2013, The journal of physical chemistry. A.

[7]  Wei Song,et al.  Contribution of hydrogen bonding to charge-transfer induced surface-enhanced Raman scattering of an intermolecular system comprising p-aminothiophenol and benzoic acid. , 2014, Physical chemistry chemical physics : PCCP.

[8]  K. Schanze,et al.  Mechanistic understanding of surface plasmon assisted catalysis on a single particle: cyclic redox of 4-aminothiophenol , 2013, Scientific Reports.

[9]  Sheng-Chao Huang,et al.  Tip-enhanced Raman spectroscopy for surfaces and interfaces. , 2017, Chemical Society reviews.

[10]  B. Sumerlin,et al.  Biomedical applications of boronic acid polymers , 2011 .

[11]  D. Ni,et al.  Rapid qualitative and quantitative determination of food colorants by both Raman spectra and Surface-enhanced Raman Scattering (SERS). , 2018, Food chemistry.

[12]  G. Jiang,et al.  Tracking the Fate of Surface Plasmon Resonance-Generated Hot Electrons by In Situ SERS Surveying of Catalyzed Reaction. , 2016, Small.

[13]  Yunfei Xie,et al.  Characterization of lipid oxidation process of beef during repeated freeze-thaw by electron spin resonance technology and Raman spectroscopy. , 2018, Food chemistry.

[14]  S. Rettig,et al.  CRYSTAL AND MOLECULAR STRUCTURE OF PHENYLBORONIC ACID, (C6H5B(OH)2) , 1977 .

[15]  Jinhuai Liu,et al.  Monitoring plasmon-driven surface catalyzed reactions in situ using time-dependent surface-enhanced Raman spectroscopy on single particles of hierarchical peony-like silver microflowers. , 2014, Nanoscale.

[16]  Thimmaiah Govindaraju,et al.  SERS and fluorescence-based ultrasensitive detection of mercury in water. , 2018, Biosensors & bioelectronics.

[17]  Nan Li,et al.  Chemical Sensing on a Single SERS Particle. , 2017, ACS sensors.