The application of CFD modelling to support the reduction of CO2 emissions in cement industry

The cement industry is one of the leading producers of anthropogenic greenhouse gases, of which CO2 is the most significant. Recently, researchers have invested a considerable amount of time studying ways to improve energy consumption and pollutant formation in the overall cement manufacturing process. One idea involves dividing the calcination and clinkering processes into two separate furnaces. The calcination process is performed in a calciner while the clinkering process takes place in a rotary kiln. As this is new technology in the cement manufacturing process, calciners are still in the research and development phase. The purpose of this paper is to demonstrate the potential of CFD to support the design and optimization of calciners, whose use appears to be essential in reduction of CO2 emission during cement production. The mathematical model of the calcination process was developed, validated and implemented into a commercial CFD code, which was then used for the analysis. From the results obtained by these simulations, researchers will gain an in-depth understanding of all thermo-chemical reactions in a calciner. This understanding can be used to optimize the calciner's geometry, to make production more efficient, to lower pollutant formation and to subsequently reduce greenhouse gas emissions.

[1]  Ron Zevenhoven,et al.  CEMENT MANUFACTURING USING ALTERNATIVE FUELS AND THE ADVANTAGES OF PROCESS MODELLING , 2004 .

[2]  Neven Duić,et al.  Validation of reduced mechanisms for nitrogen chemistry in numerical simulation of a turbulent non-premixed flame , 2009 .

[3]  G. Froment,et al.  Chemical Reactor Analysis and Design , 1979 .

[4]  Neven Duić,et al.  Adaptation of n-heptane autoignition tabulation for complex chemistry mechanisms , 2011 .

[5]  Arnaud Mercier,et al.  Prospective on the energy efficiency and CO 2 emissions in the EU cement industry , 2011 .

[6]  Matthias Krey,et al.  Assessment of clean development mechanism potential of large-scale energy efficiency measures in heavy industries , 2007 .

[7]  Gordana Stefanović,et al.  CO2 reduction options in cement industry: The Novi Popovac case , 2010 .

[8]  W. P. Jones,et al.  Global reaction schemes for hydrocarbon combustion , 1988 .

[9]  Mikiko Kainuma,et al.  A projection for global CO2 emissions from the industrial sector through 2030 based on activity level and technology changes , 2011 .

[10]  Abbas Seifi,et al.  A system dynamics model for analyzing energy consumption and CO2 emission in Iranian cement industry under various production and export scenarios , 2013 .

[11]  O. Levenspiel Chemical Reaction Engineering , 1972 .

[12]  Fotis N. Koumboulis,et al.  Indirect adaptive neural control for precalcination in cement plants , 2002, Math. Comput. Simul..

[13]  Siegmar Wirtz,et al.  A coupled fluid dynamic-discrete element simulation of heat and mass transfer in a lime shaft kiln , 2010 .

[14]  Neven Duić,et al.  Implementation of discrete transfer radiation method into SWIFT computational fluid dynamics code , 2004 .

[15]  Juan Carlos Ciscar,et al.  CO2 emission trading within the European Union and Annex B countries: the cement industry case , 2006 .

[16]  Claudia Sheinbaum,et al.  Energy use and CO2 emissions for Mexico's cement industry , 1998 .

[17]  Ernst Worrell,et al.  Potentials for energy efficiency improvement in the US cement industry , 2000 .

[18]  Kim Dam-Johansen,et al.  Modeling of in-line low-NOx calciners—a parametric study , 2002 .

[19]  Jiri Blazek,et al.  Computational Fluid Dynamics: Principles and Applications , 2001 .

[20]  Martin Schneider,et al.  Experimentelle und mathematische Modellierung der Festbettvergasung am Beispiel der Gleichstromvergasung von Holzhackschnitzeln , 2002 .

[21]  Jidong Lu,et al.  Numerical simulation study on gas–solid two-phase flow in pre-calciner , 2006 .

[22]  D. Fidaros,et al.  A parametric study of a solar calcinator using computational fluid dynamics , 2007 .

[23]  David W. Pershing,et al.  Mathematical model for the flash calcination of dispersed CaCO3 and Ca(OH)2 particles , 1989 .

[24]  Neven Duić,et al.  Numerical modelling of calcination reaction mechanism for cement production , 2012 .

[25]  Neven Duić,et al.  Three-dimensional Numerical Simulation of the Nitrogen Oxides Formation in an Oil-fired Furnace , 2007 .

[26]  D. Fidaros,et al.  Numerical modelling of flow and transport processes in a calciner for cement production , 2007 .

[27]  C. Angelopoulos High resolution schemes for hyperbolic conservation laws , 1992 .

[28]  K. P.,et al.  HIGH RESOLUTION SCHEMES USING FLUX LIMITERS FOR HYPERBOLIC CONSERVATION LAWS * , 2012 .

[29]  Marc Ross,et al.  Energy efficiency of China's cement industry , 1995 .

[30]  Neven Duić,et al.  Application of the Conservative Discrete Transfer Radiation Method to a Furnace with Complex Geometry , 2005 .

[31]  E. Gartner Industrially interesting approaches to “low-CO2” cements ☆ , 2004 .

[32]  Zhao Xiujian,et al.  Numerical study of gas–solid flow in a precalciner using kinetic theory of granular flow , 2004 .

[33]  Lynn Price,et al.  The CO2 abatement cost curve for the Thailand cement industry , 2010 .