Simplified Transient Hot-Wire method for Effective Thermal Conductivity Measurement in Geo-Materials: Microstructure and Saturation effect

The thermal conductivity measurement by a simplified transient hot-wire technique is applied to geomaterials in order to show the relationships which can exist between effective thermal conductivity, texture, and moisture of the materials. After a validation of the used “one hot-wire” technique in water, toluene, and glass-bead assemblages, the investigations were performed (1) in glass-bead assemblages of different diameters in dried, water, and acetone-saturated states in order to observe the role of grain sizes and saturation on the effective thermal conductivity, (2) in a compacted earth brick at different moisture states, and (3) in a lime-hemp concrete during 110 days following its manufacture. The lime-hemp concrete allows the measurements during the setting, desiccation and carbonation steps. The recorded Δ𝑇/ln(𝑡) diagrams allow the calculation of one effective thermal conductivity in the continuous and homogeneous fluids and two effective thermal conductivities in the heterogeneous solids. The first one measured in the short time acquisitions (<1 s) mainly depends on the contact between the wire and grains and thus microtexture and hydrated state of the material. The second one, measured for longer time acquisitions, characterizes the mean effective thermal conductivity of the material.

[1]  Françoise Homand,et al.  Effective thermal conductivity of partially saturated porous rocks , 2007 .

[2]  Keith L. Bristow,et al.  Measurement of thermal properties and water content of unsaturated sandy soil using dual-probe heat-pulse probes , 1998 .

[3]  F. Štěpánek,et al.  Effective thermal conductivity of wet particle assemblies , 2004 .

[4]  A. Bouguerra Temperature and moisture dependence on the thermal conductivity of wood-cement-based composite: experimental and theoretical analysis , 1999 .

[5]  Thomas C. Melvin,et al.  European Patent Office , 2002 .

[6]  Maria Stefanidou,et al.  Thermal Conductivity of Building Materials Employed in the Preservation of Traditional Structures , 2010 .

[7]  W. Wakeham,et al.  The thermal conductivity of toluene and water , 1993 .

[8]  William A. Wakeham,et al.  A transient hot-wire instrument for thermal conductivity measurements in electrically conducting liquids at elevated temperatures , 1982 .

[9]  W. Wakeham,et al.  An apparatus to measure the thermal conductivity of liquids , 1976 .

[10]  Ismail H. Tavman,et al.  Effective thermal conductivity of granular porous materials , 1996 .

[11]  R. Perkins,et al.  Measurement and Correlation of the Thermal Conductivity of Propane from 86 K to 600 K at Pressures to 70 MPa , 2002 .

[12]  A. Revil,et al.  Thermal conductivity of unsaturated clay-rocks , 2008 .

[13]  William A. Wakeham,et al.  Measurement of the Transport Properties of Fluids , 1991 .

[14]  S. Martemianov,et al.  A New Transient Two-Wire Method for Measuring the Thermal Diffusivity of Electrically Conducting and Highly Corrosive Liquids Using Small Samples , 2008 .

[15]  R. Perkins,et al.  Thermal Conductivity of Saturated Liquid Toluene by Use of Anodized Tantalum Hot Wires at High Temperatures , 2000, Journal of research of the National Institute of Standards and Technology.

[16]  A. Nagashima,et al.  ABSOLUTE MEASUREMENT OF THE THERMAL CONDUCTIVITY OF ELECTRICALLY CONDUCTING LIQUIDS BY THE TRANSIENT HOT-WIRE METHOD (THERMAL CONDUCTIVITY OF AN AQUEOUS NaCl SOLUTION AT HIGH PRESSURE). , 1981 .

[17]  Amélie Testu Dispersion thermique dans des milieux granulaires : caractérisation à coeur et en proche paroi , 2005 .

[18]  R. Dheilly,et al.  Effect of microstructure on the mechanical and thermal properties of lightweight concrete prepared from clay, cement, and wood aggregates , 1998 .

[19]  S. Martemianov,et al.  A New Transient Hot-Wire Instrument for Measuring the Thermal Conductivity of Electrically Conducting and Highly Corrosive Liquids using Small Samples , 2008 .

[20]  P. Bowen,et al.  Changes in portlandite morphology with solvent composition: Atomistic simulations and experiment , 2011 .

[21]  E. Gonzo Estimating correlations for the effective thermal conductivity of granular materials , 2002 .

[22]  Konstantinos Kakosimos,et al.  An Improved Application of the Transient Hot-Wire Technique for the Absolute Accurate Measurement of the Thermal Conductivity of Pyroceram 9606 up to 420 K , 2008 .

[23]  J. Kestin,et al.  The theory of the transient hot-wire method for measuring thermal conductivity , 1976 .

[24]  H. Martin Low peclet number particle-to-fluid heat and mass transfer in packed beds , 1978 .

[25]  F. Li,et al.  Measurement of thermal conductivity of hollow glass-bead-filled polypropylene composites , 2006 .

[26]  Keith L. Bristow,et al.  A small multi-needle probe for measuring soil thermal properties, water content and electrical conductivity , 2001 .

[27]  Jiangtao Wu,et al.  New Measurements of the Thermal Conductivity of PMMA, BK7, and Pyrex 7740 up to 450K , 2008 .

[28]  J. Parsons,et al.  Measurement of the properties of liquids and gases using a transient hot-wire technique. , 1978, The Review of scientific instruments.

[29]  J. Cull Thermal conductivity probes for rapid measurements in rock , 1974 .

[30]  G. Batchelor,et al.  Thermal or electrical conduction through a granular material , 1977, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[31]  William A. Wakeham,et al.  Historical Evolution of the Transient Hot-Wire Technique , 2010 .

[32]  J. C. Jaeger,et al.  Conduction of Heat in Solids , 1952 .

[33]  V. Altuzar,et al.  Atmospheric pollution profiles in Mexico City in two different seasons , 2003 .

[34]  Aj Peck,et al.  On the Cylindrical Probe Method of Measuring Thermal Conductivity with Special Reference to Soils. I. Extension of Theory and Discussion of Probe Characteristics , 1958 .