Synthesis, characterization, redox properties, and representative X-ray structures of four- and five-coordinate copper(II) complexes with polydentate aminopyridine ligands

[1]  C. Fraser,et al.  Metal Complexes with Cis alpha Topology from Stereoselective Quadridentate Ligands with Amine, Pyridine, and Quinoline Donor Groups. , 1999, Inorganic chemistry.

[2]  A. Deydier,et al.  Influence of Coordination Geometry upon Copper(II/I) Redox Potentials. Physical Parameters for Twelve Copper Tripodal Ligand Complexes , 1999 .

[3]  P. Mialane,et al.  Characterization of a Nonheme Mononuclear Peroxoiron(III) Intermediate by UV/Vis and EPR Spectroscopy and Mass Spectrometry , 1999 .

[4]  E. Rybak-Akimova,et al.  Unusual Ligand Isomerization Dictated by Coordination Requirements of the Metal Ion: A Double-Bond Shift in Cu(II)-Assisted Template Condensation between Diacetylpyridine and a Tripodal Tetramine. , 1999, Inorganic chemistry.

[5]  A. Spek,et al.  Iron Chemistry of a Pentadentate Ligand That Generates a Metastable Fe(III)-OOH Intermediate. , 1999, Inorganic chemistry.

[6]  L. Azéma,et al.  Structures of Fe(II) Complexes with N,N,N'-Tris(2-pyridylmethyl)ethane-1,2-diamine Type Ligands. Bleomycin-like DNA Cleavage and Enhancement by an Alkylammonium Substituent on the N' Atom of the Ligand. , 1999, Inorganic chemistry.

[7]  M. Sugiyama,et al.  Oxidative and random cleavage of DNA by the novel iron(II) complex capable of yielding an iron(III) hydroperoxide intermediate , 1998 .

[8]  A. Bond,et al.  Structural, EPR, and Electrochemical Studies of Binuclear Copper(II) Complexes of Bis(pentadentate) Ligands Derived from Bis(1,4,7-triazacyclonane) Macrocycles. , 1998, Inorganic chemistry.

[9]  F. A. Chavez,et al.  Synthesis, structure, and properties of N,N′-bis[2-(1-pyrazolyl)ethyl]-pyridine-2,6-dicar☐amido copper(II) , 1998 .

[10]  J. Aldrich-Wright,et al.  Design of chiral picen-based metal complexes for molecular recognition of α-aminoacids and nucleic acids , 1997 .

[11]  D. Busch,et al.  A cis-Octahedral Dichloro Complex of FeIII with a Tetradentate Dipyridyl–Diamino Ligand , 1997 .

[12]  E. C. Wilkinson,et al.  Functional models for iron-bleomycin , 1997 .

[13]  T. Murakami,et al.  Crystal structures and spectral properties of five-coordinate copper(II) complexes with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdt) and α-diamines: Approximately regular trigonal bipyramidal [Cu(en)(pmdt)](ClO4)2 and highly distorted [Cu(SS-chxn(pmdt)](ClO4)2 (en 1,2-diaminoethane and SS-chxn , 1996 .

[14]  R. Hancock,et al.  Metal Complexes in Aqueous Solutions , 1996 .

[15]  F. A. Chavez,et al.  Synthesis, Structure, and Properties of {N,N'- Bis[2-(2-pyridyl)ethyl]pyridine-2,6-dicarboxamido}copper(II). , 1996, Inorganic chemistry.

[16]  W. Kaim,et al.  Copper—A “Modern” Bioelement , 1996 .

[17]  D. Hodgson,et al.  Magnetic Exchange through Oxalate Bridges: Synthesis and Characterization of (.mu.-Oxalato)dimetal(II) Complexes of Manganese, Iron, Cobalt, Nickel, Copper, and Zinc , 1995 .

[18]  G. Anderegg,et al.  The effect of chelate ring size on metal ion size-based selectivity in polyamine ligands containing pyridyl and saturated nitrogen donor groups , 1995 .

[19]  E. C. Wilkinson,et al.  NONHEME IRON CENTERS IN OXYGEN ACTIVATION : CHARACTERIZATION OF AN IRON(III) HYDROPEROXIDE INTERMEDIATE , 1995 .

[20]  J. Lown,,et al.  Functional Models of the Antitumor Antibiotic Bleomycin , 1995, Current Medicinal Chemistry.

[21]  A. Messerschmidt Blue Copper Oxidases , 1994 .

[22]  T. Pandiyan,et al.  Synthesis, spectra and electrochemical behaviour of biomimetic copper(II) complexes with CuN5 and CuN6 chromophores , 1994 .

[23]  H. Toftlund,et al.  Synthesis and Characterization of Bis(.mu.-oxo)dimanganese(III,III), -(III,IV), and -(IV,IV) Complexes with Ligands Related to N,N'-Bis(2-pyridylmethyl)-1,2-ethanediamine (Bispicen) , 1994 .

[24]  N. Arulsamy,et al.  Synthesis and Characterization of Complexes Containing the (µ-Oxo) (µ-acetato)dimanganee(III/III) Core , 1994 .

[25]  N. Arulsamy,et al.  Binuclear oxo-bridged iron(III) complexes of N,N'-bis(2-pyridylmethyl)ethane-1,2-diamine (bispicen) and related ligands , 1994 .

[26]  N. Arulsamy,et al.  Mononuclear and binuclear oxo-bridged iron(III) complexes of N,N'-bis(2-pyridylmethyl)ethane-1,2-diamine (bispicen) , 1993 .

[27]  D. Hodgson,et al.  Syntheses and characterization of binuclear manganese(III,IV) and -(IV,IV) complexes with ligands related to N,N'-bis(2-pyridylmethyl)-1,2-ethanediamine , 1991 .

[28]  E. Pedersen,et al.  Tetranuclear heterometallic complexes of the general types [M{(OH)2CrA4}3]5+ and [M{(OH)2CoA4}3]5+ , 1991 .

[29]  D. Hodgson,et al.  Design, synthesis, and characterization of bis(.mu.-oxo)dimanganese(III,III) complexes. Steric and electronic control of redox potentials , 1990 .

[30]  T. Kaden,et al.  Metal complexes of macrocyclic ligands. Part XXXIII. Effect of the side‐chain length on the on/off equilibrium in the Ni2+ and Cu2+ complexes of 11‐(2‐aminoethyl)‐ and 11‐(3‐aminopropyl)‐1,4,7,11‐tetraazacyclotetradecane , 1990 .

[31]  J. Bradshaw,et al.  Enantiomeric Recognition of Organic Ammonium Salts by Chiral Dialkyl-, Dialkenyl-, and Tetramethyl-Substituted Pyridino-18-Crown-6 and Tetramethyl- Substituted Bis-Pyridino-18-Crown-6 Ligands: Comparison of Temperature-Dependent 1H NMR and Empirical Force Field Techniques , 1990 .

[32]  E. Pedersen,et al.  Binuclear bis(.mu.-oxo)dimanganese(III,IV) and -(IV,IV) complexes with N,N'-bis(2-pyridylmethyl)-1,2-ethanediamine , 1990 .

[33]  A. Addison Is ligand topology an influence on the redox potentials of copper complexes , 1989 .

[34]  Steven J Brown,et al.  Syntheses, structures, and spectral properties of a synthetic analog of copper(II)-bleomycin and an intermediate in the process of its formation , 1989 .

[35]  Colin Eaborn,et al.  Comprehensive Coordination Chemistry , 1988 .

[36]  Steven J Brown,et al.  Characterization of a crystalline synthetic analog of copper(II)-bleomycin , 1988 .

[37]  C. Groeneveld,et al.  EPR of azurins from Pseudomonas aeruginosa and Alcaligenes denitrificans demonstrates pH-dependence of the copper-site geometry in Pseudomonas aeruginosa protein. , 1987, Journal of inorganic biochemistry.

[38]  P. Pallavicini,et al.  N-(aminoethyl)cyclam: a tetraaza macrocycle with a coordinating tail (scorpiand). Acidity controlled coordination of the side chain to nickel(II) and nickel(III) cations , 1987 .

[39]  K. M. Davies,et al.  Redox behavior of copper(II) and copper(I) complexes with tetradentate bis(pyridyl)-dithiaether and bis(pyridyl)-diaza ligands towards ruthenium ammine and bipyridyl complexes , 1987 .

[40]  Y. Sugiura,et al.  Bleomycin Antibiotics: Metal Complexes and Their Biological Action , 1986 .

[41]  G. Newkome,et al.  Obstacle effect in palladium(II) complexes of tetraamine ligands with terminal pyridyl or picolyl residues , 1985 .

[42]  E. Pedersen,et al.  Synthesis and characterization of the chromium(III) dimer bis(.mu.-hydroxo)bis[[N,N'-bis(2-pyridylmethyl)-1,2-ethanediamine]chromium(III)] perchlorate, [(bispicen)Cr(OH)]2(ClO4)4.H2O , 1985 .

[43]  E. Pedersen,et al.  Synthesis and characterization of the dimeric chromium(III) complex di-μ- hydroxobis[{N,N′-bis(2-pyridylmethyl)-1,3-propanediamine}-chromium(III)] perchlorate, [(bispictn)Cr(OH)]2(ClO4)4·3H2O , 1984 .

[44]  G. Newkome,et al.  Synthesis and structural aspects of macrocyclic polyamines containing 2,2'-bipyridinyl units(s) , 1983 .

[45]  F. Urbach,et al.  Copper(II) complexes with tetradentate bis(pyridyl)-dithioether and bis(pyridyl)-diamine ligands. Effect of thio ether donors on the electronic absorption spectra, redox behavior, and EPR parameters of copper(II) complexes , 1983 .

[46]  A. Bencini,et al.  Formation of nickel(III) complexes with n-dentate amine macrocycles (n = 4, 5, 6). ESR and electrochemical studies , 1981 .

[47]  T. Takita,et al.  Chemistry of bleomycin. XX. The X-ray structure determination of P-3A Cu(II)-complex a biosynthetic intermediate of bleomycin. , 1978, The Journal of antibiotics.

[48]  L. A. Ochrymowycz,et al.  Letter: Redox properties of copper-thiaether complexes. Comparison to blue copper protein behavior. , 1976, Journal of the American Chemical Society.

[49]  J. Harrowfield,et al.  Geometrical, optical and conformational isomers of octahedral metal complexes formed with a linear quadridentate amine ligand. The 3,2,3-tet [1,10-dimino-4,7-diazadecane] system , 1975 .

[50]  R. H. Holm,et al.  Structural and electronic effects on the polarographic half-wave potentials of copper (II) chelate complexes. , 1975, Bioinorganic chemistry.

[51]  J. Peisach,et al.  Structural implications derived from the analysis of electron paramagnetic resonance spectra of natural and artificial copper proteins. , 1974, Archives of biochemistry and biophysics.

[52]  J. Richman,et al.  NITROGEN ANALOGS OF CROWN ETHERS , 1974 .

[53]  E. Muetterties,et al.  Idealized polytopal forms. Description of real molecules referenced to idealized polygons or polyhedra in geometric reaction path form , 1974 .

[54]  H. Goodwin,et al.  Quadridentate Chelate Compounds. II1 , 1960 .

[55]  D. Busch,et al.  Catalytic action of the iron(II) complexes of 8-methyl-1,4-bis(2-pyridylmethyl)-1,4,8-triazacycloundecane and 1-methyl-5,9-bis(2-pyridylmethyl)-1,5,9-triazacyclododecane , 1999 .

[56]  J. Pedersen,et al.  Deprotonation of low-spin mononuclear iron(III)–hydroperoxide complexes give transient blue species assigned to high-spin iron(III)–peroxide complexes , 1999 .

[57]  G. Roelfes,et al.  Resonance Raman evidence for the interconversion between an [FeIII–η1-OOH] 2+ and [FeIII–η2-O2]+ species and mechanistic implications thereof , 1999 .

[58]  V. Pavlishchuk Effect of the composition and topology of the coordination polyhedron on electron transfer in d9/d10 redox systems , 1995 .

[59]  H. Toftlund,et al.  Iron(II) complexes of polydentate aminopyridyl ligands and an exchangeable sixth ligand; reactions with peroxides. Crystal structure of [FeL1(H2O)][PF6]2·H2O [L1=N,N′-bis-(6-methyl-2-pyridylmethyl)-N,N′-bis(2-pyridylmethyl)ethane-1,2-diamine] , 1995 .

[60]  R. L. Martin,et al.  SYNTHESIS, STRUCTURE AND PROPERTIES OF FIVE-COORDINATE COPPER(II) COMPLEXES OF PENTADENTATE LIGANDS WITH PYRIDYL PENDANT ARMS , 1995 .

[61]  P. Moore,et al.  Studies of pendant-arm macrocyclic ligands. Part 8. Synthesis of two pentaazamacrocycles based upon pyridine-containing tetraazamacrocycles with a single pendant co-ordinating 2-pyridylmethyl arm, and characterisation of their nickel(II), copper(II) and zinc(II) complexes. Crystal structure of 7-(2′ , 1994 .

[62]  D. Hodgson,et al.  Magnetic exchange through hydrogen bonds: structural and magnetic characterization of cis-hydroxoaquachromium(III) complexes of tetradentate and monodentate ligands , 1994 .

[63]  T. Pandiyan,et al.  Structure, spectra and redox behaviour of copper(II) complexes of bis(benzimidazolyl)diamine ligands , 1992 .

[64]  L. A. Ochrymowycz,et al.  Comparison of the influence of saturated nitrogen and sulfur donor atoms on the properties of copper(II/I)-macrocyclic polyamino polythiaether ligand complexes: redox potentials and protonation and stability constants of CuIL species and new structural data , 1992 .

[65]  P. Moore,et al.  Studies of pendant-arm macrocyclic ligands. Part 5. Synthesis of two pyridine-containing penta-aza macrocycles with single pyrrolidinyl pendant arms and characterisation of their nickel(II) and copper(II) complexes. Crystal structure of perchlorato{7-[2′-(1″-pyrrolidinyl)ethyl]-3,7,11,17-tetra-azabi , 1987 .

[66]  P. Moore,et al.  Studies of pendant-arm macrocyclic ligands. Part 1. Synthesis of two new penta-aza ligands, and observation of pH-dependent reversible equilibria between trigonal-bipyramidal and square-planar forms of their nickel(II) and copper(II) complexes. Crystal structure of a trigonal-bipyramidal nickel(II) , 1984 .

[67]  G. H. Searle,et al.  Improved Richman-Atkins syntheses of cyclic polyamines particularly 1,4,7-triazacyclononane (tacn) and 1,4,7-triazacyclodecane (tacd), with the aid of cation-exchange in purification and isolation , 1984 .

[68]  A. W. Addison,et al.  Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorate , 1984 .

[69]  H. Gray,et al.  Spectroscopic studies of stellacyanin, plastocyanin, and azurin. Electronic structure of the blue copper sites , 1980 .

[70]  F. S. Stephens,et al.  Metal compounds of tetra-amines with terminal pyridyl residues. Crystal and molecular structures of [M(C15H20N4)](ClO4)2 {M = Pd, Cu} , 1980 .

[71]  E. Mckenzie,et al.  Crystal and molecular structure of a solvate of chloro-[1,6-bis-(2′-pyridyl)-2,5-diazahexane]copper(II) chloride , 1973 .

[72]  B. Hathaway The evidence for “out-of-the-plane” bonding in axial complexes of the copper(II) ion , 1973 .

[73]  N. A. Bailey,et al.  Crystal and molecular structures of two crystalline forms of isothiocyanato-[1,7-bis-(2-pyridyl)-2,6-diazaheptane]copper(II) thiocyanate , 1972 .

[74]  J. G. Gibson,et al.  Steric constraints in facultative ligands. The stereochemistry of cobalt(III), nickel(II), copper(II), and palladium(II) compounds of two homologous tetra-amines with terminal pyridyl residues , 1971 .

[75]  A. T. Casey,et al.  Polyamine ligands. III. Five-coordinate complexes with the quinquedentate N,N,N'-Tris[2-(2'-pyridyl)ethylethylenediamine , 1971 .

[76]  C. R. Thompson,et al.  Polyamine ligands. I. The stereochemistry of transition metal complexes with the ligand 1,8-Bis(2'-pyridyl)-3,6-diazaoctane , 1970 .

[77]  Stuart A. Rice,et al.  Inorganic Electronic Spectroscopy , 1968 .