论文信息 - Di-tert-butylchlorido(pyrrolidine-1-dithiocarboxylato-κ2 S,S′)tin(IV)

Di-tert-butylchlorido(pyrrolidine-1-dithiocarboxylato-κ2 S,S′)tin(IV)

The title compound, [Sn(C4H9)2(C5H8NS2)Cl], contains two molecules in the asymmetric unit, with similar conformations. In both molecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithiocarbamate ligand, with one Sn—S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites.

Weijie Wang | William T. A. Harrison | Yanping Feng | Fahui Li | Yantuan Li

[1] Masao Kakudo,et al. The Crystal and Molecular Structure of Dimethyltin Chloride N , N -Dimethyldithiocarbamate , 1970 .

[2] Edward R. T. Tiekink,et al. CRYSTAL AND MOLECULAR STRUCTURES OF DIPHENYLTIN(IV) BIS(N, N-DICYCLOHEXYLDITHIOCARBAMATE) AND DIPHENYLTIN(IV) BIS(N-CYCLOHEXYL, N-ETHYLDITHIOCARBAMATE) , 1995 .

[3] Seik Weng Ng,et al. Six-coordinate tin in a dialkylchlorooxinatotin(IV) complex: skew-trapezoidal bipyramidal bis(2-carbomethoxyethyl)chloro(quinolin-8-olato)tin(IV) , 1989 .

[4] G. G. Stokes. "J." , 1890, The New Yale Book of Quotations.

[5] Louis J. Farrugia,et al. ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[6] Olga Kennard,et al. Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds , 1987 .