Chloride-induced corrosion resistance of high-strength stainless steels in simulated alkaline and carbonated concrete pore solutions

Abstract This paper presents the results of a study examining the Cl − induced corrosion resistance of austenitic, duplex, and martensitic high-strength stainless steels (HSSSs) and a pearlitic prestressing steel using cyclic potentiodynamic polarization (CPP) techniques in simulated alkaline and carbonated concrete solutions. CPP testing found that in alkaline solutions, all HSSSs showed high corrosion resistance at Cl − concentrations from zero to 0.25 M. When exposed to carbonated solutions, corrosion resistance was reduced and only duplex grades S32205 and S32304 exhibited high corrosion resistance. A strong correlation between microstructural defects (e.g., strain-induced martensite) and corrosion damage was observed in the cold-drawn HSSSs.

[1]  Carolyn M. Hansson,et al.  Reinforcing steel passivation in mortar and pore solution , 2007 .

[2]  H. M. Otte,et al.  The martensite transformation in stainless steel , 1963 .

[3]  Gareth K. Glass,et al.  Making reinforced concrete immune from chloride corrosion , 2007 .

[4]  Depassivation of steel reinforcement in case of pitting corrosion: detection techniques for laboratory studies , 2009 .

[5]  W. Tsai,et al.  A study of the selective dissolution behavior of duplex stainless steel by micro-electrochemical technique , 2005 .

[6]  D. Cook Strain induced martensite formation in stainless steel , 1987 .

[7]  A. Sagüés,et al.  Chloride Corrosion Threshold of Reinforcing Steel in Alkaline Solutions—Cyclic Polarization Behavior , 2002 .

[8]  Taiji Suzuki,et al.  An experimental study of the martensite nucleation and growth in 18/8 stainless steel , 1977 .

[9]  Brian Cherry,et al.  Pitting, crevice and stress corrosion cracking studies of cold drawn eutectoid steels , 1980 .

[10]  Denny A. Jones Principles and prevention of corrosion , 1991 .

[11]  Y. Wu,et al.  Corrosion‐technical properties of high‐strength stainless steels for the application in prestressed concrete structures , 2009 .

[12]  Raghuvir Singh,et al.  Influence of Cold-Worked Structure on Electrochemical Properties of Austenitic Stainless Steels , 2007 .

[13]  Preet M. Singh,et al.  Chloride-Induced Corrosion of Prestressing Steels Considering Crevice Effects and Surface Imperfections , 2011 .

[14]  David B. McDonald,et al.  Stainless steel reinforcing as corrosion protection , 1995 .

[15]  R. C. Newman,et al.  2001 W.R. Whitney Award Lecture: Understanding the Corrosion of Stainless Steel , 2001 .

[16]  Preet M. Singh,et al.  Effect of Heat Treatment on Corrosion and Stress Corrosion Cracking of S32205 Duplex Stainless Steel in Caustic Solution , 2009 .

[17]  William H. Hartt,et al.  A CRITICAL LITERATURE REVIEW OF HIGH-PERFORMANCE CORROSION REINFORCEMENTS IN CONCRETE BRIDGE APPLICATIONS , 2004 .

[18]  N. Birbilis,et al.  Effect of Processing on Grain Size and Corrosion of AA2024-T3 , 2011 .

[19]  F. Velasco,et al.  Corrosion behaviour of corrugated lean duplex stainless steels in simulated concrete pore solutions , 2011 .

[20]  Edward G. Nawy,et al.  Prestressed Concrete: A Fundamental Approach , 1989 .

[21]  J. Pan,et al.  In situ study of selective dissolution of duplex stainless steel 2205 by electrochemical scanning tunnelling microscopy , 2001 .

[22]  J. Simmons,et al.  Overview: high-nitrogen alloying of stainless steels , 1996 .

[23]  H. Abreu,et al.  Microstructural changes produced by plastic deformation in the UNS S31803 duplex stainless steel , 2006 .

[24]  R. Newman,et al.  The mechanism of lacy cover formation in pitting , 1997 .

[25]  J. F. Jenkins Validation of Nitronic 33 in Reinforced and Prestressed Concrete. , 1987 .

[26]  N. S. Rengaswamy,et al.  RELATIONSHIP BETWEEN CHLORIDE/HYDROXIDE RATIO AND CORROSION RATE OF STEEL IN CONCRETE , 1998 .

[27]  V. Gavriljuk,et al.  Concept of a new high-strength austenitic stainless steel , 2002 .

[28]  P. Ernst,et al.  Pit growth studies in stainless steel foils. I. Introduction and pit growth kinetics , 2002 .

[29]  S. Baldo,et al.  Effect of cold rolling on microstructure and magnetic properties in a metastable lean duplex stainless steel , 2010 .

[30]  C. L. Page,et al.  Pore solution composition and chloride binding capacity of silica-fume cement pastes , 1983 .

[31]  G. Duffó,et al.  Corrosion of reinforcing steel in simulated concrete pore solutions: Effect of carbonation and chloride content , 2004 .

[32]  H. M. Laylor,et al.  Corrosion prevention and remediation strategies for reinforced concrete coastal bridges , 2002 .

[33]  C. L. Page,et al.  Initiation of chloride‐induced corrosion of steel in concrete: role of the interfacial zone , 2009 .

[34]  B. Elsener,et al.  Stainless steel reinforcing bars – reason for their high pitting corrosion resistance , 2011 .

[35]  Luca Bertolini,et al.  Behaviour of stainless steel in simulated concrete pore solution , 1996 .

[36]  J. Scully,et al.  Threshold Chloride Concentrations of Selected Corrosion-Resistant Rebar Materials Compared to Carbon Steel , 2006 .