Cross-coupling reactions using samarium(II) iodide.

[1]  G. Molander,et al.  Samarium(II) Iodide-Mediated Intramolecular Conjugate Additions of α,β-Unsaturated Lactones , 2002 .

[2]  S. Hanessian,et al.  The stereocontrolled formation of cyclic vicinal cis-diols via a samarium diiodide pinacol coupling of dialdehydes , 1991 .

[3]  H. Koshino,et al.  Synthetic studies on maitotoxin. 3. Stereoselective synthesis of the BCDE-ring system. , 2008, Organic letters.

[4]  H. Ohno,et al.  Radical cyclization by ipso substitution of the methoxy group: considerable effect of HMPA on samarium-mediated cyclization. , 2003, The Journal of organic chemistry.

[5]  Pei‐Qiang Huang,et al.  A new method for the construction of the hydroxylated tropane skeleton: enantioselective synthesis of (-)-Bao Gong Teng A. , 2011, Chemical communications.

[6]  G. Solladié,et al.  Reformatsky-Type Reaction of Chiral Nonracemic α-Bromo-α‘-sulfinyl Ketones with Aldehydes. Synthesis of Enantiomerically Pure 2-Methyl-1,3-diol Moieties , 2003 .

[7]  N. Kanomata,et al.  Synthesis of planar-chiral paracyclophanes via samarium(II)-catalyzed intramolecular pinacol coupling. , 2005, Organic letters.

[8]  Y. Tu,et al.  Total synthesis of (±)-alopecuridine and its biomimetic transformation into (±)-sieboldine A. , 2011, Angewandte Chemie.

[9]  M. Tori,et al.  CARBON-CARBON BOND FORMATION BETWEEN ENONE AND ESTER CARBONYL GROUP INDUCED BY SAMARIUM DIIODIDE , 2008 .

[10]  H. Matsubara,et al.  Selective reductions of cyclic 1,3-diesters by using SmI(2) and H(2)O. , 2010, Chemistry.

[11]  A. Kakehi,,et al.  SmI2-promoted Reformatsky-type reaction and acylation of alkyl 1-chlorocyclopropanecarboxylates. , 2008, Organic letters.

[12]  Sarah E Reisman,et al.  A unified strategy to ent-kauranoid natural products: total syntheses of (-)-trichorabdal A and (-)-longikaurin E. , 2013, Journal of the American Chemical Society.

[13]  T. Nakata,et al.  Stereoselective syntheses of the C'D'E'F'-ring system of maitotoxin and the FG-ring system of gambierol. , 2001, Organic letters.

[14]  M. Hursthouse,et al.  Samarium diiodide mediated 6-exo cyclisations of methylenecyclopropyl ketones , 2004 .

[15]  A. Dahlén,et al.  Chelating alcohols accelerate the samarium diiodide mediated reduction of 3-heptanone , 2001 .

[16]  M. Tori,et al.  Samarium(II) Iodide-mediated Intramolecular Aldol-Type Cyclization , 2001 .

[17]  F. Matsuda,et al.  Efficient medium-ring cyclization under non-high-dilution conditions using SmI 2. , 2004, Organic letters.

[18]  Jian-Liang Ye,et al.  Samarium diiodide promoted generation and asymmetric hydroxyalkylation of N,O-diprotected (3S)-3-pyrrolidinol 2-carbanions. , 2005, Organic letters.

[19]  D. Procter,et al.  The remarkable effect of cosolvent on a samarium(II)-mediated 4-exo-trig cyclization: further synthetic studies on pestalotiopsin A. , 2003, The Journal of organic chemistry.

[20]  E. Prasad,et al.  Photoinduced electron transfer from Eu(II)-complexes to organic molecules: Rate and mechanistic investigation , 2014 .

[21]  Jan Streuff.  The Electron-Way: Metal-Catalyzed Reductive Umpolung Reactions of Saturated and α,β-Unsaturated Carbonyl Derivatives , 2013 .

[22]  T. Ankner,et al.  Instantaneous SmI2/H2O/amine mediated reduction of nitroalkanes and α,β-unsaturated nitroalkenes , 2007 .

[23]  D. Ma,et al.  Total synthesis of the indole alkaloid (±)- and (+)-methyl N-decarbomethoxychanofruticosinate. , 2013, Angewandte Chemie.

[24]  G. Molander,et al.  Conjugate Addition Reactions Mediated by Samarium(II) Iodide. , 1997, The Journal of organic chemistry.

[25]  L. Morss.  Thermochemical properties of yttrium, lanthanum, and the lanthanide elements and ions , 1976 .

[26]  J. A. Grant,et al.  Characterization of the complex formed between samarium diiodide and the dehydro dimer of HMPA (diHMPA) , 2009 .

[27]  J. Inanaga,et al.  Carbon-carbon bond formation by intermolecular radical reaction. Sml2-promoted carbonyl-alkyne reductive coupling , 1991 .

[28]  T. Heightman,et al.  Application of an ephedrine chiral linker in a solid-phase, 'asymmetric catch-release' approach to gamma-butyrolactones. , 2003, Chemical communications.

[29]  T. Endo,et al.  SAMARIUM IODIDE-CATALYZED PINACOL COUPLING OF CARBONYL COMPOUNDS , 1996 .

[30]  P. Andreasen,et al.  Synthesis of a hydroxyethylene isostere of the tripeptide Arg-Gly-Leu via a convergent acyl-like radical addition strategy. , 2005, The Journal of organic chemistry.

[31]  J. Concellón,et al.  Highly Selective Reaction of α-Halo-α,β-unsaturated Esters with Ketones or Aldehydes Promoted by SmI2: An Efficient Alternative Access to Baylis−Hillman Adducts , 2005 .

[32]  H. Reissig,et al.  Towards the core structure of Strychnos alkaloids using samarium diiodide-induced reactions of indole derivatives. , 2013, Chemistry.

[33]  T. Heightman,et al.  Development of a solid-phase 'asymmetric resin-capture-release' process: application of an ephedrine chiral resin in an approach to gamma-butyrolactones. , 2004, Organic & biomolecular chemistry.

[34]  M. Szostak,et al.  Selective synthesis of 3-hydroxy acids from Meldrum's acids using SmI2-H2O , 2012, Nature Protocols.

[35]  D. Sherman,et al.  Synthesis of Triketide δ-Lactones , 2001 .

[36]  Phil S. Baran,et al.  The economies of synthesis. , 2009, Chemical Society reviews.

[37]  R. Linhardt,et al.  Chemoenzymatic synthesis of neuraminic acid containing C-glycoside polymers. , 2003, Organic letters.

[38]  T. Nakata,et al.  Synthesis of Cyclic Ether via Intramolecular Acyloin Condensation , 2006 .

[39]  K. Nicolaou,et al.  The true structures of the vannusals, part 2: Total synthesis and revised structure of vannusal B. , 2009, Angewandte Chemie.

[40]  H. Kagan,et al.  Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents , 1980 .

[41]  C. Yeung,et al.  Catalytic dehydrogenative cross-coupling: forming carbon-carbon bonds by oxidizing two carbon-hydrogen bonds. , 2011, Chemical reviews.

[42]  A. Lei,et al.  Bond formations between two nucleophiles: transition metal catalyzed oxidative cross-coupling reactions. , 2011, Chemical reviews.

[43]  G. Molander,et al.  Construction of bicyclic ring systems via a transannular SmI2-mediated ketone-olefin cyclization strategy. , 2007, The Journal of organic chemistry.

[44]  E. Prasad,et al.  Mechanistic Study of β-Substituent Effects on the Mechanism of Ketone Reduction by SmI2 , 2002 .

[45]  B. Pagenkopf,et al.  Synthesis of tetrahydroisoquinocarbazoles via C-2 alkylation of indoles with 2-alkoxycyclopropanoate esters. , 2009, Organic letters.

[46]  T. Hirao,et al.  Photoinduced Reduction and Carbonylation of Organic Chlorides with Samarium Diiodide , 1997 .

[47]  Jian-Liang Ye,et al.  Enantiodivergent synthesis of trans-3,4-disubstituted succinimides by SmI2-mediated Reformatsky-type reaction , 2008 .

[48]  J. E. Oltra,et al.  Cp2TiCl in Natural Product Synthesis , 2006 .

[49]  M. Tori,et al.  The stereochemistry of electrolysis and samarium diiodide-induced cyclization between carbonyl and enone system in inter-and intramolecular coupling , 2007 .

[50]  M. Okue,et al.  Samarium(II) iodide-induced tandem reductive coupling-Dieckmann condensation reaction: one-step synthesis of bicyclic oxacyclopentanecarboxylate from bis-α,β-unsaturated esters , 2003 .

[51]  Carmen Concellón,et al.  Sequential synthesis of (E)-alpha,beta-unsaturated primary amides with complete stereoselectivity. , 2010, The Journal of organic chemistry.

[52]  M. Tori,et al.  Cyclization into perhydronaphthalenones using samarium diiodide , 2003 .

[53]  Yuanchao Li,et al.  Synthesis of 7-substituted-5-androstene derivatives promoted by SmI2 , 2006, Steroids.

[54]  Pei‐Qiang Huang,et al.  SmI2-mediated intermolecular coupling of γ-lactam N-α-radicals with activated alkenes: asymmetric synthesis of 11-hydroxylated analogues of the lead compounds CP-734432 and PF-04475270. , 2013, The Journal of organic chemistry.

[55]  Songlin Zhang,et al.  Applications of allylsamarium bromide as a grignard reagent and a single-electron transfer reagent in the one-pot synthesis of dienes and trienes. , 2010, Chemistry.

[56]  H. Yoda,et al.  SmI2-promoted tandem desulfurization and reductive coupling reactions of aromatic lactams with carbonyl compounds , 2001 .

[57]  M. Szostak,et al.  Highly Chemoselective Reduction of Amides (Primary, Secondary, Tertiary) to Alcohols using SmI2/Amine/H2O under Mild Conditions , 2014, Journal of the American Chemical Society.

[58]  M. Helliwell,et al.  SmI2-mediated dialdehyde 'radical then aldol' cyclization cascades: a feasibility study , 2009 .

[59]  G. Molander,et al.  Total synthesis of (+)-isoschizandrin utilizing a samarium(II) iodide-promoted 8-endo ketyl-olefin cyclization. , 2003, The Journal of organic chemistry.

[60]  T. Skrydstrup,et al.  Expanding the scope of the acyl-type radical addition reactions promoted by SmI2. , 2006, The Journal of organic chemistry.

[61]  Jason T. Lowe,et al.  Total synthesis of (-)-kendomycin. , 2008, Organic letters.

[62]  S. Py,et al.  First asymmetric SmI2-induced cross-coupling of Cr(CO)3 aromatic nitrone complexes with carbonyl compounds. , 2004, Chemical communications.

[63]  E. Prasad,et al.  Solvation-controlled luminescence of SmII complexes. , 2007, Angewandte Chemie.

[64]  Jaehwan Lee,et al.  A stereo-controlled synthesis of 2,4-dimethyl-4-hydroxy-16-phenylhexadecanoic acid 1,4-lactone and its PPAR activities. , 2010, Bioorganic & medicinal chemistry letters.

[65]  G. Molander,et al.  Lanthanides in organic synthesis. 8. 1.3-Asymmetric induction in intramolecular Reformatskii-type reactions promoted by samarium diiodide , 1987 .

[66]  H. Ohno,et al.  Samarium(II)-mediated spirocyclization by intramolecular aryl radical addition onto an aromatic ring. , 2008, The Journal of organic chemistry.

[67]  J. Inanaga,et al.  An efficient intermolecular carbon-carbon bond formation via SmI2-promoted anion radical alkylation , 1989 .

[68]  K. Nicolaou,et al.  Total synthesis of the originally assigned structure of vannusal B. , 2008, Angewandte Chemie.

[69]  J. Tanko,et al.  Cyclopropylcarbinyl-type ring openings. Reconciling the chemistry of neutral radicals and radical anions. , 2002, Journal of the American Chemical Society.

[70]  David R. Williams,et al.  Studies of neodolastanes — Synthesis of the tricyclic core of the trichoaurantianolides , 2013 .

[71]  D. Williams,et al.  FRAGMENTATION AND CLEAVAGE REACTIONS MEDIATED BY SAMARIUM IODIDE. PART 2: α- AND β-ELIMINATION REACTIONS OF C-X SUBSTRATES , 2003 .

[72]  Bing Wang,et al.  SmI2-promoted intramolecular asymmetric pinacol-type ketone-tert-butanesulfinyl imine reductive coupling: stereoselectivity and mechanism. , 2009, Organic letters.

[73]  G. Solladié,et al.  A New Access to Enantiopure syn- and anti-2-Methyl-1,3-diol Moieties from Chiral Nonracemic α-Bromo α′-Sulfinyl Ketones Promoted by Samarium Diiodide , 2006 .

[74]  M. Szostak,et al.  Uncovering the Importance of Proton Donors in TmI2-Promoted Electron Transfer: Facile C−N Bond Cleavage in Unactivated Amides** , 2013, Angewandte Chemie.

[75]  Carmen Concellón,et al.  Aldol-type reactions of unmasked iodoacetic acid with carbonyl compounds promoted by samarium diiodide: efficient synthesis of carboxylic 3-hydroxyacids and their derivatives. , 2006, The Journal of organic chemistry.

[76]  J. Fang,et al.  Synthesis of ferrocenyl alkenes, dienes, and enynes via samarium diiodide promoted tandem addition and dehydration of ferrocenyl carbonyls with halides. , 2001, The Journal of organic chemistry.

[77]  Pei‐Qiang Huang,et al.  Samarium diiodide-mediated reductive couplings of chiral nitrones with aldehydes/ketones and acyl chlorides , 2010 .

[78]  E. Prasad,et al.  Effect of crown ethers on the ground and excited state reactivity of samarium diiodide in acetonitrile. , 2012, The journal of physical chemistry. A.

[79]  Chriss E McDonald,et al.  Tripyrrolidinophosphoric acid triamide as an activator in samarium diiodide reductions. , 2010, Organic letters.

[80]  Raffaella Faraoni,et al.  Total synthesis and structural revision of vannusals A and B: synthesis of the originally assigned structure of vannusal B. , 2010, Journal of the American Chemical Society.

[81]  D. Jean,et al.  Development of a tandem cyclization mediated by samarium(II) iodide: sequential intramolecular conjugate addition/nucleophilic acyl substitution , 2006 .

[82]  H. Matsuzawa,et al.  Asymmetric Samarium-Reformatsky Reaction of Chiral α-Bromoacetyl-2-oxazolidinones with Aldehydes , 2000 .

[83]  H. Matsubara,et al.  Selective reductions of cyclic 1,3-diesters using SmI(2) and H(2)O. , 2009, Journal of the American Chemical Society.

[84]  H. Reissig,et al.  Pentacyclic Compounds by Samarium Diiodide‐Induced Cascade Cyclizations of Naphthyl‐Substituted 1,3‐Diones , 2008 .

[85]  Zhen Yang,et al.  A concise approach for the total synthesis of pseudolaric acid A. , 2011, Organic letters.

[86]  S. Schulz,et al.  Synthesis of β-hydroxy-δ-trichloromethyl-δ-valerolactones by intramolecular samarium/ytterbium diiodide-mediated Reformatsky reaction , 2013 .

[87]  M. Szostak,et al.  Electron transfer reduction of unactivated esters using SmI2-H2O. , 2011, Chemical communications.

[88]  Yasuyuki Ogawa,et al.  Highly Stereoselective Samarium(II) Iodide-Mediated Aldol Reactions of Acylaziridines with Aldehydes , 2005 .

[89]  Kiyoshi Sato,et al.  The synthesis of new azoniathiahelicenes , 2006 .

[90]  A. Otaka,et al.  Synthesis of (Z)-alkene-containing cis-proline dipeptide mimetics using samarium(II) diiodide (SmI2)-mediated reductive alkylation reaction , 2007 .

[91]  Å. Nilsson,et al.  Estimating the limiting reducing power of SmI2/H2O/amine and YbI2/H2O/amine by efficient reduction of unsaturated hydrocarbons. , 2006, The Journal of organic chemistry.

[92]  A. Tarnopolsky,et al.  Reductions with SmI2: mechanistic probe for distinguishing between two operational modes of proton transfer. , 2007, Organic & biomolecular chemistry.

[93]  N. Allen,et al.  Ketone Coupling with Alkyl Iodides, Bromides, and Chlorides Using Thulium Diiodide: A More Powerful Version of SmI2(THF)x/HMPA , 2000 .

[94]  K. Tempest,et al.  A convenient pathway to Sm(II)-mediated chemistry in acetonitrile. , 2011, Organic & biomolecular chemistry.

[95]  S. Py,et al.  SmI2-mediated cross-coupling of nitrones with β-silyl acrylates: synthesis of (+)-australine. , 2012, Organic letters.

[96]  J. Kilburn,et al.  Diastereoselective SmI2 mediated cascade radical cyclisations of methylenecyclopropane derivatives—syntheses of paeonilactone B and 6-epi-paeonilactone A , 2001 .

[97]  K. Nicolaou,et al.  Total synthesis and biological evaluation of monorhizopodin and 16-epi-monorhizopodin. , 2011, Angewandte Chemie.

[98]  M. Tori,et al.  Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis , 2012, Molecules.

[99]  T. Skrydstrup.  New Sequential Reactions with Single‐Electron‐Donating Agents , 1997 .

[100]  Carmen Concellón,et al.  Synthesis of E-α,β-Unsaturated Ketones with Complete Stereoselectivity via Sequential Aldol-Type/Elimination Reactions Promoted by Samarium ­Diiodide or Chromium Dichloride , 2006 .

[101]  F. Nief.  Non-classical divalent lanthanide complexes. , 2010, Dalton transactions.

[102]  D. Bandyopadhyay,et al.  An entry to the synthesis of novel nitrogen macroheterocycles , 2007 .

[103]  K. Baldridge,et al.  Through-space interactions between face-to-face, center-to-edge oriented arenes: importance of polar-pi effects. , 2003, Organic & biomolecular chemistry.

[104]  Keisuke Suzuki,et al.  General synthesis route to benanomicin-pradimicin antibiotics. , 2007, Chemistry.

[105]  T. Skrydstrup,et al.  SmI2 reduced thioesters as synthons of unstable acyl radicals: direct synthesis of potential protease inhibitors via intermolecular radical addition. , 2003, Journal of the American Chemical Society.

[106]  Yasuyuki Ogawa,et al.  Stereoselective synthesis of δ-amino-β'-hydroxy-β,γ-unsaturated esters by the samarium(II) iodide-mediated aldol reaction of aldehydes with γ,δ-aziridiny-α,β-unsaturated esters , 2005 .

[107]  D. Davies,et al.  A stereoselective, Sm(II)-mediated approach to decorated cis-hydrindanes: synthetic studies on faurinone and pleuromutilin. , 2011, Organic & biomolecular chemistry.

[108]  J. Concellón,et al.  Sequential elimination-reduction reactions promoted by samarium diiodide: synthesis of 2,3-dideuterioesters or -amides. , 2001, Chemistry.

[109]  I. Bilkis,et al.  Reactions of SmI2 with Olefins: Mechanism and Complexation Effect on Chemoselectivity , 1996 .

[110]  Thomas M. Baker,et al.  Synthesis and reactions of the pestalotiopsin skeleton. , 2008, Angewandte Chemie.

[111]  Han Gang,et al.  Samarium(II) Iodide-Promoted Vinylogous Intramolecular Nucleophilic Acyl Substitution Reactions of $\beta$-Alkoxyacrylates , 2001 .

[112]  S. Py,et al.  Synthesis and Structural Characterization of Planar Chiral Cr(CO)3‐Complexed Aromatic Nitrones – Valuable Substrates for Asymmetric SmI2‐Induced Coupling Reactions , 2010 .

[113]  J. Kilburn,et al.  Diastereoselective SmI2-mediated cascade radical cyclisations of methylenecyclopropane derivatives—a synthesis of paeonilactone B , 1998 .

[114]  M. Ferjani,et al.  Synthesis of vinylcyclopentanes via samarium(II) mediated tandem reactions , 2004 .

[115]  S. Halder,et al.  Hydroxylated HMPA enhances both reduction potential and proton donation in SmI₂ reactions. , 2014, The Journal of organic chemistry.

[116]  F. Colobert,et al.  SmI2-coupling reaction of chiral non-racemic α-bromo-α′-sulfinyl ketones with imines: synthesis of enantiomerically pure 2-methyl-3-amino-1-ol moieties , 2009 .

[117]  Xiang Zhou,et al.  A versatile approach to pyrrolidine azasugars and homoazasugars based on a highly diastereoselective reductive benzyloxymethylation of protected tartarimide , 2007 .

[118]  Takashi Matsumoto,et al.  Tandem ring expansion of alkenyl benzocyclobutenol derivatives into substituted naphthols. , 2006, Angewandte Chemie.

[119]  G. O'Neil,et al.  Chemoselective samarium-mediated benzoyloxysulfone eliminations. , 2011, The Journal of organic chemistry.

[120]  E. Prasad,et al.  Exploring SmBr2-, SmI2-, and YbI2-mediated reactions assisted by microwave irradiation. , 2005, Chemistry.

[121]  David R. Williams,et al.  Samarium Barbier reactions of alpha-iodomethyloxazoles and thiazoles with aliphatic aldehydes. , 2005, Organic letters.

[122]  S. Agarwal,et al.  Diiodosamarium based polymerisations , 2002 .

[123]  D. Otzen,et al.  Synthesis of a ketomethylene isostere of the fibrillating peptide SNNFGAILSS. , 2009, The Journal of organic chemistry.

[124]  Tzuen-Yeuan Lin,et al.  Rate Study of Haloadamantane Reduction by Samarium Diiodide , 2002 .

[125]  A. Dahlén,et al.  Instantaneous SmI2–H2O-mediated reduction of dialkyl ketones induced by amines in THF , 2002 .

[126]  K. Daasbjerg,et al.  Mechanistic evidence for intermolecular radical carbonyl additions promoted by samarium diiodide. , 2006, Journal of the American Chemical Society.

[127]  T. Kinoshita,et al.  SmI2-Mediated Reduction of γ,γ-Difluoro-α,β-enoates with Application to the Synthesis of Functionalized (Z)-Fluoroalkene-Type Dipeptide Isosteres , 2004 .

[128]  Yonghong Deng,et al.  Preparation of a 24-nor-1,4-dien-3-one triterpene derivative from betulin: a new route to 24-nortriterpene analogues. , 2002, The Journal of organic chemistry.

[129]  P. Steel.  Recent developments in lanthanide mediated organic synthesis , 2001 .

[130]  H. Reissig,et al.  Replacement of HMPA in Samarium Diiodide Promoted Cyclizations and Reactions of Organolithium Compounds , 2012 .

[131]  H. Takayama,et al.  Asymmetric total syntheses of two phlegmarine-type alkaloids, lycoposerramines-V and -W, newly isolated from Lycopodium serratum. , 2007, Organic letters.

[132]  K. Luthman,et al.  KHMDS enhanced SmI(2)-mediated reformatsky type alpha-cyanation. , 2010, Organic letters.

[133]  S. Hoz,et al.  On the role of samarium/HMPA in the post electron-transfer steps in SmI2 reductions. , 2008, Organic letters.

[134]  M. Szostak,et al.  Stereoselective capture of N-acyliminium ions generated from α-hydroxy-N-acylcarbamides: direct synthesis of uracils from barbituric acids enabled by SmI2 reduction. , 2014, Organic letters.

[135]  D. Procter,et al.  A Samarium(II)-mediated, stereoselective cyclization for the synthesis of azaspirocycles. , 2008, Organic letters.

[136]  T. Skrydstrup,et al.  Synthesis of the C-linked disaccharide alpha-D-Man-(1-->4)-D-Man employing a SmI(2)-mediated C-glycosylation step: en route to cyclic C-oligosaccharides. , 2003, The Journal of organic chemistry.

[137]  G. Maestri,et al.  The Cyanamide Moiety, Synthesis and Reactivity , 2012 .

[138]  J. G. Urones,et al.  Synthesis of (+)-totarol , 2003 .

[139]  F. Guibé,et al.  Investigation of SmI2-mediated cyclisation of δ-iodo-α,β-unsaturated esters by deuterium 2D NMR in oriented solvents , 2002 .

[140]  M. Szostak,et al.  Beyond samarium diiodide: vistas in reductive chemistry mediated by lanthanides(II). , 2012, Angewandte Chemie.

[141]  T. Fujinami,et al.  Reductive coupling of ketones or aldehydes with electron-deficient alkenes promoted by samarium di-iodide , 1986 .

[142]  R. A. Flowers,et al.  Uncovering the mechanistic role of HMPA in the samarium Barbier reaction. , 2010, Journal of the American Chemical Society.

[143]  A. Tarnopolsky,et al.  Reduction of benzophenone by SmI2: the role of proton donors in determining product distribution. , 2005, Organic letters.

[144]  J. Beau,et al.  An Expeditious Synthesis of N‐Acetylneuraminic Acid α‐C‐Glycosyl Derivatives (“α‐C‐Glycosides”) from the Anomeric Acetates , 2007 .

[145]  Enemaerke,et al.  Evidence for ionic samarium(II) species in THF/HMPA solution and investigation of their electron-donating properties , 2000, Chemistry.

[146]  T. Honda,et al.  Efficient total synthesis of (-)-stemoamide. , 2011, Organic & biomolecular chemistry.

[147]  B. Schiøtt,et al.  Importance of C-N bond rotation in N-acyl oxazolidinones in their SmI2-promoted coupling to acrylamides. , 2009, Journal of the American Chemical Society.

[148]  P. Renaud,et al.  Radicals in Organic Synthesis , 2001 .

[149]  F. Diederich,et al.  Book review: Metal-catalyzed cross-coupling reactions. F. Diederich and P. J. Stang (eds) Wiley–VCH, Weinheim, 1998. xxi + 517 pages, £85 ISBN 3–527–29421–X , 1998 .

[150]  P. Tuchinda,et al.  Samarium dienolate mediated stereoselective synthesis of anti-1,3-diol monoesters via aldol-Tishchenko reaction , 2006 .

[151]  H. Reissig,et al.  Samarium diiodide induced ketyl-(het)arene cyclisations towards novel N-heterocycles. , 2011, Chemical Society reviews.

[152]  M. N. Bochkarev,et al.  A chemical definition of the effective reducing power of thulium(II) diiodide by its reactions with cyclic unsaturated hydrocarbons. , 2001, Chemistry.

[153]  D. Curran,et al.  Samarium(II) iodide mediated radical/polar crossover reactions of cyclobutenes. An efficient approach to the BCD ring system of the penitrems. , 2003, Organic letters.

[154]  H. Matsubara,et al.  Lactone radical cyclizations and cyclization cascades mediated by SmI2-H2O. , 2012, Journal of the American Chemical Society.

[155]  S. Py,et al.  1-(2,4,6-Triisopropylphenyl)ethylamine: A New Chiral Auxiliary for the Asymmetric Synthesis of γ-Amino Acid Derivatives , 2007 .

[156]  H. Schmalz,et al.  Radical cyclization of η6-arene-Cr(CO)3 complexes: A regio- and stereoselective entry to functionalized pseudopterosin precursors , 1996 .

[157]  Jian-Liang Ye,et al.  Concise asymmetric total synthesis of 9-epi-sessilifoliamide J. , 2011, Organic letters.

[158]  S. Handy,et al.  The intramolecular reductive cyclization of cyclic enones , 2007 .

[159]  E. Prasad,et al.  Mechanistic impact of water addition to SmI2: consequences in the ground and transition state. , 2005, Journal of the American Chemical Society.

[160]  D. Urabe,et al.  Symmetry-driven synthesis of 9-demethyl-10,15-dideoxyryanodol , 2013 .

[161]  E. Negishi.  Handbook of organopalladium chemistry for organic synthesis , 2002 .

[162]  D. Hockless,et al.  Chemoenzymatic total syntheses of the sesquiterpene (-)-patchoulenone , 2003 .

[163]  K. Pudhom,et al.  A New and Convenient Method for the Preparation of Cyclooctanone Containing Bis-Aldol Skeleton by Samarium(II) Iodide-mediated Intramolecular Aldol Cyclization of ω-Oxiranyl Keto Octanal , 2002 .

[164]  T. Nakata,et al.  SmI2-induced reductive cyclization of optically active β-alkoxyvinyl sulfoxides with aldehyde , 2007 .

[165]  L. Maron,et al.  Preliminary Theoretical Insights into SmI2-Mediated Reactions: Activation of Ketones in THF , 2013 .

[166]  A. Nomoto,et al.  On the potentially excellent reducing ability of a series of low-valent rare earths induced by photoirradiation , 2009 .

[167]  T. Skrydstrup,et al.  Organic Synthesis using Samarium Diiodide: A Practical Guide , 2010 .

[168]  E. Prasad,et al.  The role of ligand displacement in SmII-HMPA-based reductions. , 2004, Journal of the American Chemical Society.

[169]  E. Prasad,et al.  Investigation of the [Sm(N(SiMe(3))(2))(2)] reducing system in THF. Rate and mechanistic studies. , 2002, Journal of the American Chemical Society.

[170]  S. Py,et al.  Cis-stereoselective SmI2-promoted reductive coupling of keto-nitrones: first synthesis of 1-epitrehazolamine. , 2005, Organic & biomolecular chemistry.

[171]  Williams,et al.  Samarium(II) iodide promoted fragmentation and sequential reactions of aromatic 1,4-diketones , 2000, The Journal of organic chemistry.

[172]  D. Williams,et al.  FRAGMENTATION AND CLEAVAGE REACTIONS MEDIATED BY SmI2. PART 1: X-Y, X-X AND C-C SUBSTRATES , 2001 .

[173]  M. Szostak,et al.  Concise syntheses of strychnine and englerin A: the power of reductive cyclizations triggered by samarium iodide. , 2011, Angewandte Chemie.

[174]  T. Hudlický,et al.  Chemoenzymatic Formal Total Synthesis of ent‐Codeine and Other Morphinans via Nitrone Cycloadditions and/or Radical Cyclizations. Comparison of Strategies for Control of C‐9/C‐14 Stereogenic Centers , 2014 .

[175]  D. Procter,et al.  Samarium(II)-mediated linker cleavage-cyclization in fluorous synthesis: reactions of samarium enolates. , 2008, Organic letters.

[176]  Stephen K. Jackson,et al.  Mild construction of 3-methyl tetramic acids enabling a formal synthesis of palau'imide. , 2012, Organic letters.

[177]  H. Reissig,et al.  Stereoselective formation of tri- and tetracycles by samarium diiodide-induced cyclizations of naphthyl-substituted ketones. , 2004, Organic letters.

[178]  D. Poirier,et al.  Chemical synthesis and evaluation of 17α-alkylated derivatives of estradiol as inhibitors of steroid sulfatase. , 2011, European journal of medicinal chemistry.

[179]  T. Skrydstrup,et al.  Radical addition of nitrones to acrylates mediated by SmI2: asymmetric synthesis of gamma-amino acids employing carbohydrate-based chiral auxiliaries. , 2004, Chemical communications.

[180]  A. Gansäuer,et al.  Reagent-controlled transition-metal-catalyzed radical reactions. , 2000, Chemical reviews.

[181]  A. Otaka,et al.  Application of samarium diiodide (SmI2)-induced reduction of γ-acetoxy-α,β-enoates with α-specific kinetic electrophilic trapping for the synthesis of amino acid derivatives , 2003 .

[182]  H. Reissig,et al.  Samarium diiodide induced cyclizations of γ-, δ- and ε-indolyl ketones: reductive coupling, intermolecular trapping, and subsequent transformations of indolines. , 2011, Chemistry.

[183]  H. Reissig,et al.  A short formal total synthesis of strychnine with a samarium diiodide induced cascade reaction as the key step. , 2010, Angewandte Chemie.

[184]  R. Guillot,et al.  Synthesis of Spirolactonic C-Sialosides Induced by Samarium Diiodide , 2013, Synlett.

[185]  J. Shotwell,et al.  Structure and Energetics of the Samarium Diiodide-HMPA Complex in Tetrahydrofuran. , 1999, The Journal of organic chemistry.

[186]  G. Molander,et al.  Intramolecular nucleophilic acyl substitution reactions of halo-substituted esters and lactones. New applications of organosamarium reagents , 1993 .

[187]  Takashi Takahashi,et al.  One-pot, three-component coupling approach to the synthesis of α-iminocarboxamides. , 2012, Organic letters.

[188]  David R. Williams,et al.  Studies of stereocontrolled allylation reactions for the total synthesis of phorboxazole A. , 2004, Proceedings of the National Academy of Sciences of the United States of America.

[189]  J. Inanaga,et al.  SmI2-induced reductive cross-coupling of carbonyl compounds with (α,β-unsaturated esters , 1986 .

[190]  D. Procter,et al.  Samarium(II)-mediated reactions of γ,δ-unsaturated ketones. Cyclization and fragmentation processes , 2002 .

[191]  J. Concellón,et al.  Reduction of Multiple Bonds without Hydrogen or Hydride Complexes: Samarium Diiodide as a Mild Reducing Reagent , 2006 .

[192]  Yasuyuki Ogawa,et al.  Enantioselective Synthesis of C11–C17 Segment of Mycinolide IV Using Samarium(II) Iodide-mediated Aldol Reaction , 2005 .

[193]  M. Szostak,et al.  Recent advances in the chemoselective reduction of functional groups mediated by samarium(II) iodide: a single electron transfer approach. , 2013, Chemical Society reviews.

[194]  M. Szostak,et al.  Selective Reduction of Barbituric Acids Using SmI2/H2O: Synthesis, Reactivity, and Structural Analysis of Tetrahedral Adducts , 2013, Angewandte Chemie.

[195]  H. Reissig,et al.  Medium-sized carbocycles by samarium diiodide-induced carbonyl-alkene cyclizations. , 2009, Organic letters.

[196]  T. Skrydstrup,et al.  Direct entry to peptidyl ketones via SmI2-mediated C-C bond formation with readily accessible N-peptidyl oxazolidinones. , 2008, The Journal of organic chemistry.

[197]  J. T. Njardarson,et al.  Evolution of a synthetic approach to CP-263,114. , 2001, Organic letters.

[198]  Peter Blakskjaer,et al.  Further studies in the acyl-type radical additions promoted by SmI2: mechanistic implications and stereoselective reduction of the keto-functionality , 2003 .

[199]  S. Hoz,et al.  The effect of proton donors on the facial stereoselectivity in SmI2 reduction of norcamphor. , 2011, The Journal of organic chemistry.

[200]  R. W. Hoffmann,et al.  Synthesis of Pederic Acid and Related Model Studies , 2004 .

[201]  Melanie S Sanford,et al.  Palladium-catalyzed ligand-directed C-H functionalization reactions. , 2010, Chemical reviews.

[202]  Keisuke Suzuki,et al.  From Axial Chirality to Central Chiralities: Pinacol Cyclization of 2,2'-Biaryldicarbaldehyde to trans-9,10-Dihydrophenanthrene-9,10-diol. , 1999, Angewandte Chemie.

[203]  S. Hoz,et al.  The effect of replacing carbon by nitrogen in reductions with SmI2: reduction of azobenzene. , 2011, The Journal of organic chemistry.

[204]  S. Hoz,et al.  Autocatalysis and surface catalysis in the reduction of imines by SmI2. , 2011, Journal of the American Chemical Society.

[205]  K. Pudhom,et al.  Convenient Methods for the Preparation of Unsymmetrical Double Aldols , 2003 .

[206]  R. A. Flowers,et al.  Mechanism of Reduction of Primary Alkyl Radicals by SmI2−HMPA , 1999 .

[207]  D. Procter,et al.  Development of an additive-controlled, SmI2-mediated stereoselective sequence: Telescoped spirocyclisation, lactone reduction and Peterson elimination , 2013, Beilstein journal of organic chemistry.

[208]  Pinhong Chen,et al.  Synthesis and structural revision of (+/-)-laurentristich-4-ol. , 2008, The Journal of organic chemistry.

[209]  H. Reissig,et al.  Highly Diastereoselective Samarium Diiodide Induced Ketyl Cyclisations of Indole and Pyrrole Derivatives – Scope and Limitations , 2010 .

[210]  H. Reissig,et al.  Samarium Diiodide Mediated Ketyl–Aryl Coupling Reactions – Influence of Substituents and Trapping Experiments , 2008 .

[211]  H. Reissig,et al.  Samarium Diiodide Induced Reactions of Cyclopropyl Ketones: Reductive Ring Cleavage and Dimerization Leading to 1,8‐Diketones – Scope, Limitations, Mechanisms , 2006 .

[212]  H. Kagan,et al.  Use of samarium diiodide in the field of asymmetric synthesis , 2008 .

[213]  P. A. Bradley,et al.  Studies on the mechanism, selectivity, and synthetic utility of lactone reduction using SmI(2) and H(2)O. , 2009, Journal of the American Chemical Society.

[214]  S. Reisman,et al.  Evolution of a synthetic strategy: total synthesis of (+/-)-welwitindolinone A isonitrile. , 2008, Journal of the American Chemical Society.

[215]  J. Concellón,et al.  Sequenced elimination–reduction and elimination–cyclopropanation reactions of 2,3-epoxyamides promoted by samarium diiodide. Synthesis of 2,3-dideuterioamides and cyclopropanamides , 2004 .

[216]  M. Turner,et al.  Phase tag-assisted synthesis of benzo[b]carbazole end-capped oligothiophenes. , 2012, Organic letters.

[217]  G. Molander,et al.  Ketyl-allene cyclizations promoted by samarium(II) iodide. , 2005, The Journal of organic chemistry.

[218]  K. Nicolaou,et al.  Total synthesis of platensimycin. , 2006, Angewandte Chemie.

[219]  Xin Lv,et al.  Study on the coupling of acyclic esters with alkenes--the synthesis of 2-(2-hydroxyalkyl)cyclopropanols via cascade cyclization using allylsamarium bromide. , 2012, Chemical communications.

[220]  Yinlong Guo,et al.  Study on mass spectrometric behavior of samarium di-iodide in tetrahydrofuran solution , 2008 .

[221]  New samarium diiodide-induced cyclizations , 2011 .

[222]  Y. Asakawa,et al.  Biogenetic-Like Cyclizationof Denudatenone A to Dolabellane-Type Diterpenoids Inducedby Samarium(II) Iodide: A Ketyl-Olefin Radical CouplingReaction Forming Five-Membered Carbocycles , 2009 .

[223]  B. Trost,et al.  The atom economy--a search for synthetic efficiency. , 1991, Science.

[224]  T. Inokuchi.  1,2-Acyl transfer reaction for the construction of multiple carbonyl-functionalized architecture by Sm(II)-induced tandem formation and breaking of cyclopropanol. , 2005, The Journal of organic chemistry.

[225]  H. Reissig,et al.  Efficient Synthesis of Medium‐Sized Rings Incorporating Indole or Pyrrole Units by Samarium Diiodide Induced Cyclizations , 2006 .

[226]  Jeffrey H. Glans,et al.  Comprehensive Organic Synthesis II (Book Review) , 2015 .

[227]  T. Thiemann,et al.  Synthesis of 1,2,9,10-tetrakis(N-phenylamino)[2.2]metacyclophane by SmI2-mediated reductive coupling of diimine , 2005 .

[228]  D. Procter,et al.  Recent advances in the chemistry of SmI(2)-H(2)O. , 2012, Chimia.

[229]  M. Szostak,et al.  Structural analysis and reactivity of unusual tetrahedral intermediates enabled by SmI2-mediated reduction of barbituric acids: vinylogous N-acyliminium additions to α-hydroxy-N-acyl-carbamides. , 2014, Chemical communications.

[230]  K. Nicolaou,et al.  Studies toward diazonamide A: development of a hetero-pinacol macrocyclization cascade for the construction of the bis-macrocyclic framework of the originally proposed structure. , 2004, Journal of the American Chemical Society.

[231]  Yong Hae Kim,et al.  A straightforward synthesis of 4-hydroxy-(E)-2-alkenoic esters mediated by SmI2 , 2001 .

[232]  V. Pecharsky,et al.  Handbook on the physics and chemistry of rare earths , 1979 .

[233]  R. Linhardt,et al.  Stereoselective synthesis of a C-linked neuraminic acid disaccharide: potential building block for the synthesis of C-analogues of polysialic acids. , 2008, Journal of Organic Chemistry.

[234]  H. Reissig,et al.  Benzannulated Cyclooctanol Derivatives by Samarium Diiodide Induced Intramolecular Carbonyl–Alkene Coupling – Scope, Limitations, Stereoselectivity , 2006 .

[235]  Ľ. Fišera,et al.  Synthesis of trihydroxylated pyrrolizidine and indolizidine alkaloids based on SmI2-induced reductive coupling of chiral nitrones with methyl acrylate , 2011 .

[236]  J. Concellón,et al.  Synthesis of different deuterated carboxylic acids from unsaturated acids promoted by samarium diiodide and D2O. , 2002, Chemistry.

[237]  Yong Hae Kim,et al.  Facile Ring Expansions of α-Halomethyl β-Keto Esters Mediated with SmI2 , 2001 .

[238]  S. Shuto,et al.  Synthesis of 3′-β-carbamoylmethylcytidine (CAMC) and its derivatives as potential antitumor agents , 2006 .

[239]  T. Ishida,et al.  Synthetic study of perophoramidine: construction of pentacyclic core structure via SmI2-mediated reductive cyclization , 2013 .

[240]  T. Nakata,et al.  SmI2-induced cyclization of (E)- and (Z)-β-alkoxyvinyl sulfones with aldehydes , 2010 .

[241]  S. Py,et al.  Tandem SmI2-induced nitrone beta-elimination/aldol-type reaction. , 2009, Organic & biomolecular chemistry.

[242]  H. Reissig,et al.  Synthesis of new steroid analogues by samarium diiodide induced cyclisations of γ-naphthyl 1,3-diones , 2010 .

[243]  Tzuen-Yeuan Lin,et al.  Samarium Diiodide Reduction of Cinnamic Acids , 2004 .

[244]  Carmen Concellón,et al.  An Efficient Synthesis of 2‐Bromo‐3‐hydroxy Esters by Reaction of Ketones with Ethyl Dibromoacetate Promoted by Samarium Diiodide , 2006 .

[245]  R. Flowers,et al.  Mechanistic Studies on the Roles of Cosolvents and Additives in Samarium(II)-Based Reductions , 2008 .

[246]  K. Hashimoto,et al.  Formal synthesis of FPA, a kainoid amino acid, via ketyl radical cyclization , 2002 .

[247]  T. Honda.  Development of samarium diiodide-promoted regioselective carbon-carbon bond cleavage reaction of γ-halo- and ε-halo-α,β-unsaturated carbonyl compounds: application to the synthesis of biologically active natural products , 2010 .

[248]  A. Dahlén,et al.  Microwave‐Assisted Generation of Lanthanide(II) Halides in THF and Simple Quantitative Determination , 2004 .

[249]  T. Skrydstrup,et al.  Formal total synthesis of the potent renin inhibitor aliskiren: application of a SmI2-promoted acyl-like radical coupling. , 2006, The Journal of organic chemistry.

[250]  S. Hoz,et al.  Guidelines for the use of proton donors in SmI2 reactions: reduction of alpha-cyanostilbene. , 2009, Journal of the American Chemical Society.

[251]  R. G. Allen,et al.  Stereochemistry of Radical Processes. Stereospecific trans Addition of HBr to Propyne , 1958 .

[252]  D. Curran,et al.  New Mechanistic Insights into Reductions of Halides and Radicals with Samarium(II) Iodide , 2010 .

[253]  Hui-Ying Huang,et al.  Enantioselective syntheses of rigidiusculamides A and B: revision of the relative stereochemistry of rigidiusculamide A. , 2012, Chemistry, an Asian journal.

[254]  C. Uriel,et al.  Synthetic Strategies Directed Towards 5a‐Carbahexopyranoses and Derivatives Based on 6‐endo‐trig Radical Cyclizations , 2011 .

[255]  T. Nakata.  SmI(2)-induced reductive cyclizations for the synthesis of cyclic ethers and applications in natural product synthesis. , 2010, Chemical Society reviews.

[256]  D. Procter,et al.  SmI2-mediated radical cyclizations directed by a C-Si bond. , 2010, Organic letters.

[257]  T. Skrydstrup,et al.  SmI2-Promoted Radical Addition of Nitrones to α,β-Unsaturated Amides and Esters: Synthesis of γ-Amino Acids via a Nitrogen Equivalent to the Ketyl Radical , 2003 .

[258]  S. Reisman,et al.  Total synthesis of (+/-)-welwitindolinone a isonitrile. , 2006, Journal of the American Chemical Society.

[259]  T. Burke,et al.  Samarium iodide-mediated Reformatsky reactions for the stereoselective preparation of β-hydroxy-γ-amino acids: synthesis of isostatine and dolaisoleucine. , 2012, The Journal of organic chemistry.

[260]  Keisuke Suzuki,et al.  First stereoselective total synthesis of FD-594 aglycon. , 2009, Angewandte Chemie.

[261]  Jingqian Wei,et al.  Concise asymmetric synthesis of (-)-deoxoprosophylline , 2008 .

[262]  K. Lam,et al.  Toluates: unexpectedly versatile reagents , 2009 .

[263]  J. Concellón,et al.  Synthesis of Isotopically Labeled (E)-β,γ-Unsaturated Esters with Total or High Diastereoselectivity by Using Samarium Diiodide. , 2001, Angewandte Chemie.

[264]  D. Uemura,et al.  Concise synthesis of a highly functionalized cyclopentane segment: toward the total synthesis of kansuinine A , 2007 .

[265]  Shunya Takahashi,et al.  Formal total synthesis of aspergillide A , 2011 .

[266]  D. Procter,et al.  Total synthesis of (+)-pleuromutilin. , 2013, Chemistry.

[267]  H. Reissig,et al.  Regioselective samarium diiodide induced couplings of carbonyl compounds with 1,3-diphenylallene and alkoxyallenes: a new route to 4-hydroxy-1-enol ethers. , 2004, Chemistry.

[268]  T. Ankner,et al.  SmI2/H2O/amine promoted reductive cleavage of benzyl-heteroatom bonds: optimization and mechanism , 2009 .

[269]  M. N. Bochkarev,et al.  [NdI2 (thf)5 ], the First Crystallographically Authenticated Neodymium(II) Complex. , 2001, Angewandte Chemie.

[270]  E. Álvarez,et al.  Phthalimides as exceptionally efficient single electron transfer acceptors in reductive coupling reactions promoted by samarium diiodide. , 2007, Organic letters.

[271]  Jiong Yang,et al.  Total synthesis of the potent cAMP signaling agonist (-)-alotaketal A. , 2012, Journal of the American Chemical Society.

[272]  K. Daasbjerg,et al.  Is samarium diiodide an inner- or outer-sphere electron donating agent? , 1999 .

[273]  M. Jacobsen,et al.  SmI(2)-mediated cyclizations of derivatized beta-lactams for the highly diastereoselective construction of functionalized prolines. , 2002, The Journal of organic chemistry.

[274]  S. Farcas,et al.  Samarium diiodide-mediated intermolecular coupling of organic halides with cyclic imides , 2001 .

[275]  H. Koshino,et al.  Synthetic studies on maitotoxin. 2. Stereoselective synthesis of the WXYZA'-ring system. , 2008, Organic letters.

[276]  Shunya Takahashi,et al.  First total synthesis of theopederin B , 2009 .

[277]  Bing Wang,et al.  Stereospecific, Flexible and Redox‐Economic Asymmetric Synthesis of cis‐ and trans‐3‐Hydroxypipecolic Acids and ­Analogs , 2009 .

[278]  M. Tori,et al.  Samarium (II) iodide-induced intermolecular coupling of α,β-unsaturated esters with ketones: reactions of methyl propiolate and ethyl buta-2,3-dienoate with cyclohexanone and its application to synthesis of a terpene carboxylic acid , 2013 .

[279]  D. Barton,et al.  Oxygen–carbon β-bond effects in radical reactions , 1982 .

[280]  H. Reissig,et al.  Competition between Novel 8-endo-dig and 6-trig Cyclizations of Samarium Ketyls Leading either to Benzannulated Cyclooctene or to Hexahydronaphthalene Derivatives , 2000 .

[281]  V. Rawal,et al.  A Short, Stereocontrolled Synthesis of Strychnine , 1994 .

[282]  K. Nicolaou,et al.  Total synthesis and structural revision of vannusals A and B: synthesis of the true structures of vannusals A and B. , 2010, Journal of the American Chemical Society.

[283]  T. Jamison,et al.  Highly convergent total synthesis of (+)-acutiphycin. , 2006, Journal of the American Chemical Society.

[284]  S. Hoz,et al.  Broadening the scope of photostimulated SmI(2) reductions. , 2010, Chemistry.

[285]  H. Reissig,et al.  Substituent Effects in Samarium Diiodide-Induced 6-trig Cyclizations of γ-Arylketones to Functionalized Hexahydronaphthalene Derivatives , 2001 .

[286]  A. Dahlén,et al.  Mechanistic study of the SmI2/H2O/amine-mediated reduction of alkyl halides: amine base strength (pKBH+) dependent rate. , 2005, Journal of the American Chemical Society.

[287]  Sarah E Reisman,et al.  A concise total synthesis of (-)-maoecrystal Z. , 2011, Journal of the American Chemical Society.

[288]  Yuanchao Li,et al.  Total synthesis of (-)-(α)-kainic acid via a diastereoselective intramolecular [3 + 2] cycloaddition reaction of an aryl cyclopropyl ketone with an alkyne. , 2012, Organic letters.

[289]  Yu‐Wu Zhong,et al.  Samarium diiodide-induced asymmetric synthesis of optically pure unsymmetrical vicinal diamines by reductive cross-coupling of nitrones with N-tert-butanesulfinyl imines. , 2004, Organic letters.

[290]  D. Boger,et al.  Total synthesis of kopsinine. , 2013, Organic letters.

[291]  P. Antharjanam,et al.  Mechanistic study of samarium diiodide-HMPA initiated 5-exo-trig Ketyl-Olefin coupling: the role of HMPA in post-electron transfer steps. , 2008, Journal of the American Chemical Society.

[292]  A. Dahlén,et al.  Diastereoselective intramolecular SmI2-H2O-amine mediated couplings. , 2003, Organic & biomolecular chemistry.

[293]  T. Jamison,et al.  Total synthesis of (+)-acutiphycin. , 2007, The Journal of organic chemistry.

[294]  M. Light,et al.  Samarium diiodide-mediated intramolecular cyclodimerisation of bis-α,β-unsaturated carbonyl compounds , 2009 .

[295]  Pei‐Qiang Huang,et al.  Towards Stereochemical Control: Two Approaches for the Highly anti-Diastereoselective Construction of the Spirolactone Moieties of Some Stemona Alkaloids , 2013 .

[296]  J. Concellón,et al.  β-Elimination reactions by using samarium diiodide , 2004 .

[297]  J. Ziller,et al.  The Availability of Dysprosium Diiodide as a Powerful Reducing Agent in Organic Synthesis: Reactivity Studies and Structural Analysis of DyI2((DME)3 and Its Naphthalene Reduction Product1 , 2000 .

[298]  T. Lindel,et al.  Enantioselective total synthesis of the diterpene (+)-cubitene. , 2012, Angewandte Chemie.

[299]  D. Williams,et al.  Chiral Cyclobutanols and CyclopentaneDimers via Samarium(II) Iodide Induced Keto-Olefin Cyclisationsof Carbohydrate-Derived Unsaturated Ketones , 2009 .

[300]  H. Togo,et al.  Radical 3-exo-tet cyclization of 1,3-dihalopropanes with SmI2 to form cyclopropanes , 2008 .

[301]  Keisuke Suzuki,et al.  Regio- and stereocontrolled total synthesis of benanomicin B. , 2005, Angewandte Chemie.

[302]  Carmen Concellón,et al.  Synthesis and Synthetic Applicationsof Samarium Enolates of Unmasked Amides: Efficient Synthesis of3-Aminoamides and 3-Amino-2-chloroamides , 2010 .

[303]  K C Nicolaou,et al.  Total synthesis of platensimycin and related natural products. , 2009, Journal of the American Chemical Society.

[304]  J. Yadav,et al.  Stereoselective formal synthesis of aspergillide A , 2010 .

[305]  S. Ōmura,et al.  Total synthesis of (-)-borrelidin. , 2004, Organic letters.

[306]  A. Dahlén,et al.  Reduction and reductive coupling of imines by Sm(II)-based reagents , 2003 .

[307]  J. Bats,et al.  Radical Additions to (η6‐Arene)(tricarbonyl)‐chromium Complexes: Diastereoselective Synthesis of Hydrophenalene and Hydrobenzindene Derivatives by Samarium(II) Iodide Induced Cyclization , 1995 .

[308]  R. A. Flowers,et al.  Aggregation state and reducing power of the samarium diiodide–DMPU complex in acetonitrile , 2000 .

[309]  D. Procter,et al.  Samarium enolates and their application in organic synthesis , 2008 .

[310]  M. Sasaki,et al.  Organic chemistry with lanthanides , 1988 .

[311]  H. Ohno,et al.  The first samarium(II)-mediated aryl radical cyclisation onto an aromatic ring. , 2004, Chemical communications.

[312]  M. Hursthouse,et al.  Samarium diiodide coupling of enones: a remarkable cascade sequence. , 2004, Organic letters.

[313]  H. Reissig,et al.  Novel stereoselective syntheses of highly functionalized benzannulated pyrrolizidines and indolizidines by samarium diiodide induced cyclizations of indole derivatives. , 2003, Organic letters.

[314]  D. Davies,et al.  A flexible, stereoselective approach to the decorated cis-hydrindane skeleton: synthesis of the proposed structure of faurinone. , 2008, Chemistry.

[315]  G. E. Keck,et al.  A new construction of 2-alkoxypyrans by an acylation-reductive cyclization sequence. , 2007, Organic letters.

[316]  H. Reissig,et al.  Highly substituted benzannulated cyclooctanol derivatives by samarium diiodide-induced cyclizations , 2010, Beilstein journal of organic chemistry.

[317]  A. Krief,et al.  Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI(2), the Kagan Reagent. , 1999, Chemical reviews.

[318]  M. Mellah,et al.  A samarium "soluble" anode: a new source of SmI2 reagent for electrosynthetic application. , 2012, Chemistry.

[319]  M. Inoue,et al.  Synthesis of the LMN-ring fragment of the Caribbean ciguatoxin C-CTX-1 , 2007 .

[320]  E. Prasad,et al.  The role of proton donors in SmI2-mediated ketone reduction: new mechanistic insights. , 2004, Journal of the American Chemical Society.

[321]  N. Allen,et al.  Utility of neodymium diiodide as a reductant in ketone coupling reactions. , 2003, Organic letters.

[322]  Susumu Kobayashi,et al.  Highly stereoselective construction of spiro[4.5]decanes by SmI(2)-promoted ketyl radical mediated tandem cyclization. , 2007, Organic letters.

[323]  Peter G. Jones,et al.  Enantiospecific synthesis of the cubitane skeleton. , 2010, Organic letters.

[324]  E. Carreira,et al.  Total synthesis of (+)-crotogoudin. , 2013, Angewandte Chemie.

[325]  R. Linhardt,et al.  Synthesis of a C-glycoside analogue of sTn: an HIV- and tumor-associated antigen. , 2003, Angewandte Chemie.

[326]  M. Szostak,et al.  Determination of the effective redox potentials of SmI₂, SmBr₂, SmCl₂, and their complexes with water by reduction of aromatic hydrocarbons. Reduction of anthracene and stilbene by samarium(II) iodide-water complex. , 2014, The Journal of organic chemistry.

[327]  D. Procter,et al.  An asymmetric, SmI2-mediated approach to γ-butyrolactones using a new, fluorous-tagged auxiliary , 2008 .

[328]  L. Raimondi,et al.  Synthesis of enantiomerically pure C2-symmetric acyclic and cyclic 1,2-diamines via pinacol coupling of imines , 2002 .

[329]  G. Mehta,et al.  Total synthesis of (+/-)-merrilactone A. , 2006, Angewandte Chemie.

[330]  R. S. Miller,et al.  Reactions of SmI2 with Alkyl Halides and Ketones: Inner-Sphere vs Outer-Sphere Electron Transfer in Reactions of Sm(II) Reductants , 2000 .

[331]  H. Schmalz,et al.  Electron Transfer Driven Transformations of Transition Metal π-Complexes: Samarium(II) Iodide Mediated Coupling of Fluoroarene-Cr(CO)3 Complexes with Ketones , 2002 .

[332]  K. Y. Tsang,et al.  A chiral pool based synthesis of platensimycin. , 2008, Angewandte Chemie.

[333]  S. Hoz,et al.  Reduction of benzophenones with SmI2. Post electron transfer processes. , 2009, The Journal of organic chemistry.

[334]  T. Nakata,et al.  Efficient strategy for the iterative synthesis of trans-fused polycyclic ether via SmI2-induced reductive intramolecular cyclization , 2002 .

[335]  K. Kakiuchi,et al.  Regioselective radical ring-opening reaction of bicyclo[4.2.0]octan-2-ones promoted by samarium(II) iodide , 2003 .

[336]  D. Hsu,et al.  Spiranes synthesis based on samarium diiodide-mediated reductive cyclization , 2012 .

[337]  T. Skrydstrup,et al.  Selective Side Chain Introduction onto Small Peptides Mediated by Samarium Diiodide: A Potential Route to Peptide Libraries , 2000 .

[338]  G. Molander,et al.  Lanthanides in organic synthesis. Synthesis of bicyclicalcohols. , 1984 .

[339]  M. Martín-Fontecha,et al.  SmI2-mediated 3-exo-trig cyclization of β,γ-unsaturated carbonyl compounds: diastereoselective synthesis of cyclopropanols. , 2010, Organic letters.

[340]  E. Prasad,et al.  Reduction of ketones and alkyl iodides by SmI(2) and Sm(II)-HMPA complexes. Rate and mechanistic studies. , 2002, Journal of the American Chemical Society.

[341]  Xiaoguang Lei,et al.  Total Syntheses of Lycopodium Alkaloids ( + )-Fawcettimine , ( + )-Fawcettidine , and ( )-8-Deoxyserratinine * * , 2011 .

[342]  Zhen Yang,et al.  Asymmetric total syntheses of ansamacrolactams (+)-Q-1047H-A-A and (+)-Q-1047H-R-A. , 2013, Organic letters.

[343]  D. Procter,et al.  SmI2-mediated couplings of α-amino acid derivatives. Formal synthesis of (-)-pumiliotoxin 251D and (±)-epiquinamide. , 2013, Organic letters.

[344]  F. Colobert,et al.  Recent advances in the diastereoselective Reformatsky-type reaction. , 2013, Chemical Society reviews.

[345]  Pei‐Qiang Huang,et al.  SmI2-mediated radical cross-couplings of α-hydroxylated aza-hemiacetals and N,S-acetals with α,β-unsaturated compounds: asymmetric synthesis of (+)-hyacinthacine A2, (-)-uniflorine A, and (+)-7-epi-casuarine. , 2011, The Journal of organic chemistry.

[346]  S. Py,et al.  SmI2-mediated coupling of nitrones and tert-butanesulfinyl imines with allenoates: synthesis of β-methylenyl-γ-lactams and tetramic acids. , 2012, Organic letters.

[347]  Yongming Zhang,et al.  Samarium Diiodide Mediated Barbier-Type Reaction of 2-Chloromethylbenzoxazole and 2-Chloromethylbenzothiazole with Carbonyl Compounds: A Convenient Synthesis of 1-(β-Hydroxyalkyl)benzoxazoles and 1-(β-Hydroxyalkyl)benzothiazoles , 2003 .

[348]  Yongming Zhang,et al.  Elimination of benzotriazolyl group in N-(α-benzotriazol-1-ylalkyl)amides and N-(α-benzotriazol-1-ylalkyl)sulfonamides: their self-coupling and cross-coupling reactions with carbonyl compounds , 2003 .

[349]  K. Nicolaou,et al.  Samarium diiodide mediated reactions in total synthesis. , 2009, Angewandte Chemie.

[350]  G. Molander,et al.  Sequenced reactions with samarium(II) iodide. Sequential intramolecular Barbier cyclization/Grob fragmentation for the synthesis of medium-sized carbocycles. , 2001, The Journal of organic chemistry.

[351]  Jie Wu,et al.  Total synthesis of (-)-virginiamycin M2: application of crotylsilanes accessed by enantioselective Rh(II) or Cu(I) promoted carbenoid Si-H insertion. , 2011, The Journal of organic chemistry.

[352]  D. Procter,et al.  Samarium(II)-iodide-mediated cyclizations in natural product synthesis. , 2004, Chemical reviews.

[353]  G. Molander,et al.  Sequencing Reactions with Samarium(II) Iodide. , 1996, Chemical reviews.

[354]  A. Caselli,et al.  SmI2-mediated reactions of diethyl iodomethylphosphonate with esters and lactones: a highly stereoselective synthesis of a precursor of the C-glycosyl analogue of thymidine 5′-(β-l-rhamnosyl)diphosphate , 2002 .

[355]  T. Nakata,et al.  SmI2-induced reductive cyclization of (E)- and (Z)-β-alkoxyvinyl sulfones with aldehyde , 2007 .

[356]  Z. Abdallah,et al.  Anomeric acetates of N-acetylneuraminic acid are useful C-sialyl donors in samarium-mediated reformatsky coupling reactions. , 2006, Angewandte Chemie.

[357]  J. L. Chiara,et al.  1-silyl-2,6-diketones: versatile intermediates for the divergent synthesis of five- and six-membered carbocycles under radical and anionic conditions. , 2006, Organic letters.

[358]  Y. Hamada,et al.  Synthetic studies on polyoxypeptins: stereoselective synthesis of (2S,3R)-3-hydroxy-3-methylproline using SmI2-mediated cyclization , 2002 .

[359]  A. Hulme,et al.  The Evans—Tishchenko Reaction: Scope and Applications , 2012 .

[360]  H. Yoda,et al.  SmI2-Promoted novel tandem elimination and coupling reactions of aliphatic imides with carbonyl compounds : application to the synthesis of dl-isoretronecanol , 2006 .

[361]  J. L. Chiara,et al.  Control of diastereoselectivity in C=O/C=N reductive cyclizations using an intramolecularly tethered hydrazone , 2005 .

[362]  Daesung Lee,et al.  Synthesis of the 5-7-6 core of guanacastepenes. Construction of C8 quaternary carbon via the inversion of stereochemistry. , 2002, Organic letters.

[363]  H. Reissig,et al.  Samarium diiodide-induced couplings of carbonyl compounds with methoxyallene leading to 4-hydroxy 1-enol ethers. , 2003, Organic letters.

[364]  H. Broughton,et al.  Synthesis of tri- and tetracyclic diterpenes. Cyclisations promoted by SmI2 , 2005 .

[365]  H. Yoda,et al.  A New Entry for the Preparation of Substituted Aromatic Carbonyl Compounds Mediated by Samarium(II) Iodide , 2003 .

[366]  S. Fukuzawa,et al.  A Facile Synthesis of Chiral γ-Butyrolactones in Extremely High Enantioselectivity Mediated by Samarium(II) Iodide , 1997 .

[367]  T. Skrydstrup,et al.  Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines. , 2005, Chemical communications.

[368]  J. Marrot,et al.  Stereochemical assignment and first synthesis of the core of miharamycin antibiotics. , 2008, Chemistry.

[369]  T. Nakata,et al.  SmI2-induced cyclization of optically active (E)- and (Z)-β-alkoxyvinyl sulfoxides with aldehydes , 2009 .

[370]  P. Tuchinda,et al.  Difluorophenylsulfanylmethyl radical and difluoromethylene diradical synthons: gem-difluoromethylene building block. , 2004, The Journal of organic chemistry.

[371]  Yasuyuki Ogawa,et al.  A New Method for the Synthesis of β-Amino-β'-Hydroxy Ketones by the Samarium(II) Iodide-mediated Aldol Reaction of Aldehydes with Aryl or Alkyl Aziridinyl Ketones , 2004 .

[372]  K. Nicolaou,et al.  Construction of the complete aromatic core of diazonamide A by a novel hetero pinacol macrocyclization cascade reaction , 2001 .

[373]  M. d'Alarcao,et al.  Synthesis of galactosaminyl D-chiro-inositols. , 2006, Carbohydrate research.

[374]  S. Py,et al.  Reductive cross-coupling reactions (RCCR) between CN and CO for β-amino alcohol synthesis , 2009 .

[375]  E. Hasegawa,et al.  Cyclization and Ring-expansion Reactions Involving Reductive Formation and Oxidative Ring-opening of Cyclopropanol Derivatives , 2005 .

[376]  H. Kagan.  Divalent Samarium Compounds: Perspectives for Organic Chemistry , 1991 .

[377]  Yu‐Wu Zhong,et al.  A highly efficient and direct approach for synthesis of enantiopure beta-amino alcohols by reductive cross-coupling of chiral N-tert-butanesulfinyl imines with aldehydes. , 2005, Journal of the American Chemical Society.

[378]  H. Kagan,et al.  Tetrahedron report number 213 , 1986 .

[379]  D. Procter,et al.  Switching between novel samarium(II)-mediated cyclizations by a simple change in alcohol cosolvent. , 2003, Organic letters.

[380]  A. Träff,et al.  Solvent dependent reductive defluorination of aliphatic C-F bonds employing Sm(HMDS)2. , 2013, Chemical communications.

[381]  H. Ohno,et al.  The first samarium(II)-mediated stereoselective spirocyclization onto an aromatic ring. , 2002, Chemical communications.

[382]  H. Yoda,et al.  Novel and stereoselective methods for the preparation of aromatic lactams via reductive coupling reactions mediated by SmI2 , 2000 .

[383]  M. R. Webb,et al.  Radical cyclization cascades of unsaturated Meldrum's acid derivatives. , 2012, Organic letters.

[384]  Hong-kui Zhang,et al.  A flexible enantioselective approach to 3,4-dihydroxyprolinol derivatives by SmI2-mediated reductive coupling of chiral nitrone with ketones/aldehydes , 2012 .

[385]  J. Concellón,et al.  Very Rapid Preparation of SmI2 by Sonic Treatment of Iodoform and Metallic Samarium , 2003 .

[386]  W. Evans.  Advances in f element reductive reactivity as a paradigm for expanding lanthanide and actinide science and technology , 2009 .

[387]  J. Teprovich,et al.  Mechanistic studies of proton-donor coordination to samarium diiodide. , 2007, Angewandte Chemie.

[388]  Araceli G. Campaña,et al.  Bioinspired terpene synthesis: a radical approach. , 2011, Chemical Society reviews.

[389]  S. Hoz,et al.  Photostimulated reduction of nitriles by SmI2. , 2012, The Journal of organic chemistry.

[390]  H. Reissig,et al.  Highly diastereoselective samarium diiodide induced cyclizations of new 3-substituted indole derivatives. , 2009, Organic & biomolecular chemistry.

[391]  O. Wiest,et al.  Synthesis, structure, and metal complexation behavior of a new type of functionalized chiral phenanthroline derivative. , 2008, The Journal of organic chemistry.

[392]  H. Morita,et al.  Formal synthesis of (−)-oleocanthal by means of a SmI2-promoted intramolecular coupling of bromoalkyne with α,β-unsaturated ester , 2012 .

[393]  G. Molander.  Application of lanthanide reagents in organic synthesis , 1992 .

[394]  C. Sabot,et al.  An oxidative Prins-pinacol tandem process and its application to the synthesis of (-)-platensimycin. , 2010, Chemistry.

[395]  Guoqin Liu,et al.  Formal synthesis of (±)-morphine. , 2013, Chemistry, an Asian journal.

[396]  K. Houk,et al.  Reactivity of (eta(6)-arene)tricarbonylchromium complexes toward additions of anions, cations, and radicals. , 2001, Journal of the American Chemical Society.

[397]  M. Helliwell,et al.  SmI2-mediated dialdehyde cyclization cascades , 2009 .

[398]  Carmen Concellón,et al.  An easy, efficient, and completely stereoselective synthesis of (E)-alpha,beta-unsaturated esters via sequential aldol-type/elimination reactions promoted by samarium diiodide or chromium dichloride. , 2005, The Journal of organic chemistry.

[399]  Yan Zhang,et al.  Efficient remote axial-to-central chirality transfer in enantioselective SmI2-mediated reductive coupling of aldehydes with crotonates of atropisomeric 1-naphthamides. , 2006, The Journal of organic chemistry.

[400]  E. Yoshida,et al.  Highly Stereoselective C-Silylation and Alkylation of 1-Chlorocyclopropanecarboxylic Ester Using SmI2 , 2009 .

[401]  S. Hoz,et al.  Synergism and inhibition in the combination of visible light and HMPA in SmI2 reductions. , 2012, The Journal of organic chemistry.

[402]  Takayuki Kimura,et al.  Asymmetric synthesis of anti- and syn-beta-amino alcohols by reductive cross-coupling of transition metal-coordinated planar chiral arylaldehydes with aldimines. , 2002, The Journal of organic chemistry.

[403]  W. Evans,et al.  Accessing Lanthanide Diiodide Reactivity for Coupling Alkyl Chlorides to Carbonyl Compounds via the NdI3/Alkali Metal Reduction System , 2005 .

[404]  Isamu Shiina,et al.  A New Method for the Synthesis of Unsymmetrical Bis-Aldols by the Samarium(II) Iodide-Mediated Aldol Reaction of Aldehydes with Aryl or Alkyl Oxiranyl Ketones , 2000 .

[405]  Peter Blakskjaer,et al.  An improved protocol for the SmI2-promoted C-alkylation of peptides: degradation and functionalization of serine residues in linear and cyclic peptides , 2004 .

[406]  Carmen Concellón,et al.  Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium. , 2010, Chemical Society reviews.

[407]  B. Tinant,et al.  Efficient and convergent stereocontrolled spiroannulation of ketones , 2003 .

[408]  Yong Hae Kim,et al.  Intramolecular, reductive cyclization of beta-ketoisothiocyanates promoted by using samarium diiodide. , 2005, Chemistry.

[409]  D. Procter,et al.  The first synthetic studies on pestalotiopsin A. A stereocontrolled approach to the functionalised bicyclic core. , 2003, Organic & biomolecular chemistry.

[410]  S. Py,et al.  Synthesis of α-Amino Acids through Samarium(II) Iodide Promoted Reductive Coupling of Nitrones with CO2 , 2012 .

[411]  Araceli G. Campaña,et al.  SmI2-promoted intra- and intermolecular C–C bond formation with chiral N-acyl oxazolidinones , 2008 .

[412]  G. Molander,et al.  A general route toward the synthesis of the cladiellin skeleton utilizing a SmI2-mediated cyclization. , 2006, The Journal of organic chemistry.

[413]  D. Williams,et al.  Highly Functionalised Cyclobutanols by Samarium(II) Iodide Induced Radical Cyclisations of Carbohydrate-Derived Unsaturated Ketones , 2004 .

[414]  S. Castle,et al.  Advances in radical conjugate additions , 2005 .

[415]  Shouyun Yu,et al.  A convergent route to the Galbulimima alkaloids (-)-GB 13 and (+)-GB 16. , 2010, Angewandte Chemie.

[416]  R. Flowers,et al.  Electrochemical investigation of the reducing power of SmI2 in THF and the effect of HMPA cosolvent , 1997 .

[417]  M. Light,et al.  Samarium diiodide mediated intramolecular cyclisation of mixed enone-enoate systems: a simple preparation of spirocyclic ethers , 2011 .

[418]  D. Procter,et al.  Samarium(II)-mediated 4-exo-trig cyclization. A stereocontrolled approach to the core of pestalotiopsin A. , 2001, Organic letters.

[419]  M. Szostak,et al.  Electron transfer reduction of carboxylic acids using SmI2-H2O-Et3N. , 2012, Organic letters.

[420]  Y. Tu,et al.  Total syntheses of (+)-alopecuridine, (+)-sieboldine A, and (-)-lycojapodine A. , 2012, The Journal of organic chemistry.

[421]  G. Molander,et al.  Toward the total synthesis of variecolin. , 2001, Organic letters.

[422]  T. Endo,et al.  SmI2 as a Reagent in Polymer Chemistry , 1998 .

[423]  Keisuke Suzuki,et al.  Semi-pinacol strategy for constructing b-ring of pradimicin-benanomicin antibiotics , 2002 .

[424]  T. Sakurai,et al.  Electroreductive intramolecular coupling of N-(oxoalkyl)phthalimides: complementary method to samarium(II) iodide reduction , 2010 .

[425]  S. Handa,et al.  Samarium(ii) iodide-mediated intramolecular pinacol coupling reactions with cyclopropyl ketones. , 2007, Chemical communications.

[426]  Shunya Takahashi,et al.  Stereoselective total synthesis of mucocin, an antitumor agent. , 2002, Angewandte Chemie.

[427]  T. Lauterbach,et al.  Strained heterocycles in radical chemistry. , 2003, Angewandte Chemie.

[428]  A. Tarnopolsky,et al.  Reduction of activated olefins by SmI2. Detouring the classical Birch mechanism and a negative order in SmI2. , 2007, Journal of the American Chemical Society.

[429]  T. Skrydstrup,et al.  Some unusual reactivities in the SmI2-mediated reductive coupling of acrylamides and acrylates with imides , 2009 .

[430]  D. Procter,et al.  Samarium(II)-mediated 4-exo trig ketyl-olefin cyclisation of unsaturated aldehydes. A general, stereoselective synthesis of functionalised cyclobutanols , 1999 .

[431]  T. Martín,et al.  Samarium(II) promoted stereoselective synthesis of antiproliferative cis-β-alkoxy-γ-alkyl-γ-lactones , 2007 .

[432]  Vittorio Pace,et al.  NHC-Cu(I) catalysed asymmetric conjugate silyl transfer to unsaturated lactones: application in kinetic resolution. , 2013, Chemical communications.

[433]  H. Reissig,et al.  A New Samarium Diiodide Induced Reaction: Intramolecular Attack of Ketyl Radical Anions on Aryl Substituents with Formation of 1,4-Cyclohexadiene Derivatives. , 1999, Angewandte Chemie.

[434]  S. Py,et al.  SmI2‐Induced Umpolung of the CN Bond: First Reductive Conjugate Addition of Nitrones to α,β‐Unsaturated Esters , 2003 .

[435]  M. Mellah,et al.  Use of Electrochemistry to Provide Efficient SmI2 Catalytic System for Coupling Reactions. , 2013 .

[436]  Jinlong Wu,et al.  Synthesis of the C1–C12 acid fragment of amphidinolide T marine macrolides via SmI2-mediated enantioselective reductive coupling of aldehydes with a chiral crotonate , 2009 .

[437]  Aaron A. Bedermann,et al.  Toward the synthesis of phomoidride D. , 2013, The Journal of organic chemistry.

[438]  F. Guibé,et al.  Diastereoselective SmI2-mediated cyclisation of δ-oxo-α,β-unsaturated esters to cyclopropanols , 2002 .

[439]  S. García‐Granda,et al.  Addition reaction of vinylic reagents, derived from alpha-chloroenones, to carbonyl compounds promoted by samarium diiodide. , 2003, Chemistry.

[440]  M. Szostak,et al.  Selective reductive transformations using samarium diiodide-water. , 2012, Chemical communications.

[441]  P. Deslongchamps,et al.  A convergent synthesis of the cardenolide skeleton: intramolecular aldol condensation via reduction of alpha-bromoketones. , 2002, The Journal of organic chemistry.

[442]  Y. Tu,et al.  A tandem semipinacol rearrangement/alkylation of alpha-epoxy alcohols: an efficient and stereoselective approach to multifunctional 1,3-diols. , 2004, Angewandte Chemie.

[443]  K. Nicolaou,et al.  The true structures of the vannusals, part 1: Initial forays into suspected structures and intelligence gathering. , 2009, Angewandte Chemie.

[444]  P. Helquist,et al.  Samarium-promoted coupling of 1,10-phenanthroline with carbonyl compounds for synthesis of new ligands. , 2004, The Journal of organic chemistry.

[445]  M. Szostak,et al.  Preparation of samarium(II) iodide: quantitative evaluation of the effect of water, oxygen, and peroxide content, preparative methods, and the activation of samarium metal. , 2012, The Journal of organic chemistry.

[446]  Toshio Suzuki,et al.  The first enantioselective total synthesis of cyclomyltaylane-5α-ol and determination of its absolute stereochemistry , 2002 .

[447]  S. Hoz,et al.  Quantifying the electrostatic driving force behind SmI2 reductions. , 2008, Organic letters.

[448]  H. Kagan,et al.  Influence of Solvents or Additives on the Organic Chemistry Mediated by Diiodosamarium , 1999 .

[449]  M. N. Bochkarev,et al.  A novel bis(imino)amine ligand as a result of acetonitrile coupling with the diiodides of Dy(II) and Tm(II). , 2003, Journal of the American Chemical Society.

[450]  Tejas J. Upadhyay,et al.  The samarium(II)-mediated intermolecular couplings of ketones and β-alkoxyacrylates: A short asymmetric synthesis of an antifungal γ-butyrolactone , 2004 .

[451]  H. Matsubara,et al.  A ring size-selective reduction of lactones using SmI2 and H2O. , 2008, Journal of the American Chemical Society.

[452]  T. Gillmann.  Samarium (II) iodide-mediated intramolecular reductive coupling of aldehydes with allenic Esters , 1993 .

[453]  E. Corey,et al.  Enantioselective total synthesis of isoedunol and beta-araneosene featuring unconventional strategy and methodology. , 2005, Journal of the American Chemical Society.

[454]  D. Procter,et al.  Exploiting Sm(II) and Sm(III) in SmI2-initiated reaction cascades: application in a tag removal-cyclisation approach to spirooxindole scaffolds. , 2011, Organic & biomolecular chemistry.

[455]  D. Curran,et al.  Radical and palladium-catalyzed cyclizations to cyclobutenes: an entry to the BCD ring system of penitrem D. , 2004, The Journal of organic chemistry.

[456]  Wei Wang,et al.  Carbohydrates as chiral auxiliaries in enantioselective synthesis of four stereoisomers of optically active α,γ-substituted γ-butyrolactones , 2003 .

[457]  M. Tori,et al.  Preparation of seven-and eight-membered rings by carbon-carbon bond formation induced by samarium diiodide : 7-endo-and 8-endo-trig type cyclization to bicyclo[5.3.0]decanolone, bicyclo[5.4.0]undecanolone, and bicyclo[6.4.0]dodecanolone , 2008 .

[458]  L. Overman,et al.  Is there no end to the total syntheses of strychnine? Lessons learned in strategy and tactics in total synthesis. , 2012, Angewandte Chemie.

[459]  C. M. Beaudry,et al.  Reductive synthesis of aminal radicals for carbon-carbon bond formation. , 2014, Organic letters.

[460]  C. Simal,et al.  The Use of Samarium Enolates, A Novel Alternative in the Addition Reactions to Imines. Synthesis of 3‐Amino Esters, Amides and Enantiopure 3,4‐Diamino Esters , 2009 .

[461]  Thomas M. Baker,et al.  A stereoselective cyclisation cascade mediated by SmI2―H2O: synthetic studies towards stolonidiol , 2010 .

[462]  Z. Abdallah,et al.  Synthesis of a carbon-linked mimic of the disaccharide component of the tumor-related SialylTn antigen. , 2003, Angewandte Chemie.

[463]  J. Ellman,et al.  The total synthesis of tubulysin D. , 2006, Journal of the American Chemical Society.

[464]  A. Dahlén,et al.  Instantaneous SmI2/H2O/amine-mediated reductions in THF. , 2003, Chemistry.

[465]  E. Hasegawa,et al.  Cyclization and ring-expansion processes involving samarium diiodide promoted reductive formation and subsequent oxidative ring opening of cyclopropanol derivatives. , 2009, The Journal of organic chemistry.

[466]  Bangguo Wei,et al.  A flexible approach to construct three contiguous chiral centers of sphingolipids, and asymmetric synthesis of d-ribo-phytosphingosine and its derivatives , 2012 .

[467]  T. Nakata,et al.  Total synthesis of brevetoxin-B. , 2004, Journal of the American Chemical Society.

[468]  Carmen Concellón,et al.  Direct reaction of dibromoacetic acid with aldehydes promoted by samarium diiodide: an easy, efficient, and rapid synthesis of (E)-alpha,beta-unsaturated carboxylic acids with total stereoselectivity. , 2006, The Journal of organic chemistry.

[469]  Jim-Min Fang,et al.  SYNTHESIS OF XANTHENES, INDANES, AND TETRAHYDRONAPHTHALENES VIA INTRAMOLECULAR PHENYL–CARBONYL COUPLING REACTIONS , 2001 .

[470]  W. Evans.  The importance of questioning scientific assumptions: some lessons from f element chemistry. , 2007, Inorganic chemistry.

[471]  C. Seger,et al.  Samarium(II) Iodide Promoted Tandem Reductive Fragmentation and Aldol Reaction , 2001 .

[472]  Mark E. Scott,et al.  Aryl-aryl bond formation by transition-metal-catalyzed direct arylation. , 2007, Chemical reviews.

[473]  Kosuke Katagiri,et al.  Isolation, X-ray Structural Characterization, and Reactivities of Diiodosamarium(II) Complexes Bearing Amide Compounds as Ligands , 2001 .

[474]  G. Molander,et al.  Sequenced reactions with samarium(II) iodide. Sequential intramolecular Reformatsky/nucleophilic acyl substitution reactions for the synthesis of medium-sized carbocycles. , 2002, The Journal of organic chemistry.

[475]  S. Reisman,et al.  A mild and efficient synthesis of oxindoles: progress towards the synthesis of welwitindolinone A isonitrile. , 2004, Angewandte Chemie.

[476]  J. Teprovich,et al.  Dynamic ligand exchange in reactions of samarium diiodide. , 2010, Organic letters.

[477]  Hexin Xie,et al.  Auxiliary strategies for the preparation of β-amino alcohols with reductive cross-coupling and a synthesis of (−)-cytoxazone , 2005 .

[478]  T. Skrydstrup,et al.  Creating carbon-carbon bonds with samarium diiodide for the synthesis of modified amino acids and peptides. , 2006, Organic & biomolecular chemistry.

[479]  Y. Wu,et al.  Studies toward the total synthesis of clavulactone. , 2001, The Journal of organic chemistry.

[480]  S. Ōmura,et al.  Total synthesis of borrelidin. , 2007, The Journal of organic chemistry.

[481]  T. Jamison,et al.  SmI2-promoted Reformatsky-type coupling reactions in exceptionally hindered contexts. , 2008, Organic letters.

[482]  Xiaoguang Lei,et al.  Collective Synthesis of Lycopodium Alkaloids and Tautomer Locking Strategy for the Total Synthesis of (−)-lycojapodine A , 2022 .

[483]  Jie Wu,et al.  Total synthesis of (-)-virginiamycin M2. , 2010, Angewandte Chemie.

[484]  B. Wang,et al.  Concise asymmetric synthesis of (+)-CP-99,994 and (+)-L-733,060 via efficient construction of homochiral syn-1,2-diamines and syn-1,2-amino alcohols. , 2008, The Journal of organic chemistry.

[485]  Yu‐Wu Zhong,et al.  Highly Diastereoselective and Enantioselective Synthesis of Enantiopure C2-Symmetrical Vicinal Diamines by Reductive Homocoupling of Chiral N-tert-Butanesulfinyl Imines , 2004 .

[486]  Yuji Kawato,et al.  Catalytic asymmetric conjugate addition of alpha-cyanoketones for the construction of a quaternary stereogenic center. , 2010, Organic letters.

[487]  G. Lin,et al.  A New Entry to Asymmetric Synthesis of Optically Active α,γ-Substituted γ-Butyrolactones, Using a Carbohydrate Derived Amide as Both a Chiral Auxiliary and a Proton Source , 2005 .

[488]  R. A. Flowers,et al.  Catalytic Ni(II) in reactions of SmI2: Sm(II)- or Ni(0)-based chemistry? , 2011, Journal of the American Chemical Society.

[489]  T. Nishikawa,et al.  A Concise Synthesis of a Highly Strained Cyclobutane in Solanoeclepin A by Radical Cyclization , 2012 .

[490]  N. Harada,et al.  Concise total synthesis and structure assignment of TAN-1085. , 2004, Angewandte Chemie.

[491]  A. Caselli,et al.  A new entry to β-hydroxyphosphonates: the SmI2-mediated reaction of diethyl iodomethylphosphonate with carbonyl compounds , 2002 .

[492]  A. Dahlén,et al.  Samarium(II) Iodide Mediated Reductions − Influence of Various Additives , 2004 .

[493]  P. Helquist,et al.  Samarium-promoted coupling of pyridine-based heteroaryl analogues of benzylic acetates with carbonyl compounds. , 2005, Organic letters.

[494]  W. Shipe,et al.  Convergent, enantioselective syntheses of guanacastepenes A and E featuring a selective cyclobutane fragmentation. , 2006, Journal of the American Chemical Society.

[495]  T. Nakata.  SmI2-induced cyclizations and their applications in natural product synthesis. , 2010, Chemical record.

[496]  D. Curran,et al.  Additive and solvent effects on samarium diiodide reductions: the effects of water and DMPU , 1993 .

[497]  Y. Blériot,et al.  Total synthesis of calditol: structural clarification of this typical component of Archaea order Sulfolobales. , 2002, Chemistry.

[498]  Esther N. Pesciotta,et al.  Generation of SmII Reductants Using High Intensity Ultrasound , 2008 .

[499]  H. Reissig,et al.  A new, efficient and stereoselective synthesis of tricyclic and tetracyclic compounds by samarium diiodide induced cyclisations of naphthyl-substituted arylketones--an easy access to steroid-like skeletons. , 2007, Chemistry.

[500]  Riadh Zriba,et al.  SmI2-Mediated 3-exo-trig cyclisation of δ-oxo-α,β-unsaturated esters to cyclopropanols and derivatives , 2004 .

[501]  A. Novikov,et al.  Synthesis of plakortethers F and G. , 2009, The Journal of organic chemistry.

[502]  S. Py,et al.  A direct and versatile access to alpha,alpha-disubstituted 2-pyrrolidinylmethanols by SmI2-mediated reductive coupling. , 2008, Organic letters.

[503]  H. Reissig,et al.  Nitrogen‐Containing Tricyclic and Tetracyclic Compounds by Stereoselective Samarium Diiodide Promoted Cyclizations of Quinolyl‐Substituted Ketones – A New Access to Azasteroids , 2008 .

[504]  T. Honda,et al.  Integral stereocontrolled synthesis of a spiro-norlignan, sequosempervirin A: revision of absolute configuration. , 2011, Organic letters.

[505]  M. Szostak,et al.  Electron transfer reduction of nitriles using SmI2-Et3N-H2O: synthetic utility and mechanism. , 2014, Organic letters.

[506]  D. Comins,et al.  Photochemical reactions of chiral 2,3-dihydro-4(1H)-pyridones: asymmetric synthesis of (–)-perhydrohistrionicotoxin , 1998 .

[507]  A. Kishida,et al.  Samarium(II) iodide-induced cascade reaction for tricyclic γ-lactone synthesis from acyclic keto diesters , 2008 .

[508]  C. Tseng,et al.  Chemical synthesis of the englerins. , 2012, Chemistry, an Asian journal.

[509]  H. Kagan.  Twenty-five years of organic chemistry with diiodosamarium: an overview , 2003 .

[510]  R. A. Flowers,et al.  Influence of HMPA on reducing power and reactivity of SmBr(2). , 2001, Organic letters.

[511]  G. Sello,et al.  (1S,2S)-1-Amino-2-hydroxy-1,2,3,4-tetrahydronaphthalene: a new chiral auxiliary for asymmetric Reformatsky reactions , 2005 .

[512]  S. Py,et al.  Stereoselective synthesis of beta-1-C-substituted 1,4-dideoxy-1,4-imino-D-galactitols and evaluation as UDP-galactopyranose mutase inhibitors. , 2007, Bioorganic & medicinal chemistry.

[513]  T. Ritter,et al.  Introduction of fluorine and fluorine-containing functional groups. , 2013, Angewandte Chemie.

[514]  H. Murai,et al.  First direct evidence of radical intermediates in samarium diiodide induced cyclization by ESR spectra. , 2011, Organic letters.

[515]  B. Giese,et al.  Stereochemistry of Radical Reactions , 1995 .

[516]  M. Szostak,et al.  Substrate-directable electron transfer reactions. Dramatic rate enhancement in the chemoselective reduction of cyclic esters using SmI2-H2O: mechanism, scope, and synthetic utility. , 2013, Journal of the American Chemical Society.

[517]  H. Kagan,et al.  Recent developments in samarium diiodide promoted organic reactions. , 2013, Chemical record.

[518]  T. Skrydstrup,et al.  Can decarbonylation of acyl radicals be overcome in radical addition reactions? En route to a solution employing N-acyl oxazolidinones and SmI2/H2O. , 2005, Journal of the American Chemical Society.

[519]  T. Imamoto.  Lanthanides in organic synthesis , 1994 .

[520]  Pei‐Qiang Huang,et al.  A new approach to 3-hydroxyprolinol derivatives by samarium diiodide-mediated reductive coupling of chiral nitrone with carbonyl compounds. , 2009, Organic & biomolecular chemistry.

[521]  M. Inoue,et al.  A concise route to the C2-symmetric tricyclic skeleton of ryanodine , 2009 .

[522]  J. Fuchs,et al.  The effect of cosolvent on the reducing power of SmI2 in tetrahydrofuran , 1998 .

[523]  P. A. Bradley,et al.  Reductive cyclization cascades of lactones using SmI2-H2O. , 2011, Journal of the American Chemical Society.

[524]  T. Masuda,et al.  Synthetic studies on sugar-fused erinacines. , 2005, Organic & biomolecular chemistry.

[525]  M. Szostak,et al.  On the Role of Pre- and Post-Electron-Transfer Steps in the SmI2/Amine/H2O-Mediated Reduction of Esters: New Mechanistic Insights and Kinetic Studies , 2014, Chemistry.

[526]  S. Py,et al.  Total synthesis of (+)-hyacinthacine A2 based on SmI2-induced nitrone umpolung. , 2005, The Journal of organic chemistry.

[527]  小林 修,et al.  Lanthanides : chemistry and use in organic synthesis , 1999 .

[528]  G. Molander,et al.  Sequenced reactions with samarium(II) iodide , 1998 .

[529]  Riadh Zriba,et al.  A new access to ring-fused cyclopropanols through samarium diiodide-induced 3-exo-trig-cyclisations , 2007 .

[530]  M. Szostak,et al.  A general electron transfer reduction of lactones using SmI2-H2O. , 2012, Organic & biomolecular chemistry.

[531]  T. Ishida,et al.  Synthesis of 2-Iminoindolines via Samarium Diiodide Mediated Reductive Cyclization of Carbodiimides , 2012 .

[532]  Tzuen-Yeuan Lin,et al.  Rate Study of Proton Catalyzed SmI2 Reduction of 2‐Heptanone and 1,2‐Epoxydecane , 2000 .

[533]  Carmen Concellón,et al.  The use of samarium or sodium iodide salts as an alternative for the aza-Henry reaction , 2012 .

[534]  A. Ates,et al.  Efficient access to functionalised medium-ring systems by radical fragmentation/radical addition to α-iodoketones , 2005 .

[535]  T. Honda,et al.  Diastereoselective syntheses of functionalized five-membered carbocycles and heterocycles by a SmI2-promoted intramolecular coupling of bromoalkynes and alpha,beta-unsaturated esters. , 2010, Organic letters.

[536]  Carmen Concellón,et al.  Efficient nitro-aldol reaction using SmI2: a new route to nitro alcohols under very mild conditions. , 2006, The Journal of organic chemistry.

[537]  J. Fuchs,et al.  The effect of lithium bromide and lithium chloride on the reactivity of SmI2 in THF , 1997 .

[538]  T. Fujinami,et al.  Samarium(II) di-iodide induced reductive coupling of α,β-unsaturated esters with carbonyl compounds leading to a facile synthesis of γ-lactone , 1988 .

[539]  C. Merlic,et al.  The tricarbonylchromium template for stereocontrol in radical reactions of arenes. , 2001, The Journal of organic chemistry.

[540]  G. Pattenden,et al.  Searching for radical intermediates and pathways implied in the biosynthesis of some polycyclic cembranoids. A new plausible mechanism for the origin of sinulanocembranolide A in the coral Sinularia gyrosa , 2013 .

[541]  S. Hoz,et al.  Reduction of 4-styrylpyridine by SmI2: an inner sphere electron tranfer case where the binding site differs from the reaction center. , 2013, Organic letters.

[542]  B. Kim,et al.  SmI2 MEDIATED ALLYLATION OF ALDIMINES WITH ALLYL BROMIDE , 2001 .

[543]  B. Pelotier,et al.  Stereoselective Access to Trisubstituted Cyclopentanols from Chiral Unsaturated Oxo Esters by Ketyl Radical Cyclization , 2014 .

[544]  H. Kagan,et al.  Efficient formation of pinacols from aldehydes or ketones mediated by samarium diiodide , 1983 .

[545]  S. Py,et al.  Samarium Diiodide‐Induced Reductive Cross‐Coupling of Nitrones with Aldehydes and Ketones , 2002 .

[546]  Pei‐Qiang Huang,et al.  One-pot cross-coupling of N-acyl N,O-acetals with alpha,beta-unsaturated compounds. , 2009, Chemical communications.

[547]  Manuel Friedel,et al.  Oxidative cyclization of a seco-cladiellane diterpenoid , 2005 .

[548]  S. Shuto,et al.  A highly stereoselective samarium diiodide-promoted aldol reaction with 1'-phenylseleno-2'-keto nucleosides. Synthesis of 1'alpha-branched uridine derivatives. , 2002, The Journal of organic chemistry.

[549]  F. Matsuda,et al.  Acetoxyl group directed cyclization promoted by SmI2: directing group determined stereocomplementarity. , 2004, The Journal of organic chemistry.

[550]  J. Concellón,et al.  Transformation of α,β-Epoxyesters into 2,3-Dideuterioesters Promoted by Samarium Diiodide , 2003 .

[551]  S. Nakagawa,et al.  A concise stereoselective synthesis of (-)-erycibelline. , 2011, Organic & biomolecular chemistry.

[552]  D. Procter,et al.  Samarium(II)-mediated 4-exo-trig cyclisations of unsaturated aldehydes. A stereoselective approach to functionalised cyclobutanols , 2000 .

[553]  Sandip K. Nandy,et al.  Synthesis of polysubstituted benzothiophenes and sulfur-containing polycyclic aromatic compounds via samarium diiodide promoted three-component coupling reactions of thiophene-2-carboxylate. , 2002, The Journal of organic chemistry.

[554]  Pei‐Qiang Huang,et al.  One-pot reductive coupling of N-acylcarbamates with activated alkenes: application to the asymmetric synthesis of pyrrolo[1,2-a]azepin-5-one ring system and (-)-xenovenine. , 2012, Organic & biomolecular chemistry.

[555]  William J. Chain,et al.  A brief synthesis of (-)-englerin A. , 2011, Journal of the American Chemical Society.

[556]  E. Prasad,et al.  Photoinduced electron transfer reactions by SmI2 in THF: luminescence quenching studies and mechanistic investigations. , 2005, Chemistry.

[557]  K. Nicolaou,et al.  Total synthesis of echinopines A and B. , 2010, Journal of the American Chemical Society.

[558]  L. Paquette,et al.  Pinacol macrocyclization-based route to the polyfused medium-sized CDE ring system of lancifodilactone G. , 2008, Organic letters.

[559]  D. Procter,et al.  A dialdehyde cyclization cascade: an approach to pleuromutilin. , 2009, Angewandte Chemie.