Current status and recent topics of rare-earth permanent magnets

After the development of Nd–Fe–B magnets, rare-earth magnets are now essential components in many fields of technology, because of their ability to provide a strong magnetic flux. There are two, well-established techniques for the manufacture of rare earth magnets: powder metallurgy is used to obtain high-performance, anisotropic, fully dense magnet bodies; and the melt-spinning or HDDR (hydrogenation, disproportionation, desorption and recombination) process is widely used to produce magnet powders for bonded magnets. In the industry of sintered Nd–Fe–B magnets, the total amount of production has increased and their dominant application has been changed to motors. In particular, their use for motors in hybrid cars is one of the most attractive applications. Bonded magnets have also been used for small motors, and the studies of nanocomposite and Sm–Fe–N magnets have become widespread. This paper reviews the current status and future trend in the research of permanent magnets.

[1]  H. Nakamura,et al.  Magnetic properties of extremely small Nd-Fe-B sintered magnet , 2005, INTERMAG Asia 2005. Digests of the IEEE International Magnetics Conference, 2005..

[2]  R. Osugi,et al.  The magnetic and structural properties of R-Ti-Fe ternary compounds , 1987 .

[3]  K. Strnat Chapter 2 Rare earth-cobalt permanent magnets , 1988 .

[4]  R. Gopalan,et al.  Sm(Co,Cu)/sub 5//Fe exchange spring multilayer films with high energy product , 2005, INTERMAG Asia 2005. Digests of the IEEE International Magnetics Conference, 2005..

[5]  O. Yamashita,et al.  Phase boundary structure in Nd–Fe–B sintered magnets , 1999 .

[6]  J. J. Croat,et al.  High‐energy product Nd‐Fe‐B permanent magnets , 1984 .

[7]  R. K. Mishra,et al.  Microstructure and properties of step aged rare earth alloy magnets , 1981 .

[8]  Yingchang Yang,et al.  Magnetocrystalline anisotropies of RTiFe11Nx compounds , 1991 .

[9]  S. Hirosawa,et al.  Influence of Nd/Nd2Fe14B interface microstructure on the coercivity of surface Nd2Fe14B grains in Nd-sputtered Nd–Fe–B sintered magnets , 2008 .

[10]  I. R. Harris,et al.  The hydrogen decrepitation of an Ndi15Fe77B8 magnetic alloy , 1985 .

[11]  K. Ishiyama,et al.  Review of Fabrication and Characterization of Nd–Fe–B Thick Films for Magnetic Micromachines , 2007, IEEE Transactions on Magnetics.

[12]  Hisao Yamamoto,et al.  Permanent magnet materials based on the rare earth-iron-boron tetragonal compounds , 1984 .

[13]  E. Kneller,et al.  The exchange-spring magnet: a new material principle for permanent magnets , 1991 .

[14]  J. Liu,et al.  SmCo5∕Fe nanocomposites synthesized from reductive annealing of oxide nanoparticles , 2007 .

[15]  S. Hirosawa,et al.  Coercivity generation of surface Nd2Fe14B grains and mechanism of fcc-phase formation at the Nd/Nd2Fe14B interface in Nd-sputtered Nd–Fe–B sintered magnets , 2008 .

[16]  M. Sagawa,et al.  Improvement of coercivity of sintered NdFeB permanent magnets by heat treatment , 2002 .

[17]  I. R. Harris,et al.  Hydrogenation, disproportionation and desorption (HDD): An effective processing route for NdFeB-type magnets , 1990 .

[18]  Karl J. Strnat,et al.  Rare earth-cobalt permanent magnets , 1991 .

[19]  I. R. Harris,et al.  Nd-Fe-B Permanent Magnets: Hydrogen Absorption/Desorption Studies (HADS) on Nd16Fe76B8 and Nd2Fe14B , 1987 .

[20]  S. Sugimoto,et al.  Effect of the disproportionation and recombination stages of the HDDR process on the inducement of anisotropy in Nd–Fe–B magnets , 1999 .

[21]  J. M. D. Coey,et al.  Improved magnetic properties by treatment of iron-based rare earth intermetallic compounds in anmonia , 1990 .

[22]  M. Sagawa,et al.  Transmission electron microscopy study on Nd-rich phase and grain boundary structure of Nd–Fe–B sintered magnets , 2005 .

[23]  R. Gopalan,et al.  Consolidation of hydrogenation–disproportionation–desorption–recombination processed Nd–Fe–B magnets by spark plasma sintering , 2009 .

[24]  J. Liu,et al.  Preparation of Nd–Fe–B nanoparticles by surfactant-assisted ball milling technique , 2009 .

[25]  K. Ohmori,et al.  Current Status of Bonded Sm-Fe-N Anisotropic Magnets(invited) , 2003 .

[26]  S. J. Collocott,et al.  New rare‐earth intermetallic phases R3(Fe,M)29Xn: (R=Ce, Pr, Nd, Sm, Gd; M=Ti, V, Cr, Mn; and X=H, N, C) (invited) , 1994 .

[27]  N. Tezuka,et al.  Interfacial state and magnetic properties of Nd-Fe-B/Nd thin films , 2009 .

[28]  T. Ohkubo,et al.  The role of grain boundaries in the coercivity of hydrogenation disproportionation desorption recombination processed Nd–Fe–B powders , 2009 .

[29]  H. Fujii,et al.  Chapter 3 Interstitially modified intermetallics of rare earth and 3D elements , 1995 .

[30]  Y. Peng,et al.  Bulk anisotropic composite rare earth magnets , 2006 .

[31]  T. Ohkubo,et al.  Effect of post-sinter annealing on the coercivity and microstructure of Nd-Fe-B permanent magnets , 2009 .

[32]  M. Sagawa,et al.  New material for permanent magnets on a base of Nd and Fe (invited) , 1984 .

[33]  J. F. Herbst,et al.  R 2 Fe 14 B materials: Intrinsic properties and technological aspects , 1991 .

[34]  G. Hadjipanayis,et al.  Anisotropic Sm-(Co,Fe) nanoparticles by surfactant-assisted ball milling , 2009 .

[35]  J. K. Chen,et al.  On the grain‐boundary phase in iron rare‐earth boron magnets , 1987 .

[36]  Y. Tawara,et al.  Cerium, Cobalt and Copper Alloy as a Permanent Magnet Material , 1968 .

[37]  A. Walther,et al.  High performance hard magnetic NdFeB thick films for integration into micro-electro-mechanical systems , 2007, cond-mat/0703785.

[38]  G. Hoffer,et al.  A Family of New Cobalt‐Base Permanent Magnet Materials , 1967 .

[39]  Jian-sheng Wu,et al.  Dependence of the crystal structure of the Nd-rich phase on oxygen content in an Nd–Fe–B sintered magnet , 2008 .

[40]  G. Hadjipanayis,et al.  Fe-nanoparticle coated anisotropic magnet powders for composite permanent magnets with enhanced properties , 2008 .

[41]  Frederick E. Pinkerton,et al.  Pr‐Fe and Nd‐Fe‐based materials: A new class of high‐performance permanent magnets (invited) , 1984 .

[42]  H. Oesterreicher,et al.  Structure and Magnetic Properties of Nd2Fe14BH2.7 , 1984 .

[43]  R. Sherwood,et al.  NEW PERMANENT MAGNET MATERIALS , 1968 .