Sustainable valorization of food wastes into solid fuel by hydrothermal carbonization.

The aim of this study was to comparatively evaluate the effect of hydrothermal carbonization (HTC) conditions on the yield and the fuel properties of hydrochar obtained from food waste (FW) and its digestate (FD). The mass yield of hydrochars from FW and FD were found between 47.0 and 69.8%, 43.0 and 58.2%, respectively, under tested conditions. Based on both mass and energy yields, optimum temperature and duration were selected as 200 °C and 60 min for FW and 200 °C and 30 min for FD. FW and FD hydrochars produced optimum conditions had similar properties to lignite. The selected hydrochars were also subjected to steam gasification and combustion experiments. The combustion reactivity of hydrochars was found to be higher than that of lignite. Steam gasification produced 57-59 mol H2/kg hydrochar. The overall results emphasize the potential of H2 production by integrated systems of dark fermentation, HTC and steam gasification, besides production of solid fuel.

[1]  P. Basu Pyrolysis and Torrefaction , 2010 .

[2]  G. Zeng,et al.  A review of the hydrothermal carbonization of biomass waste for hydrochar formation: Process conditions, fundamentals, and physicochemical properties , 2018, Renewable and Sustainable Energy Reviews.

[3]  Xiaoqian Ma,et al.  Effects of hydrothermal treatment temperature and residence time on characteristics and combustion behaviors of green waste , 2016 .

[4]  J. Yanik,et al.  Influences of feedstock type and process variables on hydrochar properties. , 2018, Bioresource technology.

[5]  J. Kern,et al.  Hydrothermal carbonization of anaerobically digested maize silage. , 2011, Bioresource technology.

[6]  S. Ucar,et al.  Comparative evaluation of dry and wet carbonization of agro industrial wastes for the production of soil improver , 2018 .

[7]  Milan Martinov,et al.  Applicability of biogas digestate as solid fuel , 2010 .

[8]  Haris Nalakath Abubackar,et al.  Effect of percolation frequency on biohydrogen production from fruit and vegetable wastes by dry fermentation , 2019, International Journal of Hydrogen Energy.

[9]  A. B. Fuertes,et al.  Hydrothermal carbonization of biomass as a route for the sequestration of CO2: chemical and structural properties of the carbonized products. , 2011 .

[10]  Wei Hsin Chen,et al.  Wet torrefaction of microalga Chlorella vulgaris ESP-31 with microwave-assisted heating , 2017 .

[11]  J. F. González,et al.  Hydrothermal carbonization as an effective way of densifying the energy content of biomass , 2012 .

[12]  Tugba Keskin Gundogdu,et al.  Sustainable hydrogen production options from food wastes , 2018, International Journal of Hydrogen Energy.

[13]  Jillian L. Goldfarb,et al.  Hydrothermal carbonization of Opuntia ficus-indica cladodes: Role of process parameters on hydrochar properties. , 2018, Bioresource technology.

[14]  A. B. Fuertes,et al.  Chemical and structural properties of carbonaceous products obtained by hydrothermal carbonization of saccharides. , 2009, Chemistry.

[15]  Wei-Hsin Chen,et al.  Investigation on the ignition and burnout temperatures of bamboo and sugarcane bagasse by thermogravimetric analysis. , 2015 .

[16]  Yan Zhang,et al.  Co-gasification Reactivity of Coal and Woody Biomass in High-Temperature Gasification† , 2010 .

[17]  S. Mahajani,et al.  Production and utilization of fuel pellets from biomass: A review , 2018, Fuel Processing Technology.

[18]  Shicheng Zhang,et al.  Investigation on the Physical and Chemical Properties of Hydrochar and Its Derived Pyrolysis Char for Their Potential Application: Influence of Hydrothermal Carbonization Conditions , 2015 .

[19]  Elena Ficara,et al.  New opportunities for agricultural digestate valorization: current situation and perspectives , 2015 .

[20]  M. Mäkelä,et al.  Hydrothermal carbonization of lignocellulosic biomass: Effect of process conditions on hydrochar properties , 2015 .

[21]  Shakirudeen A. Salaudeen,et al.  Hydrothermal Carbonization of Fruit Wastes: A Promising Technique for Generating Hydrochar , 2018, Energies.

[22]  Surjit Singh,et al.  Fate of inorganic material during hydrothermal carbonisation of biomass: Influence of feedstock on combustion behaviour of hydrochar , 2016 .

[23]  A. Funke,et al.  Cascaded production of biogas and hydrochar from wheat straw: Energetic potential and recovery of carbon and plant nutrients , 2013 .

[24]  A. Ebert,et al.  Characterization of hydrochar obtained from hydrothermal carbonization of wheat straw digestate , 2015 .

[25]  S. G. Sahu,et al.  Thermogravimetric assessment of combustion characteristics of blends of a coal with different biomass chars , 2010 .

[26]  Chao He,et al.  Conversion of sewage sludge to clean solid fuel using hydrothermal carbonization: Hydrochar fuel characteristics and combustion behavior , 2013 .

[27]  Xianhua Wang,et al.  Physicochemical, Pyrolytic, and Combustion Characteristics of Hydrochar Obtained by Hydrothermal Carbonization of Biomass , 2016 .

[28]  Shan-Wen Du,et al.  Pretreatment of biomass by torrefaction and carbonization for coal blend used in pulverized coal injection. , 2014, Bioresource technology.

[29]  Xiaoqian Ma,et al.  Hydrothermal carbonization of typical components of municipal solid waste for deriving hydrochars and their combustion behavior. , 2017, Bioresource technology.

[30]  S. Kent Hoekman,et al.  Hydrothermal Carbonization (HTC) of Lignocellulosic Biomass , 2011 .

[31]  Marco Baratieri,et al.  Agro-industrial waste to solid biofuel through hydrothermal carbonization. , 2016, Waste management.

[32]  Bo Xiao,et al.  Hydrogen-rich gas production by steam gasification of char from biomass fast pyrolysis in a fixed-bed reactor: influence of temperature and steam on hydrogen yield and syngas composition. , 2010, Bioresource technology.

[33]  J. Yanik,et al.  Hydrothermal carbonization and torrefaction of grape pomace: a comparative evaluation. , 2014, Bioresource technology.

[34]  Hans-Günter Ramke,et al.  Hydrothermal carbonization of agricultural residues. , 2013, Bioresource technology.

[35]  S. Nishimura,et al.  Carbohydrate analysis by a phenol-sulfuric acid method in microplate format. , 2005, Analytical biochemistry.

[36]  M. Sarrafzadeh,et al.  Activity enhancement of ammonia-oxidizing bacteria and nitrite-oxidizing bacteria in activated sludge process: metabolite reduction and CO2 mitigation intensification process , 2019, Applied Water Science.

[37]  S. Román,et al.  Conversion of tomato-peel waste into solid fuel by hydrothermal carbonization: Influence of the processing variables. , 2016, Waste management.

[38]  S. Channiwala,et al.  A UNIFIED CORRELATION FOR ESTIMATING HHV OF SOLID, LIQUID AND GASEOUS FUELS , 2002 .

[39]  D. Vamvuka,et al.  A comparative reactivity and kinetic study on the combustion of coal–biomass char blends , 2006 .

[40]  M. Reza,et al.  Hydrothermal carbonization: Fate of inorganics , 2013 .

[41]  Yanjun Dai,et al.  Energy performance of an integrated bio-and-thermal hybrid system for lignocellulosic biomass waste treatment. , 2017, Bioresource technology.

[42]  S. Lam,et al.  Fruit waste as feedstock for recovery by pyrolysis technique , 2016 .

[43]  Zhengang Liu,et al.  Gasification characteristics of hydrochar and pyrochar derived from sewage sludge , 2016 .

[44]  X. Bi,et al.  Overview and some issues related to co‐firing biomass and coal , 2008 .