Autonomic Healing of Polymers

Self-healing polymers have experienced rapid technological advancement over the past seven years. They have moved from a conceptual demonstration to practical application in this time frame and have grown from a single design to a generic paradigm for modern materials development. Potential applications of self-healing polymers are quite broad, including microelectronic substrates and encapsulants, polymeric paints and coatings, structural composites, and biomedical devices. In this article, we focus on polymeric systems that heal in an autonomic fashion, that is, automatically and without human intervention. The types of systems under development and the future of this paradigm in advanced materials are discussed.

[1]  Nancy R. Sottos,et al.  Solvent-Promoted Self-Healing Epoxy Materials , 2007 .

[2]  Larry D. Stephenson,et al.  Self-healing coatings for steel , 2006 .

[3]  R. Rosenfeld Nature , 2009, Otolaryngology--head and neck surgery : official journal of American Academy of Otolaryngology-Head and Neck Surgery.

[4]  Anna C Balazs,et al.  Using nanoparticles to create self-healing composites. , 2004, The Journal of chemical physics.

[5]  Scott R White,et al.  A new self-healing epoxy with tungsten (VI) chloride catalyst , 2008, Journal of The Royal Society Interface.

[6]  N. Sottos,et al.  Microcapsule induced toughening in a self-healing polymer composite , 2004 .

[7]  Nancy R. Sottos,et al.  Effect of microcapsule size on the performance of self-healing polymers , 2007 .

[8]  N. Sottos,et al.  Autonomic healing of polymer composites , 2001, Nature.

[9]  Nancy R. Sottos,et al.  Nanocapsules for self-healing materials , 2008 .

[10]  N. Sottos,et al.  Retardation and repair of fatigue cracks in a microcapsule toughened epoxy composite – Part I: Manual infiltration , 2005 .

[11]  C. Tanford Macromolecules , 1994, Nature.

[12]  Nancy R. Sottos,et al.  Polydimethylsiloxane‐Based Self‐Healing Materials , 2006 .

[13]  J. Lewis,et al.  Self-healing materials with microvascular networks. , 2007, Nature materials.

[14]  Scott R White,et al.  Mechanophore-linked addition polymers. , 2007, Journal of the American Chemical Society.

[15]  N. Sottos,et al.  Fracture testing of a self-healing polymer composite , 2002 .

[16]  Scott R White,et al.  Self-healing kinetics and the stereoisomers of dicyclopentadiene , 2007, Journal of The Royal Society Interface.

[17]  Nancy R. Sottos,et al.  Biasing reaction pathways with mechanical force , 2007, Nature.

[18]  N. Sottos,et al.  Wax‐Protected Catalyst Microspheres for Efficient Self‐Healing Materials , 2005 .

[19]  N. Sottos,et al.  Retardation and repair of fatigue cracks in a microcapsule toughened epoxy composite—Part II: In situ self-healing , 2005 .

[20]  Anna C. Balazs,et al.  Entropy-driven segregation of nanoparticles to cracks in multilayered composite polymer structures , 2006 .

[21]  N. Sottos,et al.  Autonomic Healing of Epoxy Vinyl Esters via Ring Opening Metathesis Polymerization , 2008 .

[22]  S. Craig,et al.  A hybrid polymer gel with controlled rates of cross-link rupture and self-repair , 2007, Journal of The Royal Society Interface.

[23]  Jeffrey S. Moore,et al.  Catalyst morphology and dissolution kinetics of self-healing polymers , 2006 .

[24]  Nancy R. Sottos,et al.  A Self‐Healing Poly(Dimethyl Siloxane) Elastomer , 2007 .

[25]  N. Sottos,et al.  Life extension of self-healing polymers with rapidly growing fatigue cracks , 2007, Journal of The Royal Society Interface.