Hydrologic and geochemical modeling of a karstic Mediterranean watershed

The SWAT model was modified to simulate the hydrologic and chemical response of karstic systems and assess the impacts of land use management and climate change of an intensively managed Mediterranean watershed in Crete, Greece. A methodology was developed for the determination of the extended karst area contributing to the spring flow as well as the degree of dilution of nitrates due to permanent karst water volume. The modified SWAT model has been able to capture the temporal variability of both karst flow and surface runoff using high frequency monitoring data collected since 2004 in addition to long term flow time series collected since 1973. The overall hydrologic budget of the karst was estimated and its evaporative losses were calculated to be 28% suggesting a very high rate of karst infiltration. Nitrate chemistry of the karst was simulated by calibrating a dilution factor allowing for the estimation of the total karstic groundwater volume to approximately 500 million m 3 of reserve water. The nitrate simulation results suggested a significant impact of livestock grazing on the karstic groundwater and on surface water quality. Finally, simulation results for a set of climate change scenarios suggested a 17% decrease in precipitation, 8% decrease in ET and 22% decrease in flow in 2030–2050 compared to 2010–2020. A validated tool for integrated water management of karst areas has been developed, providing policy makers an instrument for water management that could tackle the increasing water scarcity in the island.

[1]  Jerald L. Schnoor,et al.  High-frequency monitoring for the identification of hydrological and bio-geochemical processes in a Mediterranean river basin , 2010 .

[2]  John A. Harrison,et al.  Escalating Worldwide use of Urea – A Global Change Contributing to Coastal Eutrophication , 2006 .

[3]  J. Parlange,et al.  Hourly Analyses of Hydrological and Water Quality Simulations Using the ESWAT Model , 2009 .

[4]  Xi Chen,et al.  Modelling hydrological processes influenced by soil, rock and vegetation in a small karst basin of southwest China , 2011 .

[5]  Luc Feyen,et al.  Improving pan-European hydrological simulation of extreme events through statistical bias correction of RCM-driven climate simulations , 2011 .

[6]  Klaus Wyser,et al.  A 140-year simulation of European climate with the new version of the Rossby Centre regional atmospheric climate model (RCA3) , 2005 .

[7]  E. van Meijgaard,et al.  The KNMI regional atmospheric climate model RACMO version 2.1 , 2008 .

[8]  J. Refsgaard Parameterisation, calibration and validation of distributed hydrological models , 1997 .

[9]  Ourania Tzoraki,et al.  A generalized framework for modeling the hydrologic and biogeochemical response of a Mediterranean temporary river basin , 2007 .

[10]  Nikolaos P. Nikolaidis Human impacts on soils: Tipping points and knowledge gaps , 2011 .

[11]  Demetris Koutsoyiannis,et al.  A multicell karstic aquifer model with alternative flow equations , 2006 .

[12]  N. Nikolaidis,et al.  Identification of hydrologic and geochemical pathways using high frequency sampling, REE aqueous sampling and soil characterization at Koiliaris Critical Zone Observatory, Crete , 2011 .

[13]  Luca Bonaventura,et al.  The atmospheric general circulation model ECHAM 5. PART I: Model description , 2003 .

[14]  M. Razack,et al.  Modeling daily discharge responses of a large karstic aquifer using soft computing methods: Artificial neural network and neuro-fuzzy , 2010 .

[15]  Vincent Guinot,et al.  Modelling the behaviour of a karst system catchment using non-linear hysteretic conceptual model , 2011 .

[16]  Stephen R. Workman,et al.  SIMULATION OF DAILY AND MONTHLY STREAM DISCHARGE FROM SMALL WATERSHEDS USING THE SWAT MODEL , 2000 .

[17]  D. Jacob,et al.  The role of water vapour in the atmosphere. A short overview from a climate modeller's point of view , 2001 .

[18]  F. Chapin,et al.  A safe operating space for humanity , 2009, Nature.

[19]  John R. Williams,et al.  LARGE AREA HYDROLOGIC MODELING AND ASSESSMENT PART I: MODEL DEVELOPMENT 1 , 1998 .

[20]  P. Martínez-Santos,et al.  Lumped and distributed approaches to model natural recharge in semiarid karst aquifers , 2010 .

[21]  H. Jourde,et al.  Modelling the hydrologic functions of a karst aquifer under active water management – The Lez spring , 2009 .

[22]  Claire Baffaut,et al.  Modeling Flow and Pollutant Transport in a Karst Watershed with SWAT , 2009 .

[23]  N. Kalogerakis,et al.  Dissolved organic nitrogen as an indicator of livestock impacts on soil biochemical quality , 2011 .

[24]  M. Velde,et al.  Estimating irrigation water requirements in Europe , 2009 .

[25]  M. Déqué,et al.  The ARPEGE/IFS atmosphere model: a contribution to the French community climate modelling , 1994 .

[26]  Clyde L. Munster,et al.  MODELING EFFECTS OF BRUSH MANAGEMENT ON THE RANGELAND WATER BUDGET: EDWARDS PLATEAU, TEXAS 1 , 2005 .

[27]  V. Kapsimalis,et al.  Management of nutrient emissions of Axios River catchment: Their effect in the coastal zone of Thermaikos Gulf, Greece , 2009 .

[28]  George P. Karatzas,et al.  An integrated framework for the hydrologic simulation of a complex geomorphological river basin , 2010 .

[29]  L. Zouhri,et al.  Modelling of groundwater flow in heterogeneous porous media by finite element method , 2012 .

[30]  Michel Bakalowicz,et al.  Modelling of the functioning of karst aquifers with a reservoir model: Application to Fontaine de Vaucluse (South of France) , 2007 .