FT-IR emission/transmission spectroscopy for in situ combustion diagnostics

An infrared emission/transmission (E/T) technique, (a method previously used as an in-situ diagnostic for gases and soot particles using dispersive infrared) has been implemented with a Fourier Transform Infrared Infrared (FT-IR) spectrometer and extended to include measurements on particles, as well as gases (CO2, H2O, ethylene, methane, butane, and acetylene) and soot particles. The method can measure both the concentration and temperature of each of the phases. This paper presents the applications of FT-IR E/T spectroscopy to gases and soot particles in reacting flows. Several examples are presented including a coannular laminar ethylene diffusion flame. The results for soot particle temperature and concentration in this flame are in good agreement with measurements reported by other investigators.

[1]  J. Markham,et al.  Extension of emission-transmission technique to particulate samples using FT-IR , 1986 .

[2]  A. F. Sarofim,et al.  Optical Constants of Soot and Their Application to Heat-Flux Calculations , 1969 .

[3]  P. R. Solomon,et al.  Infrared Analysis of Particulates by FT-IR Emission/Transmission Spectroscopy , 1986 .

[4]  Gregory M. Dobbs,et al.  CARS Temperature Measurements in Sooting, Laminar Diffusion Flames , 1984 .

[5]  H. Semerjian,et al.  Laser tomography for simultaneous concentration and temperature measurement in reacting flows , 1983 .

[6]  Analysis of particle composition, size and temperature by FT-IR emission/transmission spectroscopy , 1986 .

[7]  Robert J. Santoro,et al.  Optical tomography for flow field diagnostics , 1981 .

[8]  A. Coppalle,et al.  Fire flame radiation , 1983 .

[9]  R. H. Tourin Spectroscopic Gas Temperature Measurement; Pyrometry of Hot Gases and Plasmas , 1966 .

[10]  Richard H. Schlosberg,et al.  Chemistry of Coal Conversion , 1985 .

[11]  Peter R. Solomon,et al.  Very rapid coal pyrolysis , 1986 .

[12]  John Kent,et al.  Who do Diffusion flames Emit smoke , 1984 .

[13]  Z. Kam,et al.  Absorption and Scattering of Light by Small Particles , 1998 .

[14]  P. R. Solomon,et al.  5 – ANALYTICAL PYROLYSIS OF COAL USING FT-IR* , 1984 .

[15]  G. N. Ramachandran,et al.  Three-dimensional reconstruction from radiographs and electron micrographs: application of convolutions instead of Fourier transforms. , 1971, Proceedings of the National Academy of Sciences of the United States of America.

[16]  The spectral emittance of pulverized coal and char , 1988 .

[17]  Robert J. Santoro,et al.  Soot particle measurements in diffusion flames , 1983 .

[18]  M. Pinar Mengüç,et al.  Thermal Radiation Heat Transfer , 2020 .

[19]  D. Ottesen,et al.  Fourier transform infrared (FT-IR) measurements in sooting flames , 1982 .

[20]  Robert J. Santoro,et al.  The Transport and Growth of Soot Particles in Laminar Diffusion Flames , 1987 .

[21]  P. R. Solomon,et al.  Applications of Fourier Transform IR Spectroscopy in Fuel Science , 1982 .