Next-generation polymer-electrolyte-membrane fuel cells using titanium foam as gas diffusion layer.

In spite of their high conversion efficiency and no emission of greenhouse gases, polymer electrolyte membrane fuel cells (PEMFCs) suffer from prohibitively high cost and insufficient life-span of their core component system, the membrane electrode assembly (MEA). In this paper, we are proposing Ti foam as a promising alternative electrode material in the MEA. Indeed, it showed a current density of 462 mA cm(-2), being ca. 166% higher than that with the baseline Toray 060 gas diffusion layer (GDL) (278 mA cm(-2)) with 200 ccm oxygen supply at 0.7 V, when used as the anode GDL, because of its unique three-dimensional strut structure promoting highly efficient catalytic reactions. Furthermore, it exhibits superior corrosion resistance with almost no thickness and weight changes in the accelerated corrosion test, as opposed to considerable reductions in the weight and thickness of the conventional GDL. We believe that this paper suggests profound implications in the commercialization of PEMFCs, because the metallic Ti foam provides a longer-term reliability and chemical stability, which can reduce the loss of Pt catalyst and, hence, the cost of PEMFCs.

[1]  T. Ohji,et al.  Pore structure of porous ceramics synthesized from water-based slurry by freeze-dry process , 2001 .

[2]  J. Banhart Manufacture, characterisation and application of cellular metals and metal foams , 2001 .

[3]  Andrew Higier,et al.  Effect of gas diffusion layer compression on PEM fuel cell performance , 2006 .

[4]  Yanghua Tang,et al.  PEM fuel cell open circuit voltage (OCV) in the temperature range of 23 °C to 120 °C , 2006 .

[5]  L. J. Bregoli,et al.  A Reverse-Current Decay Mechanism for Fuel Cells , 2005 .

[6]  Christophe Coutanceau,et al.  Development of materials for mini DMFC working at room temperature for portable applications , 2006 .

[7]  Hansung Kim,et al.  Corrosion resistance and sintering effect of carbon supports in polymer electrolyte membrane fuel cells , 2009 .

[8]  R. Ritchie,et al.  Tough, Bio-Inspired Hybrid Materials , 2008, Science.

[9]  Y. Sung,et al.  Ionic Resistance of a Cathode Catalyst Layer with Various Thicknesses by Electrochemical Impedance Spectroscopy for PEMFC , 2012 .

[10]  N. Djilali,et al.  Effect of compression on liquid water transport and microstructure of PEMFC gas diffusion layers , 2007 .

[11]  G. Shen,et al.  Preparation of Porous NiO-Ce0.8Sm0.2O1.9 Ceramics for Anode-supported Low-temperatureSolid Oxide Fuel Cells , 2010 .

[12]  Changying Zhao Review on thermal transport in high porosity cellular metal foams with open cells , 2012 .

[13]  J. Do,et al.  Thick-film nickel–metal-hydride battery based on porous ceramic substrates , 2003 .

[14]  Sylvain Deville,et al.  Freeze-Casting of Porous Ceramics: A Review of Current Achievements and Issues , 2008, 1710.04201.

[15]  Jenn-Jiang Hwang,et al.  Effect of clamping pressure on the performance of a PEM fuel cell , 2007 .

[16]  S AnnaTampieriSimoneSprioMonica,et al.  Bio-inspired hybrid materials with smart functionalities for regenerative medicine , 2015 .

[17]  Ki Tae Park,et al.  Determination of the pore size distribution of micro porous layer in PEMFC using pore forming agents under various drying conditions , 2010 .

[18]  Haydn N. G. Wadley,et al.  Electrical Conductivity of Open-cell Metal Foams , 2002 .

[19]  Hee-Young Park,et al.  Performance of membrane electrode assemblies using PdPt alloy as anode catalysts in polymer electrolyte membrane fuel cell , 2012 .

[20]  D. Dunand,et al.  Directionally freeze-cast titanium foam with aligned, elongated pores , 2008 .

[21]  Jinhan Cho,et al.  Tribological properties of biocompatible Ti-10W and Ti-7.5TiC-7.5W. , 2014, Journal of the mechanical behavior of biomedical materials.

[22]  M. Donachie Titanium: A Technical Guide , 1988 .

[23]  D. Dunand,et al.  Amorphous Zr-Based Foams with Aligned, Elongated Pores , 2010, Metallurgical and Materials Transactions A.

[24]  L. Carrette,et al.  Fuel cells: principles, types, fuels, and applications. , 2000, Chemphyschem : a European journal of chemical physics and physical chemistry.

[25]  B. Su,et al.  Hierarchically Structured Porous Materials for Energy Conversion and Storage , 2012 .

[26]  K. Ho,et al.  Elucidation of electrochemical properties of electrolyte-impregnated micro-porous ceramic films as f , 2011 .