Tailoring Microporosity in Covalent Organic Frameworks

The microporosity of covalent organic frameworks (COFs) is tailored using a facile synthetic approach that introduces alkyl functionalities into the pore and generates networks with pore diameters between 1-2 nm. The added substituents significantly alter the host-guest properties of the resulting materials.

[1]  H. Amouri,et al.  Supramolecular assemblies based on organometallic quinonoid linkers: a new class of coordination networks. , 2008, Angewandte Chemie.

[2]  P. Budd,et al.  Catalysis by microporous phthalocyanine and porphyrin network polymers , 2008 .

[3]  Omar M Yaghi,et al.  Reticular synthesis of microporous and mesoporous 2D covalent organic frameworks. , 2007, Journal of the American Chemical Society.

[4]  M. Antonietti,et al.  Exploring Polymers of Intrinsic Microporosity – Microporous, Soluble Polyamide and Polyimide , 2007 .

[5]  J. Lavigne,et al.  Defining Self-Assembling Linear Oligo(dioxaborole)s , 2007 .

[6]  Qingrui Zhang,et al.  Improved adsorption of 4-nitrophenol onto a novel hHyper-cross-linked polymer. , 2007, Environmental science & technology.

[7]  M. A. van der Veen,et al.  Selective adsorption and separation of xylene isomers and ethylbenzene with the microporous vanadium(IV) terephthalate MIL-47. , 2007, Angewandte Chemie.

[8]  S. Shen,et al.  Studies progress of preparation, properties and applications of hyper-cross-linked polystyrene networks , 2007 .

[9]  P. Budd,et al.  Microporous Polymers as Potential Hydrogen Storage Materials , 2007 .

[10]  V. Yam,et al.  Self-assembly of one- and two-dimensional coordination polymers with quinonoid backbones featuring coinage metals as nodes , 2007 .

[11]  Michael O'Keeffe,et al.  Designed Synthesis of 3D Covalent Organic Frameworks , 2007, Science.

[12]  P. Budd,et al.  The potential of organic polymer-based hydrogen storage materials. , 2007, Physical chemistry chemical physics : PCCP.

[13]  Neil L. Campbell,et al.  Hydrogen Storage in Microporous Hypercrosslinked Organic Polymer Networks , 2007 .

[14]  S. Kitagawa,et al.  Three-dimensional porous coordination polymer functionalized with amide groups based on tridentate ligand: selective sorption and catalysis. , 2007, Journal of the American Chemical Society.

[15]  William R. Gemmill,et al.  Facile Synthesis of a Highly Crystalline, Covalently Linked Porous Boronate Network , 2006 .

[16]  P. Budd,et al.  Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage. , 2006, Chemical Society reviews.

[17]  Henrietta W. Langmi,et al.  Towards polymer-based hydrogen storage materials: engineering ultramicroporous cavities within polymers of intrinsic microporosity. , 2006, Angewandte Chemie.

[18]  Michael O'Keeffe,et al.  Porous, Crystalline, Covalent Organic Frameworks , 2005, Science.

[19]  Mark D. Smith,et al.  Substituent effects on the structure and supramolecular assembly of bis(dioxaborole)s. , 2005, Chemical communications.

[20]  Omar M Yaghi,et al.  Strategies for hydrogen storage in metal--organic frameworks. , 2005, Angewandte Chemie.

[21]  Y. Kawazoe,et al.  Highly controlled acetylene accommodation in a metal–organic microporous material , 2005, Nature.

[22]  D. Sherrington,et al.  Evaluation of a new hypercrosslinked polymer as a sorbent for solid-phase extraction of polar compounds. , 2005, Journal of chromatography. A.

[23]  P. Budd,et al.  Free volume and intrinsic microporosity in polymers , 2005 .

[24]  Wenbin Lin,et al.  Hybrid organic-inorganic solids for heterogeneous asymmetric catalysis , 2005 .

[25]  G. Goerigk,et al.  Structure and Catalytic Properties of Pt-Modified Hyper-Cross-Linked Polystyrene Exhibiting Hierarchical Porosity , 2004 .

[26]  Lee Brammer,et al.  Developments in inorganic crystal engineering. , 2004, Chemical Society reviews.

[27]  Omar M. Yaghi,et al.  Metal-organic frameworks: a new class of porous materials , 2004 .

[28]  M. Rosseinsky,et al.  Recent developments in metal–organic framework chemistry: design, discovery, permanent porosity and flexibility ☆ , 2004 .

[29]  Susumu Kitagawa,et al.  Functional porous coordination polymers. , 2004, Angewandte Chemie.

[30]  Omar M Yaghi,et al.  Hydrogen sorption in functionalized metal-organic frameworks. , 2004, Journal of the American Chemical Society.

[31]  Neil B. McKeown,et al.  Solution‐Processed, Organophilic Membrane Derived from a Polymer of Intrinsic Microporosity , 2004 .

[32]  C. Su,et al.  Exceptionally stable, hollow tubular metal-organic architectures: synthesis, characterization, and solid-state transformation study. , 2004, Journal of the American Chemical Society.

[33]  Matthew J. Davis,et al.  Self-assembled nanotubes that reversibly bind acetic acid guests. , 2003, Journal of the American Chemical Society.

[34]  Stuart L James,et al.  Metal-organic frameworks. , 2003, Chemical Society reviews.

[35]  Michael O'Keeffe,et al.  Reticular synthesis and the design of new materials , 2003, Nature.

[36]  J. Eckert,et al.  Hydrogen Storage in Microporous Metal-Organic Frameworks , 2003, Science.

[37]  A. Cheetham,et al.  Hydrogen adsorption in nanoporous nickel(II) phosphates. , 2003, Journal of the American Chemical Society.

[38]  V. Davankov,et al.  Hypercrosslinked polymers: basic principle of preparing the new class of polymeric materials , 2002 .

[39]  Qing Min Wang,et al.  Metallo-organic molecular sieve for gas separation and purification , 2002 .

[40]  Howard J Halpern,et al.  General synthesis of persistent trityl radicals for EPR imaging of biological systems. , 2002, The Journal of organic chemistry.

[41]  Gautam R Desiraju,et al.  Hydrogen bridges in crystal engineering: interactions without borders. , 2002, Accounts of chemical research.

[42]  Wenbin Lin,et al.  Crystal engineering of NLO materials based on metal--organic coordination networks. , 2002, Accounts of chemical research.

[43]  Michael O'Keeffe,et al.  Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage , 2002, Science.

[44]  Valérie Cabuil,et al.  Designed Hybrid Organic−Inorganic Nanocomposites from Functional Nanobuilding Blocks , 2001 .

[45]  M. Zaworotko,et al.  From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids. , 2001, Chemical reviews.

[46]  M. Kanatzidis,et al.  Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry , 2000 .

[47]  J. Tour,et al.  Synthesis, flame‐retardancy testing, and preliminary mechanism studies of nonhalogenated aromatic boronic acids: A new class of condensed‐phase polymer flame‐retardant additives for acrylonitrile–butadiene–styrene and polycarbonate , 2000 .

[48]  Mohamed Eddaoudi,et al.  Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties , 2000 .

[49]  Douglas A. Loy,et al.  Tailored Porous Materials , 1999 .

[50]  J. Zubieta,et al.  Organic-Inorganic Hybrid Materials: From "Simple" Coordination Polymers to Organodiamine-Templated Molybdenum Oxides. , 1999, Angewandte Chemie.

[51]  D. Braga,et al.  Crystal Engineering and Organometallic Architecture. , 1998, Chemical reviews.

[52]  P. D. Ellis,et al.  Boron–carbon coupling constants: II—the tetraphenylborate anion , 1974 .

[53]  A. J. Oliver,et al.  FT-NMR investigation of 13C11B coupling , 1973 .

[54]  J. Pople The effect of quadrupole relaxation on nuclear magnetic resonance multiplets , 1958 .