Analytical solution of time periodic electroosmotic flows: analogies to Stokes' second problem.

Analytical solutions of time periodic electroosmotic flows in two-dimensional straight channels are obtained as a function of a nondimensional parameter kappa, which is based on the electric double-layer (EDL) thickness, kinematic viscosity, and frequency of the externally applied electric field. A parametric study as a function of kappa reveals interesting physics, ranging from oscillatory "pluglike" flows to cases analogous to the oscillating flat plate in a semi-infinite flow domain (Stokes' second problem). The latter case differs from the Stokes' second solution within the EDL, since the flow is driven with an oscillatory electric field rather than an oscillating plate. The analogous case of plate oscillating with the Helmholtz-Smoluchowski velocity matches our analytical solution in the bulk flow region. This indicates that the instantaneous Helmholtz-Smoluchowski velocity is the appropriate electroosmotic slip condition even for high-frequency excitations. The velocity profiles for large kappa values show inflection points very near the walls with localized vorticity extrema that are stronger than the Stokes layers. This have the potential to result in low Reynolds number flow instabilities. It is also shown that, unlike the steady pure electroosmotic flows, the bulk flow region of time periodic electroosmotic flows are rotational when the diffusion length scales are comparable to and less than the half channel height.