Sensitive detection of oxygen using a diffused integrating cavity as a gas absorption cell

Abstract In this study, an oxygen monitoring system was demonstrated for sensitive oxygen detection. The system is based on tunable diode laser absorption spectroscopy (TDLAS) and wavelength modulation spectroscopy (WMS). Stable 2nd-harmonic signals of oxygen were detected by measuring the oxygen P9 absorption line at 764.38 nm. In the detection, a cubic diffuse integrating cavity was employed as a gas absorption cell to increase the optical path length and achieve a higher sensitivity. In addition, to perform automatic gas concentration measurements, a data recording and analyzing program based on the National Instruments LabVIEW software platform was developed. An uncertainty of 0.05% and a detection sensitivity of 350 ppmv were obtained using this system.

[1]  J. K. Radhakrishnan,et al.  Validation of wavelength modulation spectroscopy techniques for oxygen concentration measurement , 2014 .

[2]  Yargo Bonetti,et al.  Versatile multipass cell for laser spectroscopic trace gas analysis , 2012 .

[3]  A. Dreizler,et al.  Robust, spatially scanning, open-path TDLAS hygrometer using retro-reflective foils for fast tomographic 2-D water vapor concentration field measurements , 2014 .

[4]  Rudy Peeters,et al.  Cavity enhanced absorption and cavity enhanced magnetic rotation spectroscopy , 1998 .

[5]  R. Tatam,et al.  Optical gas sensing: a review , 2012 .

[7]  Shaohua Wu,et al.  Tunable multi-mode diode laser absorption spectroscopy for methane detection , 2013 .

[8]  A. O’Keefe,et al.  Cavity ring‐down optical spectrometer for absorption measurements using pulsed laser sources , 1988 .

[9]  Markus-Christian Amann,et al.  Laser spectroscopic oxygen sensor using diffuse reflector based optical cell and advanced signal processing , 2010 .

[10]  Herwig Kogelnik,et al.  Off-Axis Paths in Spherical Mirror Interferometers , 1964 .

[11]  John U. White Long Optical Paths of Large Aperture , 1942 .

[12]  Jane Hodgkinson,et al.  Using integrating spheres as absorption cells: path-length distribution and application of Beer's law. , 2009, Applied optics.

[13]  Xin Zhou,et al.  Application of tunable diode laser absorption spectroscopy in the detection of oxygen , 2015, Applied Optics and Photonics China.

[14]  Y. Amao,et al.  Probes and Polymers for Optical Sensing of Oxygen , 2003 .

[15]  Eric L. Brosha,et al.  Dense diffusion barrier limiting current oxygen sensors , 1998 .

[16]  Cheng-Shane Chu,et al.  Portable optical oxygen sensor based on time-resolved fluorescence. , 2014, Applied optics.

[17]  O. Korablev,et al.  TDLAS a laser diode sensor for the in situ monitoring of H2O, CO2 and their isotopes in the Martian atmosphere , 2006 .

[18]  Albert Manninen,et al.  Compact multipass optical cell for laser spectroscopy. , 2013, Optics letters.

[19]  Volker Ebert,et al.  Simultaneous in situ measurement of CO, H2O, and gas temperatures in a full-sized coal-fired power plant by near-infrared diode lasers. , 2003, Applied optics.