We studied the interaction of highly charged ions on metal surfaces leading to the emission of electrons from the projectile and from the target. The target electrons are due to potential emission, kinetic emission, and Auger-electron emission. In our electron spectra two types of target Auger electrons are distinguished. Electrons near 135 and 220 eV are ascribed to Pt {ital N}{sub 45}{ital O1}{ital O23} and {ital N}{sub 45}{ital N67}{ital V} Auger transitions. They are caused by {ital K}-vacancy transfer into the Pt {ital N} shell and are only emitted under bombardment with N{sup 6+} and O{sup 7+}. The other type of electrons near 40 and 60 eV are ascribed to Pt {ital O}{sub 23}{ital VV} and {ital N}{sub 67}{ital VV} Auger transitions. They are due to direct ionization and are emitted under bombardment with each projectile used. According to our analysis, the initial projectile {ital K}-shell vacancy survives the transport to and at least 8{times}10{sup {minus}16} s within the target surface.