Effect of Transition Metal Oxides on Decomposition and Deflagration of Composite Solid Propellant Systems: A Survey

Introduction T metal oxides (TMO) like Fe2O3, CuO, MnO2, CuCr2O4, etc., form a very popular group of catalysts for burning rate modification of composite solid propellants. Although it is well known that these oxides affect the decomposition characteristics of polymers and oxidizers like ammonium perchlorate (AP)' and potassium perchlorate, (KP) the exact mechanism of the effect on solid propellants is by no means clear even today. Much fragmentary literature is available on the effect of these oxides on propellant burning and decomposition, oxidizer burning and decomposition, and sandwich and condensed mixture combustion. It is the purpose of this review to bring the material together so that a comprehensive picture can be drawn of the mechanism of the action of these catalysts. It may be mentioned here that these oxides also catalyze hydrocarbon oxidation reactions by inducing free radical decomposition of hydroperoxides (formed by the contact of oxidizer and hydrocarbon).

[1]  V. I. Gritsan,et al.  On the mechanism of the thermal decomposition of ammonium perchlorate , 1970 .

[2]  H. S. Fry,et al.  THE DECOMPOSITION OF POTASSIUM PERCHLORATE AND ITS CATALYSIS BY FERRIC OXIDE , 1923 .

[3]  C. Burnside.  Correlation of ferric oxide surface area and propellant burning rate , 1975 .

[4]  V. Verneker,et al.  Studies on vacuum pyrolysis of ammonium perchlorate and ammonium perchlorate/polystyrene propellant in the presence of transition metal oxides , 1980 .

[5]  M. R. Udupa.  Thermal decomposition of potassium perchlorate in presence of chromium(III) oxide and nickel(II) chromite(III) , 1975 .

[6]  N. Bakhman,et al.  Catalytic effect of ferrous oxide on burning rate of condensed mixtures , 1974 .

[7]  G. Pearson,et al.  Catalyzed Ignition of Composite Propellent Fuels by Gaseous Oxygen , 1969 .

[8]  Martin Summerfield,et al.  Burning Mechanism of Ammonium Perchlorate Propellants , 1960 .

[9]  P. Jacobs,et al.  Decomposition and combustion of ammonium perchlorate , 1969 .

[10]  A. Hermoni,et al.  The catalytic decomposition of ammonium perchlorate , 1961 .

[11]  M. Markowitz,et al.  The Differential Thermal Analysis of Perchlorates. VII. Catalytic Decompositions of the Alkali Metal Perchlorates by Manganese Dioxide , 1965 .

[12]  F. Solymosi,et al.  Catalysis of solid phase reactions effect of doping of cupric oxide catalyst on the thermal decomposition and explosion of ammonium perchlorate , 1962 .

[13]  F. Solymosi.  Initiation of ammonium perchlorate—Ignition by chromic oxidetitanium dioxide catalysts , 1965 .

[14]  J. Powling,et al.  MEASUREMENT OF THE BURNING SURFACE TEMPERATURES OF PROPELLANT COMPOSITIONS BY INFRARED EMISSION , 1962 .

[15]  R. Friedman,et al.  Further studies of pure ammonium perchlorate deflagration , 1961 .

[16]  G. Pearson.  Composite propellent catalysts: Copper chromate and chromite , 1970 .

[17]  H. Wise,et al.  Solid Propellant Kinetics. I. The Ammonium Perchlorate/Copper Chromite/ Fuel System , 1971 .

[18]  V. Mohan,et al.  Electrical Conduction in Ammonium Perchlorate , 1977 .

[19]  W. Rudloff,et al.  Catalytic effect of metal oxides on thermal decomposition reactions. II. Catalytic effect of metal oxides on the thermal decomposition of potassium chlorate and potassium perchlorate as detected by thermal analysis methods , 1970 .

[20]  C. Pittman.  Location of action of burning-rate catalysts in composite propellantcombustion. , 1969 .

[21]  R. Friedman,et al.  Deflagration of ammonium perchlorate , 1957 .

[22]  V. Verneker,et al.  Mechanistic studies on the pyrolysis and combustion of polystyrene/ammonium perchlorate propellants in the presence of transition metal oxides , 1980 .

[23]  Sunitha.,et al.  Effect of catalyst concentration on burning rate of composite solid propellants , 1977 .

[24]  R. Waesche,et al.  The effects of pressure and additives on the kinetics of decomposition of ammonium perchlorate. , 1967 .

[25]  P. Jacobs,et al.  The thermal decomposition of ammonium perchlorate in the presence of manganese dioxide , 1959 .

[26]  O. Korobeinichev,et al.  Study of high-temperature kinetics and mechanism of thermal decomposition of mixtures of ammonium perchlorate-polymeric binder-catalyst using the time-of-flight mass-spectrometer , 1974 .

[27]  Leo Reich,et al.  Elements of polymer degradation , 1971 .

[28]  L. Bircumshaw,et al.  The thermal decomposition of ammonium perchlorate - І. Introduction, experimental, analysis of gaseous products, and thermal decomposition experiments , 1954, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[29]  F. Solymosi,et al.  Thermal Decomposition of Ammonium Perchlorate in Presence of Zinc Oxide , 1961, Nature.

[30]  R. Friedman,et al.  THE MECHANISM OF DEFLAGRATION OF PURE AMMONIUM PERCHLORATE , 1959 .

[31]  H. Wise,et al.  Thermal decomposition of ammonium perchlorate , 1968 .

[32]  G. Pellett.  Heterogeneous NH4ClO4 decomposition using isothermal and pulsed laser mass spectrometry , 1970 .

[33]  A. G. Keenan,et al.  Kinetics of the low temperature thermal decomposition of ammonium perchlorate and its catalysis by copper ion , 1972 .

[34]  K. Kishore,et al.  Mechanism of catalytic activity of transition metal oxides on solid propellant burning rate , 1978 .

[35]  R. Landel,et al.  Chemistry in space research , 1972 .

[36]  J. Handley,et al.  Behavior of Several Catalysts in the Combustion of Solid Propellant Sandwiches , 1974 .

[37]  T. Boggs,et al.  The combustion of ammonium perchlorate and various inorganic additives , 1975 .

[38]  O. Krylov,et al.  Catalyzed burning rates of ammonium perchlorate and polymethylmethacrylate mixtures , 1974 .

[39]  J. Handley,et al.  Catalytic Effects in the Combustion of AP-HTPB Sandwiches to 3200 PSIA , 1973 .

[40]  E. Petersen,et al.  The Effect of Catalysts on the Deflagration Limits of Ammonium Perchlorate , 1972 .

[41]  F. Solymost,et al.  The thermal stability of ammonium perchlorate-lithium perchlorate mixture. The role of eutectic formation , 1966 .

[42]  M. R. Udupa.  Thermal behaviour of potassium perchlorate and potassium chlorate in presence of chromium(VI) oxide , 1976 .

[43]  K. Kishore,et al.  Action of transition metal oxides on composite solid propellants , 1980 .

[44]  P. Jacobs,et al.  The effect of additives on the thermal decomposition of ammonium perchlorate , 1961 .

[45]  P. Jacobs,et al.  The thermal decomposition and ignition of mixtures of ammonium perchlorate + copper chromite , 1967 .

[46]  A. Burcat,et al.  A Study on the Mechanism of the Thermal Decomposition of Ammonium Perchlorate , 1968 .