Techno-economic assessment of biogas plant upgrading by adsorption of hydrogen sulfide on treated sewage–sludge

Abstract Biogas plant upgrading by adsorption of hydrogen sulfide on treated sewage–sludge was techno-economically assessed. Three different processes were included in the study: the desulfurization of biogas by adsorption, the in-situ regeneration of the adsorbent and its production from sewage-sludge. Biogas plant upgrading was performed for a flow rate of 1000 Nm 3 /h of biogas with a H 2 S concentration of 2000 ppmv and a breakthrough concentration of 200 ppmv, which is the technical limit value for internal combustion engines. The cost due to the steam required for the in-situ regeneration was evaluated in two different scenarios: as a bought external utility and as an in-situ produced utility, installing an electric or a biogas steam boiler. According to the cash flow analysis carried out, all the options require a similar minimum selling price for the upgraded biogas (about 0.27–0.29 €/Nm 3 ), with a cost of the overall desulfurization process between 2.5 and 4.0 c€/Nm 3 .

[1]  Hailong Li,et al.  Investigation of thermal integration between biogas production and upgrading , 2015 .

[2]  Robert J. Farrauto,et al.  Conversion of Residual Biomass into Liquid Transportation Fuel: An Energy Analysis , 2011 .

[3]  M. B. Murillo,et al.  Energetic assessment of air-steam gasification of sewage sludge and of the integration of sewage sludge pyrolysis and air-steam gasification of char , 2014 .

[4]  Electo Eduardo Silva Lora,et al.  Techno-economic analysis of municipal solid waste gasification for electricity generation in Brazil , 2015 .

[5]  Granular Activated Carbons from Agricultural By-products: Process Description and Estimated Cost of Production , 2003 .

[6]  M. Ahmaruzzaman,et al.  Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals. , 2011, Advances in colloid and interface science.

[7]  Qie Sun,et al.  Selection of appropriate biogas upgrading technology-a review of biogas cleaning, upgrading and utilisation , 2015 .

[8]  James Riley Couper,et al.  Process Engineering Economics , 2003 .

[9]  F. J. Gutiérrez Ortiz,et al.  Prediction of fixed-bed breakthrough curves for H2S adsorption from biogas: Importance of axial dispersion for design , 2016 .

[10]  A. Aden,et al.  Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass , 2007 .

[11]  Melissa L. Morris The design of an expert system to aid in the selection of a wood fired boiler system , 2008 .

[12]  P. Ollero,et al.  Biogas desulfurization by adsorption on thermally treated sewage-sludge , 2014 .

[13]  Don W. Green,et al.  Perry's Chemical Engineers' Handbook , 2007 .

[14]  M. Demirbas,et al.  Biowastes-to-biofuels , 2011 .

[15]  Ching-Ping Tseng,et al.  Pilot-scale chemical-biological system for efficient H2S removal from biogas. , 2013, Bioresource technology.

[16]  Andrea Corti,et al.  Comparison of different biological treatment scenarios for the organic fraction of municipal solid waste , 2013, International Journal of Environmental Science and Technology.

[17]  Ching-Ping Tseng,et al.  Elimination of high concentration hydrogen sulfide and biogas purification by chemical-biological process. , 2013, Chemosphere.

[18]  Xavier Gabarrell,et al.  Explorative economic analysis of a novel biogas upgrading technology using carbon mineralization. A case study for Spain. , 2015 .

[19]  P. Ollero,et al.  Modeling and simulation of the adsorption of biogas hydrogen sulfide on treated sewage–sludge , 2014 .

[20]  F. J. G. Ortiz,et al.  High performance regenerative adsorption of hydrogen sulfide from biogas on thermally-treated sewage-sludge , 2016 .

[21]  J. Rintala,et al.  Trace compounds affecting biogas energy utilisation – A review , 2011 .

[22]  Klaus D. Timmerhaus,et al.  Plant design and economics for chemical engineers , 1958 .