Soy Protein Isolate/Genipin-Based Nanoparticles for the Stabilization of Pickering Emulsion to Design Self-Healing Guar Gum-Based Hydrogels.

Nowadays, stretchable self-healing hydrogels designed by biomass-based materials have gathered remarkable attention in numerous frontier fields such as wound healing, health monitoring issues, and electronic skin. In this study, soy protein isolate (SPI), a common plant protein, was cross-linked to nanoparticles (SPI NPs) by Genipin, (Gen) which was attracted from the native Geniposide. Oil-in-water (O/W) Pickering emulsion was formed by SPI NPs wrapping the linseed oil, and further implanted into poly(acrylic acid)/guar gum (PAA/GG)-based self-healing hydrogels by multiple reversible weak interactions. With the addition of Pickering emulsion, the hydrogels have achieved a remarkable self-healing ability (self-healing efficiency could reach 91.6% within 10 h) and mechanical properties (tensile strength of 0.89 MPa and strain of 853.2%). Therefore, these hydrogels with good reliable durability have outstanding application prospects in sustainable materials.

[1]  Baozhong Lü,et al.  Top-Down Production of Sustainable and Scalable Hemicellulose Nanocrystals. , 2022, Biomacromolecules.

[2]  Chun Liu,et al.  Elaboration of Cationic Soluble Soybean Polysaccharides-Epigallocatechin Gallate Nanoparticles with Sustained Antioxidant and Antimicrobial Activities. , 2022, Journal of agricultural and food chemistry.

[3]  F. Cousin,et al.  Edge-On (Cellulose II) and Face-On (Cellulose I) Adsorption of Cellulose Nanocrystals at the Oil–Water Interface: A Combined Entropic and Enthalpic Process , 2022, Biomacromolecules.

[4]  M. Hedenqvist,et al.  Robust Assembly of Cross-Linked Protein Nanofibrils into Hierarchically Structured Microfibers , 2022, ACS nano.

[5]  Yu-hong Feng,et al.  In Situ Characterization and Interfacial Viscoelastic Properties of Pickering Emulsions Stabilized by AIE-Active Modified Alginate and Chitosan Complexes , 2022, ACS Sustainable Chemistry & Engineering.

[6]  Dongzhi Zhang,et al.  Guar Gum/Ethyl Cellulose-Polyvinyl Pyrrolidone Composite-Based Quartz Crystal Microbalance Humidity Sensor for Human Respiration Monitoring. , 2022, ACS applied materials & interfaces.

[7]  Ren Liu,et al.  The preparation of linseed oil loaded graphene/polyaniline microcapsule via emulsion template method for self-healing anticorrosion coatings , 2022, Colloids and Surfaces A: Physicochemical and Engineering Aspects.

[8]  Siqi Huan,et al.  Depletion Effects and Stabilization of Pickering Emulsions Prepared from a Dual Nanocellulose System , 2022, ACS Sustainable Chemistry & Engineering.

[9]  V. Schmitt,et al.  Biosourced Polymeric Emulsifiers for Miniemulsion Copolymerization of Myrcene and Styrene: Toward Biobased Waterborne Latex as Pickering Emulsion Stabilizer. , 2022, Biomacromolecules.

[10]  B. Nannenga,et al.  Protein-Nanoparticle Complex Structure Determination by Cryo-Electron Microscopy. , 2022, ACS Applied Bio Materials.

[11]  Qingwen Wang,et al.  Fully Biobased Soy Protein Adhesives with Integrated High-Strength, Waterproof, Mildew-Resistant, and Flame-Retardant Properties , 2022, ACS Sustainable Chemistry & Engineering.

[12]  Shouke Yan,et al.  Robust and ultra-fast self-healing elastomers with hierarchically anisotropic structures and used for wearable sensors , 2022, Chemical Engineering Journal.

[13]  S. Ou,et al.  Water-In-Oil Pickering Emulsions Stabilized by Microcrystalline Phytosterols in Oil: Fabrication Mechanism and Application as a Salt Release System. , 2022, Journal of agricultural and food chemistry.

[14]  S. Hsu,et al.  Biomimetic Strain-Stiffening in Chitosan Self-Healing Hydrogels. , 2022, ACS applied materials & interfaces.

[15]  N. Vishwakarma,et al.  Freeze-Thaw-Induced Physically Cross-linked Superabsorbent Polyvinyl Alcohol/Soy Protein Isolate Hydrogels for Skin Wound Dressing: In Vitro and In Vivo Characterization. , 2022, ACS applied materials & interfaces.

[16]  S. Eichhorn,et al.  Octylamine-Modified Cellulose Nanocrystal-Enhanced Stabilization of Pickering Emulsions for Self-Healing Composite Coatings , 2022, ACS applied materials & interfaces.

[17]  B. Binks,et al.  Pickering Emulsions Stabilized by Polystyrene Particles Possessing Different Surface Groups , 2022, Langmuir : the ACS journal of surfaces and colloids.

[18]  Xuejun Cui,et al.  Recent advances in polysaccharide-based self-healing hydrogels for biomedical applications. , 2022, Carbohydrate polymers.

[19]  C. Lee,et al.  Creating ultrahigh surface area functional carbon from biomass for high performance supercapacitor and facile removal of emerging pollutants , 2022 .

[20]  Yudong Zheng,et al.  Double-Modified Bacterial Cellulose/Soy Protein Isolate Composites by Laser Hole Forming and Selective Oxidation Used for Urethral Repair. , 2021, Biomacromolecules.

[21]  Lin Zhang,et al.  Wear in-situ self-healing polymer composites incorporated with bifunctional microcapsules , 2021, Composites Part B: Engineering.

[22]  Dayong Yang,et al.  Sustainable Bioplastic Made from Biomass DNA and Ionomers. , 2021, Journal of the American Chemical Society.

[23]  Mahdiyar Shahbazi,et al.  Development of an Antioxidative Pickering Emulsion Gel through Polyphenol-Inspired Free-Radical Grafting of Microcrystalline Cellulose for 3D Food Printing , 2021, Biomacromolecules.

[24]  Md. Farhad Ismail,et al.  Surface characterization of thin-film composite membranes using contact angle technique: Review of quantification strategies and applications. , 2021, Advances in colloid and interface science.

[25]  B. Lin,et al.  Stretchable, rapid self-healing guar gum-poly(acrylic acid) hydrogels as wearable strain sensors for human motion detection based on Janus graphene oxide. , 2021, International journal of biological macromolecules.

[26]  S. Ahmad,et al.  Injectable, Self-Healing, and Biocompatible N,O-Carboxymethyl Chitosan/Multialdehyde Guar Gum Hydrogels for Sustained Anticancer Drug Delivery. , 2021, Biomacromolecules.

[27]  Guangfu Liao,et al.  Bringing Material Concepts into Conventional Biorefineries: Considerations of Sources, Preparations, and Applications of Lignin Nanomaterials , 2021, ACS Sustainable Chemistry & Engineering.

[28]  W. Bi,et al.  Molecular Property-Tailored Soy Protein Extraction Process Using a Deep Eutectic Solvent , 2021, ACS Sustainable Chemistry & Engineering.

[29]  Qijun Ding,et al.  Pickering emulsions stabilized by spherical cellulose nanocrystals. , 2021, Carbohydrate polymers.

[30]  Hongshun Yang,et al.  Characteristics and application of fish oil-in-water pickering emulsions structured with tea water-insoluble proteins/κ-carrageenan complexes , 2021 .

[31]  B. Lin,et al.  Nanocomposite hydrogels enhanced by cellulose nanocrystal-stabilized Pickering emulsions with self-healing performance in subzero environment , 2021, Cellulose.

[32]  I. Hernando,et al.  Protein- and polysaccharide-based particles used for Pickering emulsion stabilisation , 2021 .

[33]  Yuzo Nishizaki,et al.  Molecular Structure of Gardenia Blue Pigments by Reaction of Genipin with Benzylamine and Amino Acids. , 2021, Journal of agricultural and food chemistry.

[34]  S. Shi,et al.  Nacre-Inspired Strong and Multifunctional Soy Protein-Based Nanocomposite Materials for Easy Heat-Dissipative Mobile Phone Shell. , 2021, Nano letters.

[35]  Tianfeng Chen,et al.  Edible CaCO3 nanoparticles stabilized Pickering emulsion as calcium‐fortified formulation , 2021, Journal of Nanobiotechnology.

[36]  D. Mcclements,et al.  Pickering Emulsions via Interfacial Nanoparticle Complexation of Oppositely Charged Nanopolysaccharides. , 2021, ACS applied materials & interfaces.

[37]  M. A. Torlopov,et al.  Pickering emulsions stabilized by partially acetylated cellulose nanocrystals for oral administration: oils effect and in vivo toxicity , 2021, Cellulose.

[38]  Tao Wu,et al.  Preparation and characterization of oleogel-in-water pickering emulsions stabilized by cellulose nanocrystals , 2021 .

[39]  Sang Hyun Lee,et al.  Immobilization of laccase via cross-linked enzyme aggregates prepared using genipin as a natural cross-linker. , 2020, International journal of biological macromolecules.

[40]  Xiaomei Ma,et al.  Biocompatible and self-healing ionic gel skin as shape-adaptable and skin-adhering sensor of human motions , 2020 .

[41]  K. Landfester,et al.  Responsive Colloidosomes with Triple Function for Anticorrosion , 2020, ACS applied materials & interfaces.

[42]  Yuxiang Liu,et al.  Skin-inspired cellulose conductive hydrogels with integrated self-healing, strain, and thermal sensitive performance. , 2020, Carbohydrate polymers.

[43]  H. Xiong,et al.  Double-induced se-enriched peanut protein nanoparticles preparation, characterization and stabilized food-grade pickering emulsions , 2020 .

[44]  Xiaoquan Yang,et al.  Food-Grade Emulsions and Emulsion Gels Prepared by Soy Protein-Pectin Complex Nanoparticles and Glycyrrhizic Acid Nanofibrils. , 2020, Journal of agricultural and food chemistry.

[45]  Xiaojing Li,et al.  The characterization and stability of the soy protein isolate/1-Octacosanol nanocomplex. , 2019, Food chemistry.

[46]  Guanglin Wang,et al.  Surface Engineering of Porous Carbon for Self-Healing Nanocomposite Hydrogels by Mussel-inspired Chemistry and PET-ATRP. , 2019, ACS applied materials & interfaces.

[47]  Lei Tao,et al.  Self-Healing Hydrogel with a Double Dynamic Network Comprising Imine and Borate Ester Linkages , 2019, Chemistry of Materials.

[48]  N. Singha,et al.  Carbohydrate and collagen-based doubly-grafted interpenetrating terpolymer hydrogel via N-H activated in situ allocation of monomer for superadsorption of Pb(II), Hg(II), dyes, vitamin-C, and p-nitrophenol. , 2019, Journal of hazardous materials.

[49]  Jie Zhu,et al.  Fabrication and characterization of pickering emulsions stabilized by octenyl succinic anhydride -modified gliadin nanoparticle , 2019, Food Hydrocolloids.

[50]  Guangzhi Yang,et al.  Encapsulation of linseed oil in graphene oxide shells for preparation of self-healing composite coatings , 2019, Progress in Organic Coatings.

[51]  F. Abbasi,et al.  Synthesis and characterization of high durable linseed oil-urea formaldehyde micro/nanocapsules and their self-healing behaviour in epoxy coating , 2018, Progress in Organic Coatings.

[52]  Amit Kumar,et al.  Guar gum and its composites as potential materials for diverse applications: A review. , 2018, Carbohydrate polymers.

[53]  Qixin Zhou,et al.  Evaluation and failure analysis of linseed oil encapsulated self-healing anticorrosive coating , 2018 .

[54]  A. Kamali,et al.  Chemical crosslinking of biopolymeric scaffolds: Current knowledge and future directions of crosslinked engineered bone scaffolds. , 2018, International journal of biological macromolecules.

[55]  Jufang Wang,et al.  Preparation and characterization of double crosslinked hydrogel films from carboxymethylchitosan and carboxymethylcellulose. , 2014, Carbohydrate polymers.

[56]  Yapeng Fang,et al.  Soy proteins: A review on composition, aggregation and emulsification , 2014 .

[57]  Chuan-he Tang,et al.  Emulsifying properties of soy protein nanoparticles: influence of the protein concentration and/or emulsification process. , 2014, Journal of agricultural and food chemistry.

[58]  Chuan-he Tang,et al.  Soy protein nanoparticle aggregates as pickering stabilizers for oil-in-water emulsions. , 2013, Journal of agricultural and food chemistry.

[59]  Z. Teng,et al.  Nanoparticles synthesized from soy protein: preparation, characterization, and application for nutraceutical encapsulation. , 2012, Journal of agricultural and food chemistry.

[60]  Xiu-li Wang,et al.  Biodegradable soy protein isolate-based materials: a review. , 2011, Biomacromolecules.

[61]  Giuseppe Gigli,et al.  Superhydrophobicity due to the hierarchical scale roughness of PDMS surfaces. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[62]  D. Rousseau,et al.  Kinetic and mechanistic considerations in the gelation of genipin-crosslinked gelatin. , 2006, International journal of biological macromolecules.