Synthesis, Characterisation and Luminescent Properties of Lanthanide-Organic Polymers with Picolinic and Glutaric Acids

Three new lanthanide(III) complexes (Ln = Sm, Tb and Eu) of picolinic and glutaric acid were prepared and characterised. The crystal structure of the complex [Sm(glu)(pic)(H2O)2] (where Hpic and H2glu stand for picolinic and glutaric acid, respectively) was determined by single-crystal X-ray diffraction. All the Ln complexes were characterised by elemental analysis, infrared spectroscopy, X-ray powder diffraction and thermoanalytical measurements. The combined data show that these Ln complexes are isostructural. The effect of both organic ligands on the photoluminescent behaviour of the Sm3+, Eu3+ and Tb3+ complexes is discussed and we anticipate the possibility of controlling the photoluminescence of picolinic-containing lanthanide compounds by systematically varying the length of the bridging ligand. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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