Optimal control strategies for hydrogen production when coupling solid oxide electrolysers with intermittent renewable energies

The penetration of intermittent renewable energies requires the development of energy storage technologies. High temperature electrolysis using solid oxide electrolyser cells (SOECs) as a potential energy storage technology, provides the prospect of a cost-effective and energy efficient route to clean hydrogen production. The development of optimal control strategies when SOEC systems are coupled with intermittent renewable energies is discussed. Hydrogen production is examined in relation to energy consumption. Control strategies considered include maximizing hydrogen production, minimizing SOEC energy consumption and minimizing compressor energy consumption. Optimal control trajectories of the operating variables over a given period of time show feasible control for the chosen situations. Temperature control of the SOEC stack is ensured via constraints on the overall temperature difference across the cell and the local temperature gradient within the SOEC stack, to link materials properties with system performance; these constraints are successfully managed. The relative merits of the optimal control strategies are analyzed.

[1]  C. Adjiman,et al.  The Effects of Operating Conditions on the Performance of a Solid Oxide Steam Electrolyser: A Model‐Based Study , 2010 .

[2]  J. Ivy,et al.  Summary of Electrolytic Hydrogen Production: Milestone Completion Report , 2004 .

[3]  P. Sorensen,et al.  Power Fluctuations From Large Wind Farms , 2007, IEEE Transactions on Power Systems.

[4]  Nigel P. Brandon,et al.  Hydrogen production through steam electrolysis: Model-based dynamic behaviour of a cathode-supported intermediate temperature solid oxide electrolysis cell , 2008 .

[5]  Jiong Shen,et al.  Constrained model predictive control of a solid oxide fuel cell based on genetic optimization , 2011 .

[6]  J. Kilner,et al.  Performance of solid oxide electrolysis cells based on scandia stabilised zirconia , 2009 .

[7]  Nigel P. Brandon,et al.  Anode-supported intermediate-temperature direct internal reforming solid oxide fuel cell. II. Model-based dynamic performance and control , 2005 .

[8]  Stephen J. Skinner,et al.  Solid oxide proton conducting steam electrolysers , 2008 .

[9]  M. Laguna-Bercero Recent advances in high temperature electrolysis using solid oxide fuel cells: A review , 2012 .

[10]  Herb Dobbs,et al.  Performance Evaluation of Solid Oxide Fuel Cell Engines Integrated With Single/Dual-Spool Turbochargers , 2011 .

[11]  Srikanth Gopalan,et al.  A solid oxide membrane electrolyzer for production of hydrogen and syn-gas from steam and hydrocarbo , 2011 .

[12]  Jonathan Deseure,et al.  Modelling of solid oxide steam electrolyser: Impact of the operating conditions on hydrogen production , 2011 .

[13]  Carl M. Stoots,et al.  3D CFD model of a multi-cell high-temperature electrolysis stack , 2007 .

[14]  M. Zahid,et al.  High temperature water electrolysis in solid oxide cells , 2008 .

[15]  S. McIntosh,et al.  On the reversibility of anode supported proton conducting solid oxide cells , 2011 .

[16]  M Manage,et al.  A techno-economic appraisal of hydrogen generation and the case for solid oxide electrolyser cells , 2011 .

[17]  M. Laguna-Bercero,et al.  Micro-spectroscopic study of the degradation of scandia and ceria stabilized zirconia electrolytes i , 2011 .

[18]  Xiongwen Zhang,et al.  Nonlinear model predictive control based on the moving horizon state estimation for the solid oxide fuel cell , 2008 .

[19]  Marco Sorrentino,et al.  Model-based development of low-level control strategies for transient operation of solid oxide fuel cell systems , 2011 .

[20]  Dennis Y.C. Leung,et al.  Mathematical modeling of the coupled transport and electrochemical reactions in solid oxide steam electrolyzer for hydrogen production , 2007 .

[21]  F. Tietz,et al.  Nine Thousand Hours of Operation of a Solid Oxide Cell in Steam Electrolysis Mode , 2011 .

[22]  G. Schiller,et al.  High temperature water electrolysis using metal supported solid oxide electrolyser cells (SOEC) , 2009 .

[23]  R. Sargent,et al.  Solution of a Class of Multistage Dynamic Optimization Problems. 2. Problems with Path Constraints , 1994 .

[24]  N. Brandon,et al.  Hydrogen production through steam electrolysis: Control strategies for a cathode-supported intermediate temperature solid oxide electrolysis cell , 2008 .

[25]  J. O’Brien,et al.  High-temperature electrolysis for large-scale hydrogen and syngas production from nuclear energy: summary of system simulation and economic analyses , 2010 .

[26]  D. Brett,et al.  Performance of solid oxide electrolysis cells based on composite La0.8Sr0.2MnO3−δ – yttria stabilized zirconia and Ba0.5Sr0.5Co0.8Fe0.2O3−δ oxygen electrodes , 2010 .

[27]  Jonathan Deseure,et al.  Simulation of a high temperature electrolyzer , 2010 .

[28]  Connor J. Moyer,et al.  Polarization Characteristics and Chemistry in Reversible Tubular Solid-Oxide Cells Operating on Mixtures of H2, CO, H2O , and CO2 , 2011 .