3-Chloropropane-1,2-diol Fatty Acid Esters in Potato Products

The occurrence of 3-chloropropane-1,2-diol fatty acid esters (bound 3-MCPD) in French fries and potato chips is reported. These products belong to the group of foodstuffs with high amount of 3-MCPD esters. Bound 3-MCPD was determined in all analysed samples in following concentrations: pre-frying French fries 27-64 µg/kg, French fries (final product) 100-258 µg/kg and potato chips 229-1008 µg/kg. Palm oil used for frying potato chips was analysed as well and the bound 3-MCPD levels ranged from 654 to 1920 µg/kg. 3-MCPD esters are formed in these products as a consequence of the processing technique. Especially frying oil represents the main source of these contaminants in frying potato products.

[1]  C. Crews,et al.  Optical isomers of chloropropanediols: Mechanisms of their formation and decomposition in protein hydrolysates , 2018 .

[2]  O. Novotný,et al.  Esters of 3-chloropropane-1,2-diol in foodstuffs , 2018 .

[3]  L. Karsulínová,et al.  Analysis of the lipid fractions of coffee creamers, cream aerosols, and bouillon cubes for their health risk associated constituents , 2018 .

[4]  M. Doležal,et al.  Determination of free and bound 3-chloropropane-1,2-diol by gas chromatography with mass spectrometric detection using deuterated 3-chloropropane-1,2-diol as internal standard , 2018 .

[5]  M. Doležal,et al.  Occurrence of 3-chloropropane-1,2-diol fatty acid esters in infant and baby foods , 2009 .

[6]  C. Hamlet,et al.  Chloropropanols and Chloroesters , 2008 .

[7]  J. Hajšlová,et al.  Occurrence of 3-MCPD fatty acid esters in human breast milk , 2008, Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment.

[8]  G. Williamson,et al.  Esters of 3-chloro-1,2-propanediol (3-MCPD) in vegetable oils: Significance in the formation of 3-MCPD , 2008, Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment.

[9]  M. Doležal,et al.  Fatty acid esters of 3-chloropropane-1,2-diol in edible oils , 2006, Food additives and contaminants.

[10]  C. Crews,et al.  Occurrence of 3-chloro-propane-1,2-diol (3-MCPD) and related compounds in foods: a review , 2002, Food additives and contaminants.

[11]  J. Davídek,et al.  New chlorine-containing organic compounds in protein hydrolysates. , 1980, Journal of agricultural and food chemistry.

[12]  J. Veĺišek Formation of volatile chlorohydrins from glycerol (triacetin, tributyrin) and hydrochloric acid , 1979 .

[13]  R. Kraft,et al.  Halogenlipide. I. Massenspektrometrische Strukturuntersuchung stellungsisomerer Fettsäureester der Halogenpropandiole (Desoxyhalogen-glyceride) , 1979 .