Optical Constants of Water in the 200-nm to 200-microm Wavelength Region.

Extinction coefficients k(lambda) for water at 25 degrees C were determined through a broad spectral region by manually smoothing a point by point graph of k(lambda) vs wavelength lambda that was plotted for data obtained from a review of the scientific literature on the optical constants of water. Absorption bands representing k(lambda) were postulated where data were not available in the vacuum uv and soft x-ray regions. A subtractive Kramers-Kronig analysis of the combined postulated and smoothed portions of the k(lambda) spectrum provided the index of refraction n(lambda) for the spectral region 200 nm </= lambda </= 200 microm.

[1]  M. Querry,et al.  Optical Constants of Water in the Infrared , 1971 .

[2]  Melchor Centeno The Refractive Index of Liquid Water in the Near Infra-Red Spectrum , 1941 .

[3]  J. Barrett,et al.  Ultra-Violet Absorption Spectra of the Molecules H2O, HDO and D2O , 1960, Nature.

[4]  Seraphin A. Sullivan Experimental Study of the Absorption in Distilled Water, Artificial Sea Water, and Heavy Water in the Visible Region of the Spectrum* , 1963 .

[5]  J. Lane,et al.  Dielectric dispersion in pure polar liquids at very high radio-frequencies I. Measurements on water, methyl and ethyl alcohols , 1952, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[6]  Dudley A. Williams,et al.  Far-Infrared Spectrum of Liquid Water* , 1966 .

[7]  J. Saxton Dielectric dispersion in pure polar liquids at very high radio-frequencies II. Relation of experimental results to theory , 1952, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[8]  S. Penner,et al.  The near-infrared absorption of liquid water at temperatures between 27 and 209°C☆ , 1964 .

[9]  D. Hornig,et al.  Vibrational Dynamics in Liquid Water: A New Interpretation of the Infrared Spectrum of the Liquid , 1968 .

[10]  W. E. Holland,et al.  Optical Constants in the Infrared for Aqueous Solutions of NaCl , 1972 .

[11]  E. Arakawa,et al.  Electronic Properties of Liquid Water in the Vacuum Ultraviolet , 1968 .

[12]  M. Querry,et al.  Refractive Index of Water in the Infrared , 1969 .

[13]  Earle K. Plyler,et al.  Infrared Absorption of Liquid Water from 2 to 42 Microns , 1954 .

[14]  R. K. Ahrenkiel,et al.  Modified Kramers–Kronig Analysis of Optical Spectra , 1971 .

[15]  R. Jones,et al.  Errata - The Shapes of Infrared Absorption Bands of Liquids , 1971 .

[16]  J. Curcio,et al.  Near infrared absorption spectrum of liquid water , 1951 .

[17]  W. Price,et al.  Ultra-violet Absorption Spectra of the Molecules H2O, HDO and D2O , 1960, Nature.

[18]  R. Young,et al.  Shapes of infrared absorption bands of liquids , 1971 .

[19]  C. P. Smyth,et al.  Microwave Absorption and Molecular Structure in Liquids. XXV. Measurements of Dielectric Constant and Loss at 3.1‐mm Wavelength by an Interferometric Method , 1959 .

[20]  M. W. Williams,et al.  Optical and Dielectric Properties of Water in the Vacuum Ultraviolet , 1972 .

[21]  W. K. Thompson Infra-red spectroscopic studies of aqueous systems. Part 1.—Molar extinction coefficients of water, deuterium oxide, deuteriumhydrogen oxide, aqueous sodium chloride and carbon disulphide , 1965 .

[22]  J. G. Bayly,et al.  The absorption spectra of liquid phase H2O, HDO and D2O from 0·7 μm to 10 μm , 1963 .

[23]  W. H. Wilson,et al.  Predicted Optical Properties for Clear Natural Water , 1972 .

[24]  G. M. Hale,et al.  Influence of Temperature on the Spectrum of Water , 1972 .

[25]  Dudley A. Williams,et al.  Lambert Absorption Coefficients of Water in the Infrared , 1971 .

[26]  R. Bachrach,et al.  Exciton-Optical Properties of TlBr and TlCl , 1970 .

[27]  A. E. Martin,et al.  Investigations of infra-red spectra (2.5—7.5µ). Absorption of water , 1940, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[28]  J. R. Collins A New Infra-red Absorption Band of Liquid Water at 2.52μ , 1939 .

[29]  William M. Irvine,et al.  Infrared optical properties of water and ice spheres , 1968 .

[30]  M. Halmann,et al.  Temperature Dependence of Absorption of Liquid Water in the Far-Ultraviolet Region , 1966 .

[31]  E. Arakawa,et al.  Optical Measurements of Liquid Water in the Vacuum Ultraviolet , 1969 .

[32]  E. K. Plyler,et al.  Absolute Absorption Coefficients of Liquid Water at 295μ, 47μ, and 61μ , 1965 .

[33]  C. Hodgman Transmission of Ultraviolet Radiation by Water , 1933 .

[34]  H. Gebbie,et al.  Submillimetre Absorption and Dispersion of Liquid Water , 1966, Nature.

[35]  J. Barrett,et al.  The photolysis of liquid water , 1960 .

[36]  J L WEEKS,et al.  Absorption coefficients of liquid water and aqueous solutions in the far ultraviolet. , 1963, Radiation research.

[37]  G. L. Clarke,et al.  Laboratory Analysis of the Selective Absorption of Light by Sea Water , 1939 .