Reliability study of an emerging fire suppression system

Self-contained fire extinguishers are a robust, reliable and minimally invasive means of fire suppression for gloveboxes. Plutonium gloveboxes are known to present harsh environmental conditions for polymer materials, these include radiation damage and chemical exposure, both of which tend to degrade the lifetime of engineered polymer components. The primary component of interest in self-contained fire extinguishers is the nylon 6-6 machined tube that comprises the main body of the system. Thermo-mechanical modeling and characterization of nylon 6-6 for use in plutonium glovebox applications has been carried out. Data has been generated regarding property degradation leading to poor, or reduced, engineering performance of nylon 6-6 components. In this study, nylon 6-6 tensile specimens conforming to the casing of self-contained fire extinguisher systems have been exposed to hydrochloric, nitric, and sulfuric acids. This information was used to predict the performance of a load bearing engineering component comprised of nylon 6-6 and designed to operate in a consistent manner over a specified time period. This study provides a fundamental understanding of the engineering performance of the fire suppression system and the effects of environmental degradation due to acid exposure on engineering performance. Data generated help identify the limitations of self-contained fire extinguishers. No critical areas of concern for plutonium glovebox applications of nylon 6-6 have been identified when considering exposure to mineral acid.

[1]  R. Singh,et al.  Progress in the Area of Degradation and Stabilization of Nylon 66 , 1998 .

[2]  Variation of Burnable Neutron Absorbers in a Heavy Water–Moderated Fuel Lattice: A Potential to Improve CANDU Reactor Operating Margins , 2015 .

[3]  Harry J. Elston What the TSA can teach us about chemical safety , 2014 .

[4]  D. R. Gee,et al.  The effect of ionizing radiation on the thermal properties of linear high polymers: Part 2. Nylon-6 , 1970 .

[5]  High Energy Radiation Effects on the Thermal Properties and Density of Nylon 6 Fibers , 1989 .

[6]  Richard W. Neu,et al.  Mechanical behavior of nylon 66 fibers under monotonic and cyclic loading , 2006 .

[7]  J. Keith Nisbett,et al.  Shigley's Mechanical Engineering Design , 1983 .

[8]  Jun Chen,et al.  Toughened nylon66/nylon6 ternary nanocomposites by elastomers , 2010 .

[9]  L. Nicolais,et al.  Glass transition temperature in nylons , 1976 .

[10]  Michael E. Cournoyer,et al.  Investigation of injury/illness data at a nuclear facility: Part II , 2015 .

[11]  D. Millsap Evaluation of nylon 6,6 in use in Fire Foe® fire suppression systems within plutonium gloveboxes , 2012 .

[12]  Michael E. Cournoyer,et al.  Elements of a Glovebox Glove Integrity Program , 2009 .

[13]  M. Cournoyer,et al.  Physio-chemical degradation of thermally aged hypalon glove samples , 2004 .

[14]  V. T. Bui,et al.  Diffusion of sulfuric acid solutions in Nylon 6,6 monitored by neutron activation analysis , 2005 .

[15]  V. Deniz,et al.  Effects of gamma and electron beam irradiation on the properties of calendered cord fabrics , 2010 .

[16]  Clifford Goodman,et al.  American Society of Mechanical Engineers , 1988 .

[17]  J. A. Donovan,et al.  Creep enhanced adsorbtion of water or aqueous zinc chloride solution increases the creep rate of nylon 6,6 , 2001 .

[18]  V. Deniz,et al.  Effect of gamma irradiation on the properties of tyre cords , 2007 .

[19]  G. George,et al.  The effect of morphology on the environmental degradation of nylon 6 under tensile load , 1990 .

[20]  Anthony G. Atkins,et al.  Mixed mode fracture toughness as a separation parameter when cutting polymers , 2009 .

[21]  H. Taylor,et al.  Oxidative Degradation of Nylon 66 Filaments , 1968 .

[22]  Yiu-Wing Mai,et al.  Mechanical and dynamic mechanical properties of nylon 66/montmorillonite nanocomposites fabricated by melt compounding , 2004 .