Assessment of the weathering effects on cellulose based materials through a multianalytical approach

Paper and papyrus endurance depends on their intrinsic properties that are related to the manufacture processes and to the environmental conditions (temperature, humidity, presence of micro-organisms, etc.). During the time, paper and papyrus undergo unavoidable ageing processes causing mainly the degradation of the cellulose. In the framework of the European Project “PAPERTECH” a multi-analytical approach was selected to carefully study the behaviour, properties, and the quality of different samples of paper with different provenience, before and after artificial ageing. This work was focused to understand and explain the degradation processes occurring in paper during the time. Portable EDXRF, NMR, Raman, FTIR, ATR, mechanical properties, colour measurement and XRD analyses were performed before and after the accelerated weathering. The light and the chemical oxidation were found to cause the most aggressive ageing processes.

[1]  H. Edwards,et al.  Fourier-transform Raman spectroscopic study of a Neolithic waterlogged wood assemblage , 2009, Analytical and bioanalytical chemistry.

[2]  G. Luciano,et al.  Thermal analysis and characterisation of cellulose oxidised with sodium methaperiodate , 2004 .

[3]  Czesława Paluszkiewicz,et al.  FT-IR and FT-Raman study of hydrothermally degradated cellulose , 2001 .

[4]  J. Sugiyama,et al.  Electron diffraction study on the two crystalline phases occurring in native cellulose from an algal cell wall , 1991 .

[5]  J. Havermans Effects of Air Pollutants on the Accelerated Ageing of Cellulose-based Materials , 1995 .

[6]  Stephen J. Eichhorn,et al.  Deformation mechanisms in cellulose fibres, paper and wood , 2001 .

[7]  Howell G. M. Edwards,et al.  Raman spectroscopic database of azo pigments and application to modern art studies , 2000 .

[8]  D Capitani,et al.  Monitoring degradation in paper: non-invasive analysis by unilateral NMR. Part II. , 2004, Journal of magnetic resonance.

[9]  Yongliang Liu Vibrational spectroscopic investigation of Australian cotton cellulose fibres Part 1. A Fourier transform Raman study , 1998 .

[10]  K. Castro,et al.  On-line FT-Raman and dispersive Raman spectra database of artists’ materials (e-VISART database) , 2005, Analytical and bioanalytical chemistry.

[11]  Lennart Salmén,et al.  Characterization of the crystalline structure of cellulose using static and dynamic FT-IR spectroscopy. , 2004, Carbohydrate research.

[12]  Paul Wyeth,et al.  Identification of Cellulosic Fibres by FTIR Spectroscopy - Thread and Single Fibre Analysis by Attenuated Total Reflectance , 2003 .

[13]  M. Missori,et al.  Carbonyl groups development on degraded cellulose. Correlation between spectroscopic and chemical results , 2007 .

[14]  Andrea Gorassini,et al.  FTIR – Deconvolution Spectra of Paper Documents , 2002 .

[15]  S. Vicini,et al.  Influence of the artificial weathering on thermal stability of paper-based materials , 2008 .

[16]  Thomas C. Farrar,et al.  Pulse and Fourier transform NMR , 1971 .

[17]  J. Madariaga,et al.  Vibrational spectroscopy at the service of industrial archaeology: Nineteenth-century wallpaper , 2007 .

[18]  L. Segal',et al.  An Empirical Method for Estimating the Degree of Crystallinity of Native Cellulose Using the X-Ray Diffractometer , 1959 .

[19]  G. Hoatson,et al.  Modelling one‐ and two‐dimensional solid‐state NMR spectra , 2002 .

[20]  Sibel Yildiz,et al.  The effects of thermal modification on crystalline structure of cellulose in soft and hardwood , 2007 .

[21]  A. Potthast,et al.  Studies on oxidative modifications of cellulose in the periodate system: Molecular weight distribution and carbonyl group profiles , 2007 .

[22]  S Sharma,et al.  Degradation of historical paper: nondestructive analysis by the NMR-MOUSE. , 2003, Journal of magnetic resonance.

[23]  C. Langford,et al.  A Modified Cross-Polarization Magic Angle Spinning 13C NMR Procedure for the Study of Humic Materials , 1996 .

[24]  K. Schenzel,et al.  Quantitative analysis of the transformation process of cellulose I → cellulose II using NIR FT Raman spectroscopy and chemometric methods , 2009 .

[25]  Raffaele Lamanna,et al.  On the inversion of multicomponent NMR relaxation and diffusion decays in heterogeneous systems , 2005 .

[26]  R. Atalla,et al.  Native Cellulose: A Composite of Two Distinct Crystalline Forms , 1984, Science.

[27]  R. Sun,et al.  Physico-chemical and thermal characterization of cellulose from barley straw , 2005 .

[28]  M. Carvalho,et al.  Artificial aging processes in modern papers: X-ray spectrometry studies , 2006 .

[29]  Giorgio Luciano,et al.  FTIR and WAXS analysis of periodate oxycellulose : Evidence for a cluster mechanism of oxidation , 2006 .