New laser-based approaches to improve the passivation and rear contact quality in high efficiency crystalline silicon solar cells

Laser processing has been the tool of choice last years to develop improved concepts in contact formation for high efficiency crystalline silicon (c-Si) solar cells. New concepts based on standard laser fired contacts (LFC) or advanced laser doping (LD) techniques are optimal solutions for both the front and back contacts of a number of structures with growing interest in the c-Si PV industry. Nowadays, substantial efforts are underway to optimize these processes in order to be applied industrially in high efficiency concepts. However a critical issue in these devices is that, most of them, demand a very low thermal input during the fabrication sequence and a minimal damage of the structure during the laser irradiation process. Keeping these two objectives in mind, in this work we discuss the possibility of using laser-based processes to contact the rear side of silicon heterojunction (SHJ) solar cells in an approach fully compatible with the low temperature processing associated to these devices. First we discuss the possibility of using standard LFC techniques in the fabrication of SHJ cells on p-type substrates, studying in detail the effect of the laser wavelength on the contact quality. Secondly, we present an alternative strategy bearing in mind that a real challenge in the rear contact formation is to reduce the damage induced by the laser irradiation. This new approach is based on local laser doping techniques previously developed by our groups, to contact the rear side of p-type c-Si solar cells by means of laser processing before rear metallization of dielectric stacks containing Al2O3. In this work we demonstrate the possibility of using this new approach in SHJ cells with a distinct advantage over other standard LFC techniques.

[1]  R. Alcubilla,et al.  Laser processing of Al2O3/a‐SiCx:H stacks: a feasible solution for the rear surface of high‐efficiency p‐type c‐Si solar cells , 2013 .

[2]  Heather Booth,et al.  Laser Processing in Industrial Solar Module Manufacturing , 2010 .

[3]  n-type emitter surface passivation in c-Si solar cells by means of antireflective amorphous silicon carbide layers , 2006 .

[4]  C. Voz,et al.  Parameterization of local laser doping and laser-fired contacts for high efficiency c-Si solar cells , 2012 .

[5]  C. Voz,et al.  p-type c-Si solar cells based on rear side laser processing of Al2O3/SiCx stacks , 2012 .

[6]  Carlos Molpeceres,et al.  Influence of wavelength on laser doping and laser-fired contact processes for c-Si solar cells , 2012, Other Conferences.

[7]  Ralf Preu,et al.  Laser‐fired rear contacts for crystalline silicon solar cells , 2002 .

[8]  C. Ballif,et al.  High-efficiency Silicon Heterojunction Solar Cells: A Review , 2012 .

[9]  M. I. Sánchez-Aniorte,et al.  Optimization of Laser Processes for Local Rear Contacting of Passivated Silicon Solar Cells , 2014 .

[10]  C. Voz,et al.  Laser‐fired contact optimization in c‐Si solar cells , 2012 .

[11]  Stefan W. Glunz,et al.  Investigation of laser‐fired rear‐side recombination properties using an analytical model , 2006 .

[12]  Bernhard Fischer,et al.  Loss analysis of crystalline silicon solar cells using photoconductance and quantum efficiency measurements , 2003 .

[13]  D. Biro,et al.  LFC ON SCREEN PRINTED ALUMINIUM REAR SIDE METALLIZATION , 2009 .

[14]  Paul A. Basore,et al.  Extended spectral analysis of internal quantum efficiency , 1993, Conference Record of the Twenty Third IEEE Photovoltaic Specialists Conference - 1993 (Cat. No.93CH3283-9).