Adding a New Member to the MXene Family: Synthesis, Structure, and Electrocatalytic Activity for the Hydrogen Evolution Reaction of V4C3Tx

Two-dimensional transition-metal-based carbides (or nitrides), so-called MXenes, that can be derived from the three-dimensional MAX phases, have attracted considerable attention throughout the past...

[1]  L. Nyborg,et al.  Stoichiometric vanadium oxides studied by XPS , 2012 .

[2]  C. M. Hamm,et al.  Non-conventional Synthesis of the 413 MAX Phase V4AlC3 , 2016 .

[3]  J. Schuster,et al.  The ternary systems: CrAlC, VAlC, and TiAlC and the behavior of H-phases (M2AlC) , 1980 .

[4]  A. Vojvodić,et al.  Tuning the Basal Plane Functionalization of Two-Dimensional Metal Carbides (MXenes) To Control Hydrogen Evolution Activity , 2017 .

[5]  Jinlan Wang,et al.  Transition Metal‐Promoted V2CO2 (MXenes): A New and Highly Active Catalyst for Hydrogen Evolution Reaction , 2016, Advanced science.

[6]  Andrea R. Gerson,et al.  Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn , 2010 .

[7]  A. Du,et al.  2D MXenes: A New Family of Promising Catalysts for the Hydrogen Evolution Reaction , 2017 .

[8]  Yury Gogotsi,et al.  Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide , 2013, Science.

[9]  V. Presser,et al.  Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2 , 2011, Advanced materials.

[10]  Tatsuya Shinagawa,et al.  Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion , 2015, Scientific Reports.

[11]  Hui Pan.  Ultra-high electrochemical catalytic activity of MXenes , 2016, Scientific Reports.

[12]  K. Thygesen,et al.  Two-Dimensional MXenes as Catalysts for Electrochemical Hydrogen Evolution: A Computational Screening Study , 2017 .

[13]  Yanchun Zhou,et al.  Discovery of carbon-vacancy ordering in Nb4AlC3–x under the guidance of first-principles calculations , 2015, Scientific Reports.

[14]  Michel W. Barsoum,et al.  MAX Phases: Properties of Machinable Ternary Carbides and Nitrides , 2013 .

[15]  Yury Gogotsi,et al.  Amine‐Assisted Delamination of Nb2C MXene for Li‐Ion Energy Storage Devices , 2015, Advanced materials.

[16]  Yury Gogotsi,et al.  25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials , 2014, Advanced materials.

[17]  J. Etzkorn,et al.  V2AlC, V4AlC3-x (x ≈ 0.31), and V12Al3C8: Synthesis, Crystal Growth, Structure, and Superstructure , 2007 .

[18]  Yury Gogotsi,et al.  2D metal carbides and nitrides (MXenes) for energy storage , 2017 .

[19]  Yanchun Zhou,et al.  Crystal Structure of V4AlC3: A New Layered Ternary Carbide , 2008 .

[20]  Yury Gogotsi,et al.  Two-dimensional transition metal carbides. , 2012, ACS nano.

[21]  A. Vojvodić,et al.  Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution , 2016 .