论文信息 - Luminescent dicyanoplatinum(II) complexes as sensors for the optical measurement of oxygen concentrations

Luminescent dicyanoplatinum(II) complexes as sensors for the optical measurement of oxygen concentrations

The emission spectra of [Pt(L)(CN) 2 ] (L=4,7-diphenyl-1,-10-phenanthrolline or 4,4'-di-tert-butyl-2,2'-bipyridine) immobilized in silicone rubber are concentration dependent. At low concentrations of platinum complex a single emission peak is observed. Oxygen quenching of the emission is shown to be a sensitive method for measuring oxygen concentraions in the gas phase. The polymer films containing the platinum complex are very stable, and no photochemical degradation was observed when they were subjected to step changes in the oxygen concentration. The films are not sensitive to alkyl halides such as chloroform and dichloromethane

Kwok-Yin Wong | Kwok‐yin Wong | Weekey Wai-San Lee | Xiang Ming. Li | Xiang Li

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