Optical vibrons in CdSe dots and dispersion relation of the bulk material

We examine the dependence on size distribution of the Raman line shape of optical vibron modes in CdSe dots. A detailed comparison with the theory of electron-hole correlated Raman scattering in spherical quantum dots, which includes LO-confined modes, is carried out. The obtained CdSe vibron frequencies are found to map well on the ab initio calculated LO phonon dispersion relations of wurtzite CdSe along the [001] direction of the Brillouin zone.