Moisture Dependent Softening Behavior of Wood

An improved understanding of material behavior during the manufacture of wood-based composites can increase the efficiency of wood utilization and provide insight into the development of new processes and products that manipulate the viscoelastic nature of wood. One specific area where additional knowledge can be of great benefit is the influence of heat and moisture on the softening behavior of wood. The thermal softening behavior of wood at four moisture levels from 0 to 20% was evaluated using dielectric thermal analysis (DETA). Coincident in situ relaxations attributed to the softening of amorphous wood components in the range of 20 to 200°C were observed and found to exhibit the characteristics of a glass transition. The moisture dependence of this transition was characterized, and differences in the observed T g were detected between juvenile and mature wood. Time-temperature superposition was also shown to be applicable to the wood and water system.

[1]  L. Salmén Viscoelastic properties ofin situ lignin under water-saturated conditions , 1984 .

[2]  M. Wolcott,et al.  Fundamentals of flakeboard manufacture: viscoelastic behavior of the wood component. , 1990 .

[3]  E. L. Back,et al.  Glass transitions of wood components hold implications for molding and pulping processes [Wood and paper materials]. , 1982 .

[4]  J. Ferry Viscoelastic properties of polymers , 1961 .

[5]  Graham Williams,et al.  Anelastic and Dielectric Effects in Polymeric Solids , 1991 .

[6]  W. Cousins Young's modulus of hemicellulose as related to moisture content , 1978, Wood Science and Technology.

[7]  P. Hedvig,et al.  Dielectric spectroscopy of polymers , 1977 .

[8]  M. Wolcott Modeling viscoelastic cellular materials for the pressing of wood composites , 1989 .

[9]  J. Cowie,et al.  Polymers: Chemistry and Physics of Modern Materials , 1973 .

[10]  D. Atack Dynamic mechanical loss properties of wood , 1981 .

[11]  T. Aoki,et al.  Studies on the Thermoplasticization of Wood , 1979 .

[12]  G. M. Irvine,et al.  The glass transitions of lignin and hemicellulose and their measurement by differential thermal analysis , 1984 .

[13]  B. Tobias,et al.  THERMOSET CURE BY DYNAMIC MECHANICAL, DIELECTRIC, AND CALORIMETRIC METHODS , 1992 .

[14]  M. Wolcott,et al.  Fundamental Aspects of Wood Deformation Pertaining To Manufacture of Wood-Based Composites , 1994 .

[15]  D. Goring,et al.  Thermal softening of lignin, hemicellulose and cellulose , 1963 .

[16]  L. Salmén,et al.  Softening Temperature of Moist Wood Measured by Differential Scanning Calorimetry , 1990 .

[17]  J. P. Armstrong,et al.  The effect of specific gravity on several mechanical properties of some world woods , 1984, Wood Science and Technology.

[18]  M. Norimoto,et al.  Influence of Thermal Softening and Degradation on the Radial Compression Behavior of Wet Spruce , 1998 .

[19]  Grigoriy I. Torgovnikov,et al.  Dielectric Properties of Wood and Wood-Based Materials , 1993, Springer Series in Wood Science.

[20]  Warren P. Mason,et al.  Introduction to polymer viscoelasticity , 1972 .

[21]  F. Kamke,et al.  Equilibrium Moisture Content of Wood in High-Temperature Pressurized Environments , 2007 .

[22]  W. Hillis,et al.  The Softening Temperatures of Wood , 1978 .