Preparation of emulsions and particles by membrane emulsification for the food processing industry.

Abstract Emulsions play an important role in the formulation of foods for production of o/w emulsions, e.g., dressings, artificial milks, cream liqueurs, as well as for preparation of some w/o emulsions, e.g. margarines and low fat spreads. Over the last 20 years, there has been a growing interest in a technique for making emulsions known as “membrane emulsification”. This method involves using a low pressure to force the dispersed phase to permeate through a membrane into the continuous phase. The distinguishing feature is that the resulting droplet size is controlled primarily by the choice of the membrane and not by the generation of turbulent droplet break-up. This article provides a review on the membrane emulsification process for the food processing industry: the main characteristics of the membrane emulsification process are summarized; and simple emulsions, multiple emulsions, and encapsulated materials prepared using membrane emulsification are described.

[1]  Erich J. Windhab,et al.  Continuous membrane emulsification by using a membrane system with controlled pore distance , 2006 .

[2]  Matthias Wessling,et al.  Tailoring surface properties for controlling droplet formation at microsieve membranes , 2007 .

[3]  J. Weiss,et al.  Liposomal Nanocapsules in Food Science and Agriculture , 2005, Critical reviews in food science and nutrition.

[4]  Richard A. Williams,et al.  Controlled Production of Emulsions Using a Crossflow Membrane: Part I: Droplet Formation from a Single Pore , 1998 .

[5]  S. Adachi,et al.  Preparation of fine W/O/W emulsion through membrane filtration of coarse W/O/W emulsion and disappearance of the inclusion of outer phase solution , 2004 .

[6]  M. Nagai,et al.  Preparation of W/O (Water‐in‐Oil) Emulsions Using a PTFE (Polytetrafluoroethylene) Membrane—A New Emulsification Device , 2003 .

[7]  Krassimir D. Danov,et al.  Capillary mechanisms in membrane emulsification: oil-in-water emulsions stabilized by Tween 20 and milk proteins , 2002 .

[8]  R. Arshady,et al.  Microcapsules for food. , 1993, Journal of microencapsulation.

[9]  Enrico Drioli,et al.  State of the Art and Recent Progresses in Membrane Contactors , 2005 .

[10]  David Anthony Barrow,et al.  Analysis of droplet size during crossflow membrane emulsification using stationary and vibrating micromachined silicon nitride membranes , 2005 .

[11]  R. Boom,et al.  Preparation of double emulsions by membrane emulsification—a review , 2005 .

[12]  Richard A. Williams,et al.  Controlled Production of Emulsions Using a Crossflow Membrane: Part II: Industrial Scale Manufacture , 1998 .

[13]  G. Trägårdh,et al.  Food emulsions using membrane emulsification: conditions for producing small droplets , 1999 .

[14]  R. Boom,et al.  Influence of dynamic interfacial tension on droplet formation during membrane emulsification. , 2004, Journal of colloid and interface science.

[15]  E. Dickinson,et al.  Food Colloids, Proteins, Lipids and Polysaccharides , 1997 .

[16]  D. Dalgleish Food emulsions—their structures and structure-forming properties , 2006 .

[17]  M. Nagai,et al.  Membrane emulsification a versatile tool for the synthesis of polymeric microspheres , 2000 .

[18]  J. Aguilera,et al.  Aerated food gels: fabrication and potential applications , 2008 .

[19]  K. Kandori,et al.  Preparation of monodispersed W/O emulsions by Shirasu-porous-glass filter emulsification technique , 1991 .

[20]  M. Nagai,et al.  Uniform titanium dioxide (TiO 2) microcapsules prepared by glass membrane emulsification with subsequent solvent evaporation , 2002, Journal of microencapsulation.

[21]  A. Shono,et al.  Microscopic observation of emulsion droplet formation from a polycarbonate membrane , 2002 .

[22]  Goran T. Vladisavljevic,et al.  Preparation and analysis of oil-in-water emulsions with a narrow droplet size distribution using Shirasu-porous-glass (SPG) membranes☆ , 2002 .

[23]  E. Windhab,et al.  Dynamically enhanced membrane foaming , 2007 .

[24]  G. Vladisavljević,et al.  Preparation of water-in-oil emulsions using microporous polypropylene hollow fibers: influence of some operating parameters on droplet size distribution , 2002 .

[25]  T. Emrick,et al.  Sizing nanoparticle-covered droplets by extrusion through track-etch membranes. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[26]  E. Drioli,et al.  Effects of organic solvents on ultrafiltration polyamide membranes for the preparation of oil-in-water emulsions. , 2005, Journal of colloid and interface science.

[27]  M. Nakajima,et al.  Shirasu Porous Glass membrane emulsification: Characterisation of membrane structure by high-resolution X-ray microtomography and microscopic observation of droplet formation in real time , 2007 .

[28]  M. Nakano,et al.  Comparative Study of Two Preparation Methods of w/o/w Emulsions : Stirring and Membrane Emulsification , 1997 .

[29]  Pieter Walstra,et al.  Principles of emulsion formation , 1993 .

[30]  H. Rawel,et al.  Protein-Stabilized Emulsions Prepared by the Micro-Porous Glass Method , 2004 .

[31]  Y. Asano,et al.  Viscosity change in oil/water food emulsions prepared using a membrane emulsification system , 1999 .

[32]  Kan-ich Suzuki,et al.  Preparation of Corn Oil/Water and Water/Corn Oil Emulsions Using PTFE Membranes , 1998 .

[33]  S. Nakao,et al.  Transport mechanism of deformable droplets in microfiltration of emulsions , 2001 .

[34]  Gerald Muschiolik,et al.  Automated image analysis as a control tool for multiple emulsions , 2005 .

[35]  R. V. D. Sman,et al.  Optimization of the membrane and pore design for micro-machined membranes , 2006 .

[36]  M. Tomita,et al.  Preparation of food emulsions using a membrane emulsification system , 1996 .

[37]  H. Fessi,et al.  The membrane emulsification process: a review , 2004 .

[38]  Na Li,et al.  Preparation of oil-in-water emulsions using polyamide 10 kDa hollow fiber membrane , 2003 .

[39]  M. Goto,et al.  Effects of Interfacial Tension and Viscosities of Oil and Water Phases on Monodispersed Droplet Formation Using a Shirasu-porous-glass (SPG) Membrane , 2006 .

[40]  K. Nakanishi,et al.  An Application of Silica‐Based Monolithic Membrane Emulsification Technique for Easy and Efficient Preparation of Uniformly Sized Polymer Particles , 2005 .

[41]  I. Scherze,et al.  Emulsification using micro porous glass (MPG): surface behaviour of milk proteins , 1999 .

[42]  H. Schubert,et al.  Production of O/W Emulsions Containing Astaxanthin by Repeated Premix Membrane Emulsification , 2005 .

[43]  M. A. Augustin,et al.  Microencapsulation of food ingredients , 2001 .

[44]  Helmar Schubert,et al.  Effect of Dynamic Interfacial Tension on the Emulsification Process Using Microporous, Ceramic Membranes☆ , 1998 .

[45]  G. Vladisavljević,et al.  Permeability of hydrophilic and hydrophobic Shirasu-porous-glass (SPG) membranes to pure liquids and its microstructure , 2005 .

[46]  R. V. D. Sman,et al.  Evaluation of microsieve membrane design , 2006 .

[47]  M. Shimizu,et al.  Particle control of emulsion by membrane emulsification and its applications. , 2000, Advanced drug delivery reviews.

[48]  M. Bally,et al.  Production of large unilamellar vesicles by a rapid extrusion procedure: characterization of size distribution, trapped volume and ability to maintain a membrane potential. , 1985, Biochimica et biophysica acta.

[49]  Yuzoh Asano,et al.  Water/Oil Emulsions Prepared by the Membrane Emulsification Method and Their Stability , 1999 .

[50]  M. Hope,et al.  Extrusion technique to generate liposomes of defined size. , 2003, Methods in enzymology.

[51]  K. Kandori,et al.  Preparation of uniform silica hydrogel particles by SPG filter emulsification method , 1992 .

[52]  Mitsutoshi Nakajima,et al.  Production of O/W emulsions using SPG membranes, ceramic α-aluminium oxide membranes, microfluidizer and a silicon microchannel plate - a comparative study , 2004 .

[53]  S. Omi Preparation of monodisperse microspheres using the Shirasu porous glass emulsification technique , 1996 .

[54]  A. Shono,et al.  Visualization and characterization of SPG membrane emulsification , 2002 .

[55]  Jiyong Park,et al.  Microencapsulation of Lactobacillus casei YIT 9018 using a Microporous Glass Membrane Emulsification System , 2003 .

[56]  K. Nakanishi,et al.  Membrane Emulsification Using Sol-Gel Derived Macroporous Silica Glass , 2000 .

[57]  Gerald Muschiolik,et al.  Multiple emulsions for food use , 2007 .

[58]  G. Trägårdh,et al.  Membrane emulsification — a literature review , 2000 .

[59]  A. Bals,et al.  The influence of the pore size, the foaming temperature and the viscosity of the continuous phase on the properties of foams produced by membrane foaming , 2003 .

[60]  J. W. Goodwin,et al.  Production of porous suspension polymer beads with a narrow size distribution using a cross-flow membrane and a continuous tubular reactor , 2001 .

[61]  G. Vladisavljević,et al.  Performance of rotating membrane emulsification for o/w production , 2006 .

[62]  J. Adler-Nissen,et al.  Apparatus for Emulsion Production in Small Scale and Under Controlled Shear Conditions , 2004 .

[63]  M. Decloux,et al.  Recent and Emerging Applications of Membrane Processes in the Food and Dairy Industry , 2001 .

[64]  F. Szoka,et al.  Preparation of liposomes of defined size distribution by extrusion through polycarbonate membranes. , 1979, Biochimica et biophysica acta.

[65]  R. V. D. Sman,et al.  Analysis of droplet formation and interactions during cross-flow membrane emulsification , 2002 .

[66]  Goran T Vladisavljević,et al.  Recent developments in manufacturing emulsions and particulate products using membranes. , 2005, Advances in colloid and interface science.

[67]  K. Kandori,et al.  Formation mechanisms of monodispersed W/O emulsions by SPG filter emulsification method , 1991 .

[68]  Hatem Fessi,et al.  MEMBRANE EMULSIFICATION AND MICROCHANNEL EMULSIFICATION PROCESSES , 2005 .

[69]  Guanghui Ma,et al.  A Comparison of Membrane Emulsification Obtained Using SPG (Shirasu Porous Glass) and PTFE [Poly(Tetrafluoroethylene)] Membranes , 2002 .

[70]  M. Shimizu,et al.  Membrane Emulsification by Microporous Glass , 1992 .

[71]  L. Chu,et al.  Preparation of highly monodisperse W/O emulsions with hydrophobically modified SPG membranes. , 2006, Journal of colloid and interface science.

[72]  A. Bals,et al.  Effect of pre-heating on the foaming properties of whey protein isolate using a membrane foaming apparatus , 2003 .

[73]  Remko M. Boom,et al.  Status of cross-flow membrane emulsification and outlook for industrial application , 2004 .

[74]  M. Nagai,et al.  Preparation and analysis of uniform emulsion droplets using SPG membrane emulsification technique , 2000 .