Development of a highly sensitive humidity sensor based on the capacitive micromachined ultrasonic transducer

Abstract In this paper, we present a highly sensitive capacitive micromachined ultrasonic transducer (CMUT) based resonant gravimetric humidity sensor using graphene oxide as the sensing material. The CMUT transducer with a diameter of 2 mm and an operating frequency of 12 MHz was fabricated by the direct wafer bonding technique. To validate the design, both the laser vibrometer and the vector network analyzer were adopted to characterize the resonant properties of the fabricated device. A graphene oxide thin film was then coated as the water vapor absorbing layer on the resonating membranes of the CMUT. The humidity sensing performance of the CMUT humidity sensor was evaluated through the electrical impedance analysis over a relative humidity (RH) range of 22.5% to 93.6%. Frequency shifts caused by the added mass of the absorbed water molecules was observed in the measurements. The CMUT humidity sensor exhibited a sensitivity of up to 11.5 kHz/%RH in the tested humidity range and showed a good repeatability and a rapid response/recovery. Benefit from the microelectromechanical (MEMS) technology and the water-sensitive graphene oxide, the developed CMUT humidity sensor is expected to be a strong candidate for miniaturized, highly sensitive, and reliable humidity sensors.

[1]  Gwo-Bin Lee,et al.  Humidity Sensors: A Review , 2005 .

[2]  Dongzhi Zhang,et al.  High-performance QCM humidity sensor based on graphene oxide/tin oxide/polyaniline ternary nanocomposite prepared by in-situ oxidative polymerization method , 2018, Sensors and Actuators B: Chemical.

[3]  Yadong Jiang,et al.  Novel highly sensitive QCM humidity sensor with low hysteresis based on graphene oxide (GO)/poly(ethyleneimine) layered film , 2016 .

[4]  Edward Hæggström,et al.  Fabricating capacitive micromachined ultrasonic transducers with wafer-bonding technology , 2003 .

[5]  W. Kern The Evolution of Silicon Wafer Cleaning Technology , 1990 .

[6]  Jie Li,et al.  A Novel CMUT-Based Resonant Biochemical Sensor Using Electrospinning Technology , 2019, IEEE Transactions on Industrial Electronics.

[7]  Jianlin Zhao,et al.  High performance graphene oxide-based humidity sensor integrated on a photonic crystal cavity , 2017, 1701.02499.

[8]  Massimo Pappalardo,et al.  Capacitive micromachined ultrasonic transducer (CMUT) arrays for medical imaging , 2006, Microelectron. J..

[9]  M. Dresselhaus,et al.  Ultrahigh humidity sensitivity of graphene oxide , 2013, Scientific Reports.

[10]  Xiangdong Chen,et al.  Graphene oxide thin film coated quartz crystal microbalance for humidity detection , 2011 .

[11]  Kwan Kyu Park,et al.  Capacitive micromachined ultrasonic transducers for chemical detection in nitrogen , 2007 .

[12]  Omer Oralkan,et al.  Capacitive micromachined ultrasonic transducers for medical imaging and therapy , 2011, Journal of micromechanics and microengineering : structures, devices, and systems.

[13]  J. Xie,et al.  A high performance humidity sensor based on surface acoustic wave and graphene oxide on AlN/Si layered structure , 2018 .

[14]  Marina Cole,et al.  A film bulk acoustic resonator oscillator based humidity sensor with graphene oxide as the sensitive layer , 2017 .

[15]  Kwan Kyu Park,et al.  A Multichannel Oscillator for a Resonant Chemical Sensor System , 2014, IEEE Transactions on Industrial Electronics.

[16]  Hongyu Yu,et al.  Film Bulk Acoustic-Wave Resonator Based Relative Humidity Sensor Using ZnO Films , 2010 .

[17]  Kwan Kyu Park,et al.  Chemical vapor detection using a capacitive micromachined ultrasonic transducer. , 2011, Analytical chemistry.

[18]  Yuanjie Su,et al.  Reduced graphene oxide-polyethylene oxide composite films for humidity sensing via quartz crystal microbalance , 2018 .

[19]  Butrus T. Khuri-Yakub,et al.  Distinguishing chemicals using CMUT chemical sensor array and artificial neural networks , 2014, 2014 IEEE International Ultrasonics Symposium.

[20]  E. Riedo,et al.  Room-temperature metastability of multilayer graphene oxide films. , 2012, Nature materials.

[21]  Mohd Nizar Hamidon,et al.  Humidity Sensors Principle, Mechanism, and Fabrication Technologies: A Comprehensive Review , 2014, Sensors.

[22]  M. Bjorkqvist,et al.  Studies on hysteresis reduction in thermally carbonized porous silicon humidity sensor , 2006, IEEE Sensors Journal.

[23]  L. Greenspan Humidity Fixed Points of Binary Saturated Aqueous Solutions , 1977, Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry.

[24]  A. Manzoli,et al.  Atomic force microscope microcantilevers used as sensors for monitoring humidity , 2014 .

[25]  Butrus T. Khuri-Yakub,et al.  Capacitive Micromachined Ultrasonic Transducers: Theory and Technology , 2003 .

[26]  A. S. Savoia,et al.  A CMUT probe for medical ultrasonography: from microfabrication to system integration , 2012, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[27]  Lu Wang,et al.  Highly sensitive surface acoustic wave (SAW) humidity sensors based on sol–gel SiO2 films: Investigations on the sensing property and mechanism , 2015 .

[28]  Witold Pedrycz,et al.  Variational Inference-Based Automatic Relevance Determination Kernel for Embedded Feature Selection of Noisy Industrial Data , 2019, IEEE Transactions on Industrial Electronics.

[29]  Kwan Kyu Park,et al.  CMUT as a chemical sensor for DMMP detection , 2008, 2008 IEEE International Frequency Control Symposium.

[30]  E. Thomsen,et al.  Combined colorimetric and gravimetric CMUT sensor for detection of benzyl methyl ketone , 2018, Sensors and Actuators B: Chemical.