Core–shell, hollow-structured iridium–nickel nitride nanoparticles for the hydrogen evolution reaction

We synthesized core–shell, hollow-structured iridium–nickel nitride nanoparticles and then evaluated their activity in the hydrogen evolution reaction (HER). Coupling Ni nitrides with the IrNi cores enhances the HER activity of Ir shells to a level comparable to that of Pt/C, while reducing the Ir loading of the catalyst.

[1]  Tanja Neumann,et al.  Elements Of X Ray Diffraction , 2016 .

[2]  A. Frenkel,et al.  Hydrogen-evolution catalysts based on non-noble metal nickel-molybdenum nitride nanosheets. , 2012, Angewandte Chemie.

[3]  Irene J. Hsu,et al.  Atomic layer deposition synthesis of platinum-tungsten carbide core-shell catalysts for the hydrogen evolution reaction. , 2012, Chemical communications.

[4]  W. Marsden I and J , 2012 .

[5]  A. Frenkel,et al.  Carbon-Supported IrNi Core–Shell Nanoparticles: Synthesis, Characterization, and Catalytic Activity , 2011 .

[6]  Jingguang G. Chen,et al.  Low-cost hydrogen-evolution catalysts based on monolayer platinum on tungsten monocarbide substrates. , 2010, Angewandte Chemie.

[7]  Lei Zhang,et al.  Effect of synthetic reducing agents on morphology and ORR activity of carbon-supported nano-Pd–Co alloy electrocatalysts , 2007 .

[8]  D. Akins,et al.  Carbon-supported Pd-Co bimetallic nanoparticles as electrocatalysts for the oxygen reduction reaction , 2007 .

[9]  J. Nørskov,et al.  Hydrogen evolution over bimetallic systems: understanding the trends. , 2006, Chemphyschem : a European journal of chemical physics and physical chemistry.

[10]  K. Sumiyama,et al.  Why do cubic nanoparticles favor a square array? Mechanism of shape-dependent arrangement in nanocube self-assemblies , 2006 .

[11]  Arumugam Manthiram,et al.  Nanostructured Pt-M/C (M = Fe and Co) catalysts prepared by a microemulsion method for oxygen reduction in proton exchange membrane fuel cells , 2005 .

[12]  Hubert A. Gasteiger,et al.  Handbook of fuel cells : fundamentals technology and applications , 2003 .

[13]  Ermete Antolini,et al.  Formation of carbon-supported PtM alloys for low temperature fuel cells: a review , 2003 .

[14]  C. Amatore Frontiers of electrochemistry. , 2003, Chemphyschem : a European journal of chemical physics and physical chemistry.

[15]  Allen J. Bard,et al.  Electrochemical Methods: Fundamentals and Applications , 1980 .