Liquid hydrogen pump performance and durability testing through repeated cryogenic vessel filling to 700 bar

Abstract This paper reports the results of a comprehensive test of liquid hydrogen (LH2) pump performance and durability conducted while cycle testing a prototype thin-lined cryogenic pressure vessel 456 times to 700 bar. This extensive LH2 pump experimental data set provides a wealth of information vital for a complete evaluation of the future potential of this promising technology for ambient temperature and cryo-compressed vessel refueling. The experiment was conducted at Lawrence Livermore National Laboratory (Livermore, CA)'s hydrogen test facility, specifically built for this experiment and including a containment vessel for safe testing of the prototype vessel and a control room for efficient monitoring. Original pump and storage instrumentation was complemented with an electric power analyzer and a boil-off mass flow meter for more complete pump characterization. The results of the experiment confirm most of the expected virtues of the LH2 pump: rapid (3 min) refueling of the 65-liter prototype vessel at high flow rate (1.55 kgH2 per minute on average), unlimited back to back refueling, low electricity consumption (1.1 kWh/kg H2), no measurable degradation, and low maintenance. High cryogenic vessel fill density is another key performance metric that was demonstrated in an earlier publication. These virtues derive from the high density of LH2 enabling pressurization to high density with relatively little energy consumption and high throughput from a small displacement pump. Boil-off losses as high as 27.7% of dispensed hydrogen were measured, at experimental conditions not representative of operation at a hydrogen refueling station. These losses drop to 15.4% for operation that may be representative of a small station (332 kg/day), while we anticipate less than 6% boil-off with the existing pump and Dewar with improved LH2 delivery truck operations and a more favorable arrangement of the LH2 pump relative to the Dewar.

[1]  Amgad Elgowainy,et al.  Hydrogen storage technology options for fuel cell vehicles: Well-to-wheel costs, energy efficiencies , 2011 .

[2]  Francisco Espinosa-Loza,et al.  Safe, long range, inexpensive and rapidly refuelable hydrogen vehicles with cryogenic pressure vessels , 2013 .

[3]  M. J. Moran,et al.  Fundamentals of Engineering Thermodynamics , 2014 .

[4]  F. Elizalde-Blancas,et al.  The potential for avoiding hydrogen release from cryogenic pressure vessels after vacuum insulation failure , 2018 .

[5]  Kevin L. Simmons,et al.  Advancements and Opportunities for On-Board 700 Bar Compressed Hydrogen Tanks in the Progression Towards the Commercialization of Fuel Cell Vehicles , 2017 .

[6]  Rajesh K. Ahluwalia,et al.  Supercritical cryo-compressed hydrogen storage for fuel cell electric buses , 2018 .

[7]  Salvador M. Aceves,et al.  Onboard Storage Alternatives for Hydrogen Vehicles , 1998 .

[8]  H. Roh,et al.  Performance assessment of 700-bar compressed hydrogen storage for light duty fuel cell vehicles , 2017 .

[9]  S. Aceves,et al.  The isentropic expansion energy of compressed and cryogenic hydrogen , 2014 .

[10]  Rajesh K. Ahluwalia,et al.  Technical assessment of compressed hydrogen storage tank systems for automotive applications , 2010 .

[11]  Salvador M. Aceves,et al.  Thermodynamics of Insulated Pressure Vessels for Vehicular Hydrogen Storage , 1997, Advanced Energy Systems.

[12]  O. Kircher,et al.  Validation of Cryo-compressed Hydrogen Storage ( CcH 2 ) – a Probabilistic Approach , 2011 .

[13]  Francisco Espinosa-Loza,et al.  Rapid high density cryogenic pressure vessel filling to 345 bar with a liquid hydrogen pump , 2018, International Journal of Hydrogen Energy.

[14]  S. Aceves,et al.  Modeling of sudden hydrogen expansion from cryogenic pressure vessel failure , 2011 .

[15]  M. McLinden,et al.  NIST Standard Reference Database 23: Reference Fluid Thermodynamic and Transport Properties-REFPROP, Version 8.0 , 2007 .

[16]  Oliver Kircher,et al.  Cryo‐Compressed Hydrogen Storage , 2016 .

[17]  Francisco Espinosa-Loza,et al.  High-density automotive hydrogen storage with cryogenic capable pressure vessels , 2009 .