Superamphiphobic CaLi-based bulk metallic glasses

A superamphiphobic (both superhydrophobic and superoleophobic) CaLi-based bulk metallic glass (BMG) surface was constructed by etching the surface with water and modifying the etched surface with fluoroalkylsilane coating. The modified surface exhibits high corrosion resistance and stable superamphiphobicity with a high static contact angle of more than 150°; these properties could extend the practical applications of BMGs. The superamphiphobicity mechanism of the BMG is discussed. The facile method can be used to form other BMG surfaces with special wettability.

[1]  Xinjian Feng,et al.  Design and Creation of Superwetting/Antiwetting Surfaces , 2006 .

[2]  Lei Jiang,et al.  One‐Step Solution‐Immersion Process for the Fabrication of Stable Bionic Superhydrophobic Surfaces , 2006 .

[3]  Mingwei Chen,et al.  Mechanical Behavior of Metallic Glasses: Microscopic Understanding of Strength and Ductility , 2008 .

[4]  Jin Zhai,et al.  Super-hydrophobic surfaces: From natural to artificial , 2002 .

[5]  Lei Zhai,et al.  Stable Superhydrophobic Coatings from Polyelectrolyte Multilayers , 2004 .

[6]  Roughness effect on the measurement of interface stress , 2000 .

[7]  Lei Jiang,et al.  Bioinspired surfaces with special wettability. , 2005, Accounts of chemical research.

[8]  J. D. Hosson,et al.  Influence of surface roughness on the wetting angle , 1995 .

[9]  Xi Zhang,et al.  Superhydrophobic surfaces: from structural control to functional application , 2008 .

[10]  W. Wang,et al.  Amorphous metallic plastic. , 2005, Physical review letters.

[11]  J. Schroers,et al.  Write and erase mechanisms for bulk metallic glass , 2008 .

[12]  Weihua Wang,et al.  Correlations between elastic moduli and properties in bulk metallic glasses , 2006 .

[13]  Gang Wang,et al.  Super Plastic Bulk Metallic Glasses at Room Temperature , 2007, Science.

[14]  Weihua Wang,et al.  Binary Cu–Zr Bulk Metallic Glasses , 2004 .

[15]  A. Cassie,et al.  Wettability of porous surfaces , 1944 .

[16]  Jin Zhai,et al.  Bioinspired construction of Mg-Li alloys surfaces with stable superhydrophobicity and improved corrosion resistance , 2008 .

[17]  Jan Genzer,et al.  Recent developments in superhydrophobic surfaces and their relevance to marine fouling: a review , 2006, Biofouling.

[18]  Weihua Wang,et al.  Magnetocaloric effect in Gd-based bulk metallic glasses , 2006 .

[19]  D. Quéré,et al.  On water repellency , 2005 .

[20]  Weihua Wang Roles of minor additions in formation and properties of bulk metallic glasses , 2007 .

[21]  H. Erbil,et al.  Transformation of a Simple Plastic into a Superhydrophobic Surface , 2003, Science.

[22]  Michael Newton,et al.  Progess in superhydrophobic surface development. , 2008, Soft matter.

[23]  P. Liaw,et al.  Development and Characterization of Low-Density Ca-Based Bulk Metallic Glasses: An Overview , 2008 .

[24]  W. Barthlott,et al.  Purity of the sacred lotus, or escape from contamination in biological surfaces , 1997, Planta.

[25]  Douglas C. Hofmann,et al.  Designing metallic glass matrix composites with high toughness and tensile ductility , 2008, Nature.

[26]  Zushu Hu,et al.  Wetting behavior of molten In–Sn alloy on bulk amorphous and crystalline Cu40Zr44Al8Ag8 , 2007 .