Synthesis, properties and physical applications of ionanofluids

Ionic liquids have proved to be one of the most impressive classes of fluids, due to their properties and applications to chemistry and engineering. One of the most recent applica‐ tions of complex systems of ionic liquids and nanomaterials are IoNanofluids, from heat transfer to catalysis, solar absorbing panels, lubricants or luminescent materials. These novel materials belong to the class of nanofluids proposed in the last years and are a mixture of ionic liquid and nanomaterial, in the form of nanoparticle dispersion, and have already re‐ sulted in a number of publications in chemical and physical journals.

[1]  K. Leong,et al.  Investigations of thermal conductivity and viscosity of nanofluids , 2008 .

[2]  A. Lewandowski,et al.  Heat capacities of ionic liquids and their heats of solution in molecular liquids , 2005 .

[3]  A. Mohammad.  Green Solvents I: Properties and Applications in Chemistry , 2012 .

[4]  F. R. Norwood,et al.  On Thermal Conductivities , 1968 .

[5]  E. Grulke,et al.  Anomalous thermal conductivity enhancement in nanotube suspensions , 2001 .

[6]  Peter Wasserscheid,et al.  Ionic Liquids in Synthesis , 2002 .

[7]  S. M. Mercer,et al.  CO2-triggered switchable solvents, surfactants, and other materials , 2012 .

[8]  A. Kokorin,et al.  Ionic Liquids: Theory, Properties, New Approaches , 2011 .

[9]  Y. Xuan,et al.  Investigation on Convective Heat Transfer and Flow Features of Nanofluids , 2003 .

[10]  R. Tye,et al.  thermal conductivity , 2019 .

[11]  A. Ahsan.  Two Phase Flow, Phase Change and Numerical Modeling , 2011 .

[12]  Yulong Ding,et al.  Experimental investigation into the pool boiling heat transfer of aqueous based γ-alumina nanofluids , 2005 .

[13]  Robin Smith,et al.  Chemical Process: Design and Integration , 2005 .

[14]  P. Wasserscheid,et al.  Ionic Liquids-New "Solutions" for Transition Metal Catalysis. , 2000, Angewandte Chemie.

[15]  K. Leong,et al.  Enhanced thermal conductivity of TiO2—water based nanofluids , 2005 .

[16]  I. Hemeon,et al.  Manganese dioxide allylic and benzylic oxidation reactions in ionic liquids , 2004 .

[17]  R. P. Swatloski,et al.  Efficient, halide free synthesis of new, low cost ionic liquids: 1,3-dialkylimidazolium salts containing methyl- and ethyl-sulfate anions , 2002 .

[18]  C. Drummond,et al.  Protic ionic liquids: solvents with tunable phase behavior and physicochemical properties. , 2006, The journal of physical chemistry. B.

[19]  M. Draye,et al.  Correlating the structure and composition of ionic liquids with their toxicity on Vibrio fischeri: A systematic study. , 2012, Journal of hazardous materials.

[20]  G. Voth,et al.  IONIC LIQUIDS , 2004 .

[21]  W. Kunz,et al.  Low Toxic Ionic Liquids, Liquid Catanionics, and Ionic Liquid Microemulsions , 2011 .

[22]  D. Macfarlane,et al.  Thermal Degradation of Ionic Liquids at Elevated Temperatures , 2004 .

[23]  Takuzo Aida,et al.  Ionic liquids for soft functional materials with carbon nanotubes. , 2007, Chemistry.

[24]  Seda Keskin,et al.  A review of ionic liquids towards supercritical fluid applications , 2007 .

[25]  J. H. Kim,et al.  Effect of nanoparticles on critical heat flux of water in pool boiling heat transfer , 2003 .

[26]  Takuzo Aida,et al.  Molecular Ordering of Organic Molten Salts Triggered by Single-Walled Carbon Nanotubes , 2003, Science.

[27]  Suojiang Zhang,et al.  Determination of Physical Properties for the Binary System of 1-Ethyl-3-methylimidazolium Tetrafluoroborate + H2O , 2004 .

[28]  C. A. N. Castro,et al.  Accurate Measurement of Physicochemical Properties on Ionic Liquids and Molten Salts , 2012 .

[29]  L. Rebelo,et al.  Ionic liquids: a pathway to environmental acceptability. , 2011, Chemical Society reviews.

[30]  O. Johansen.  Thermal Conductivity of Soils , 1977 .

[31]  J. Troncoso,et al.  Excess properties for binary systems ionic liquid + ethanol : Experimental results and theoretical description using the ERAS model , 2008 .

[32]  O. K. Crosser,et al.  Thermal Conductivity of Heterogeneous Two-Component Systems , 1962 .

[33]  C. A. N. Castro,et al.  Thermophysical properties of ionic liquids: Do we know how to measure them accurately?☆ , 2010 .

[34]  Robin D. Rogers,et al.  Heat capacities of ionic liquids and their applications as thermal fluids , 2003 .

[35]  K. Patil,et al.  One-step in situ synthesis of NHx-adsorbed rhodium nanocrystals at liquid-liquid interfaces for possible electrocatalytic applications. , 2011, Journal of colloid and interface science.

[36]  John S. Wilkes,et al.  Thermochemistry of ionic liquid heat-transfer fluids , 2005 .

[37]  J. Troncoso,et al.  Excess molar properties for binary systems of alkylimidazolium-based ionic liquids + nitromethane. Experimental results and ERAS-model calculations , 2009 .

[38]  H. Steinrück,et al.  Ionic Liquids in Catalysis , 2015, Catalysis Letters.

[39]  J. Magee,et al.  The effect of dissolved water on the viscosities of hydrophobic room-temperature ionic liquids. , 2005, Chemical communications.

[40]  Zhengguo Zhang,et al.  Surfactant-free ionic liquid-based nanofluids with remarkable thermal conductivity enhancement at very low loading of graphene , 2012, Nanoscale Research Letters.

[41]  Chun Yang,et al.  Determination of the effective thermal diffusivity of nanofluids by the double hot-wire technique , 2006 .

[42]  J. Magee,et al.  Density, Viscosity, Speed of Sound, and Electrolytic Conductivity for the Ionic Liquid 1-Hexyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide and Its Mixtures with Water† , 2007 .

[43]  K. Driesen,et al.  Strong luminescence of rare earth compounds in ionic liquids: Luminescent properties of lanthanide(III) iodides in the ionic liquid 1-dodecyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide , 2006 .

[44]  J. L. Legido,et al.  Physical properties of ionic liquids based on 1-alkyl-3-methylimidazolium cation and hexafluorophosphate as anion and temperature dependence , 2007 .

[45]  Kenneth A. Dawson,et al.  The need for in situ characterisation in nanosafety assessment: funded transnational access via the QNano research infrastructure , 2012, Nanotoxicology.

[46]  S. M. Sohel Murshed,et al.  An Experimental Study of Surface Tension-Dependent Pool Boiling Characteristics of Carbon Nanotubes-Nanofluids , 2009 .

[47]  S. M. Sohel Murshed,et al.  Nanofluids as Advanced Coolants , 2012 .

[48]  J. Pacheco,et al.  DEVELOPMENT OF A MOLTEN-SALT THERMOCLINE THERMAL STORAGE SYSTEM FOR PARABOLIC TROUGH PLANTS , 2001 .

[49]  Joan F. Brennecke,et al.  Thermophysical Properties of Imidazolium-Based Ionic Liquids , 2004 .

[50]  I. Marrucho,et al.  High-Pressure Densities and Derived Thermodynamic Properties of Imidazolium-Based Ionic Liquids , 2007 .

[51]  M. Freemantle.  DESIGNER SOLVENTS : IONIC LIQUIDS MAY BOOST CLEAN TECHNOLOGY DEVELOPMENT , 1998 .

[52]  J. Maxwell.  A Treatise on Electricity and Magnetism , 1873, Nature.

[53]  Ichiro Minami,et al.  Effect and mechanism of additives for ionic liquids as new lubricants , 2007 .

[54]  F. Rodrigues,et al.  Studies of ionic liquid solutions by soft X-ray absorption spectroscopy , 2007 .

[55]  P. Suarez,et al.  TWO-PHASE CATALYTIC HYDROGENATION OF OLEFINS BY RU(II) AND CO(II) COMPLEXES DISSOLVED IN 1-N-BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE IONIC LIQUID , 1997 .

[56]  Wenhua Yu,et al.  Review and Comparison of Nanofluid Thermal Conductivity and Heat Transfer Enhancements , 2008 .

[57]  C. A. N. Castro,et al.  Ionanofluids: New Heat Transfer Fluids for Green Processes Development , 2012 .

[58]  Christopher Hardacre,et al.  Catalysis in ionic liquids. , 2007, Chemical reviews.

[59]  H. Ngo,et al.  Thermal properties of imidazolium ionic liquids , 2000 .

[60]  Haisheng Chen,et al.  Forced convective heat transfer of nanofluids , 2007 .

[61]  K. R. Seddon,et al.  Paradigm confirmed: the first use of ionic liquids to dramatically influence the outcome of chemical reactions. , 2004, Organic letters.

[62]  J. Eastman,et al.  Measuring Thermal Conductivity of Fluids Containing Oxide Nanoparticles , 1999 .

[63]  Elisa Langa,et al.  Thermal Properties of Ionic Liquids and IoNanofluids of Imidazolium and Pyrrolidinium Liquids , 2010 .

[64]  C. A. N. Castro,et al.  Importance of Accurate Data on Viscosity and Thermal Conductivity in Molten Salts Applications , 2003 .

[65]  P. Wasserscheid,et al.  1-n-Butyl-3-methylimidazolium ([bmim]) octylsulfate—an even ‘greener’ ionic liquid , 2002 .

[66]  V. Srinivasadesikan,et al.  On the Chemical Stabilities of Ionic Liquids , 2009, Molecules.

[67]  K. Leong,et al.  Thermophysical and electrokinetic properties of nanofluids – A critical review , 2008 .

[68]  Takao Tsukada,et al.  Thermal Conductivities of [bmim][PF6], [hmim][PF6], and [omim][PF6] from 294 to 335 K at Pressures up to 20 MPa , 2007 .

[69]  T. Welton,et al.  Using Kamlet-Taft solvent descriptors to explain the reactivity of anionic nucleophiles in ionic liquids. , 2006, The Journal of organic chemistry.

[70]  J. Aires-de-Sousa,et al.  Synthesis and properties of new functionalized guanidinium based ionic liquids as non-toxic versatile organic materials , 2010 .

[71]  S. M. Sohel Murshed,et al.  Enhanced thermal conductivity and specific heat capacity of carbon nanotubes ionanofluids , 2012 .

[72]  Stephen U. S. Choi.  Enhancing thermal conductivity of fluids with nano-particles , 1995 .

[73]  A. Jess,et al.  New Ionic Liquids Based on Alkylsulfate and Alkyl Oligoether Sulfate Anions :Synthesis and Applications , 2003 .

[74]  S. M. Sohel Murshed,et al.  Forced Convective Heat Transfer of Nanofluids in Minichannels , 2011 .

[75]  Soon-Heung Chang,et al.  Boiling heat transfer performance and phenomena of Al2O 3-water nano-fluids from a plain surface in a pool , 2004 .

[76]  Robin D. Rogers,et al.  Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation , 2001 .

[77]  M. Nunes da Ponte,et al.  A detailed thermodynamic analysis of [C4mim][BF4]+ water as a case study to model ionic liquid aqueous solutions , 2004 .

[78]  R. Prasher,et al.  Thermal conductance of nanofluids: is the controversy over? , 2008 .

[79]  A. Katritzky,et al.  Combustible ionic liquids by design: is laboratory safety another ionic liquid myth? , 2006, Chemical communications.

[80]  José S. Torrecilla,et al.  A quantum-chemical-based guide to analyze/quantify the cytotoxicity of ionic liquids , 2010 .

[81]  C. Gordon.  New developments in catalysis using ionic liquids , 2001 .

[82]  Saeed Zeinali Heris,et al.  Experimental investigation of oxide nanofluids laminar flow convective heat transfer , 2006 .

[83]  Yulong Ding,et al.  Experimental investigation into convective heat transfer of nanofluids at the entrance region under laminar flow conditions , 2004 .

[84]  S. Stolte,et al.  Mixture effects and predictability of combination effects of imidazolium based ionic liquids as well as imidazolium based ionic liquids and cadmium on terrestrial plants (Triticum aestivum) and limnic green algae (Scenedesmus vacuolatus) , 2008 .

[85]  P. Goodrich,et al.  Recyclable copper catalysts based on imidazolium-tagged bis(oxazolines): A marked enhancement in rate and enantioselectivity for Diels-Alder reactions in ionic liquid , 2007 .

[86]  Youquan Deng,et al.  Green and moisture-stable Lewis acidic ionic liquids (choline chloride · xZnCl2) catalyzed protection of carbonyls at room temperature under solvent-free conditions , 2006 .

[87]  J. Torrecilla,et al.  A COSMO-RS based guide to analyze/quantify the polarity of ionic liquids and their mixtures with organic cosolvents. , 2010, Physical Chemistry, Chemical Physics - PCCP.

[88]  C. A. N. Castro,et al.  Influence of Thermophysical Properties of Ionic Liquids in Chemical Process Design , 2009 .

[89]  Huen Lee,et al.  Refractive index and heat capacity of 1-butyl-3-methylimidazolium bromide and 1-butyl-3-methylimidazolium tetrafluoroborate, and vapor pressure of binary systems for 1-butyl-3-methylimidazolium bromide + trifluoroethanol and 1-butyl-3-methylimidazolium tetrafluoroborate + trifluoroethanol , 2004 .

[90]  D. Warheit,et al.  Characterization of nanomaterials for toxicity assessment. , 2009, Wiley interdisciplinary reviews. Nanomedicine and nanobiotechnology.

[91]  D. Armstrong,et al.  Solvent properties of the 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid , 2003, Analytical and bioanalytical chemistry.

[92]  Yulong Ding,et al.  Heat transfer of aqueous suspensions of carbon nanotubes (CNT nanofluids) , 2006 .

[93]  T. Welton,et al.  Solvent strength of ionic liquid/CO2 mixtures , 2004 .