Processing and properties of engineering plastics recycled from waste electrical and electronic equipment (WEEE)

Abstract The characteristics of engineering plastics used in the preparation of electrical and electronic equipment were studied. More specifically, their thermal response was recorded by DSC experiments, the rheological properties were investigated via MFI tests and the mechanical properties were evaluated with tensile tests. The aim was to establish a procedure for recycling the same engineering plastics deriving from waste of electrical and electronic equipment (WEEE), which offers the additional advantage of using the as-received waste stream as a recyclable mixture, i.e. without sorting and classification of its components. The experimental results showed that blends of PC with ABS or ABS/HIPS can be prepared by direct mixing and this, would allow easy handling of the engineering plastics coming from WEEE, i.e. blending without the need of sorting. These mixtures can be easily processed and display acceptable mechanical properties with reasonable cost. Therefore, the processing characteristics and properties of the systems studied in this work could be the key for the design of an interesting approach for handling solid plastic waste from electrical and electronic devices.

[1]  M. Khan,et al.  Rheological and mechanical properties of ABS/PC blends , 2005 .

[2]  Antal Boldizar,et al.  Degradation of ABS during repeated processing and accelerated ageing , 2003 .

[3]  Hangquan Li,et al.  Recycling of polycarbonate by blending with maleic anhydride grafted ABS , 2004 .

[4]  A. Cunha,et al.  Recycling of poly(ethylene terephthalate) as polymer‐polymer composites , 2002 .

[5]  J. Arnold,et al.  Recycling of acrylonitrile–butadiene–styrene and high‐impact polystyrene from waste computer equipment , 2002 .

[6]  R. Greco,et al.  Influence of low molecular weight ABS species on properties of PC/ABS systems , 2000 .

[7]  A. Hiltner,et al.  Phase morphology of injection-moulded polycarbonate/acrylonitrile-butadiene-styrene blends , 1992 .

[8]  D. R. Paul,et al.  Fracture characterization of PC/ABS blends: effect of reactive compatibilization, ABS type and rubber concentration , 1999 .

[9]  T Matsuto,et al.  Material and heavy metal balance in a recycling facility for home electrical appliances. , 2004, Waste management.

[10]  Xiaodong Liu,et al.  Recycling of ABS and ABS/PC blends , 1999 .

[11]  Juan Carlos Cortés López,et al.  Kinetic analysis of thermal degradation of recycled polycarbonate/acrylonitrile–butadiene–styrene mixtures from waste electric and electronic equipment , 2006 .

[12]  A. Albertsson,et al.  Improvements in the Properties of Mechanically Recycled Thermoplastics , 1998, Engineering Plastics.

[13]  Eric Forssberg,et al.  Mechanical recycling of waste electric and electronic equipment: a review. , 2003, Journal of hazardous materials.

[14]  Rosa Yeh,et al.  Detection of degradation of ABS materials via DSC , 2006 .

[15]  Rafael Balart,et al.  Recycling of ABS and PC from electrical and electronic waste. Effect of miscibility and previous degradation on final performance of industrial blends , 2005 .

[16]  Blaine Lilly,et al.  Characterization of virgin and postconsumer blended high‐impact polystyrene resins for injection molding , 2002 .

[17]  Ana Inés Fernández,et al.  A proposal for quantifying the recyclability of materials , 2002 .

[18]  A. Wong Polycarbonate Effects on Selected Mechanical Properties of Polycarbonate/Acrylonitrile-Butadiene-Styrene (PC/ABS) Binary Blending Systems , 2003 .