Synthesis of[W(η5-C5H5)2H(L)] and[W(η5-C5H5)2L2]2+ cations (L = NCMe, NCPh,C4H8O or CNBut). Crystal and molecularstructures of[W(η5-C5H5)2H(C4H8O)][CF3SO3] and[W(η5-C5H5)2(NCMe)2][CF3SO3]2