论文信息 - A New Type of Glycoglycerolipids from Corynebacterium aquaticum

A New Type of Glycoglycerolipids from Corynebacterium aquaticum

A new type of glycoglycerolipids, S361A and S365A, were obtained from Corynebacterium aquaticum strains, S361 and S365, newly isolated from soils, and were identified as (2R)-1-[α-glucopyranosyl-(1α-3)-(6-O-acyl-α-mannopyranosyl)]-3-O-acylglycerol and (2R)- 1-[α-mannopyranosyl-(1α-3)-(6-O-acyl-α-mannopyra- nosyl)]-3-O-acylglycerol, respectively. S365A was identical to a novel glycoglycerolipid recently isolated from some bacteria, but S361A was a new analog having a glucosylmannosyl in place of the dimannosyl group. Our results indicate that this sn-2 lysotype of glyceroglycolipids may be widely distributed in bacteria.

[1] A. Blond,et al. Lutoside: an acyl-1-(acyl-6′-mannobiosyl)-3-glycerol isolated from the sponge-associated bacterium Micrococcus luteus , 1997 .

[2] V. Wray,et al. A new type of glycolipid, 1-[α-mannopyranosyl-(1α-3)-(6-O-acyl-α-mannopyranosyl)]-3-O-acylglycerol, from Arthrobacter atrocyaneus , 1997 .

[3] A. Gamian,et al. Structural studies of the major glycolipid from Saccharopolyspora genus. , 1996, Carbohydrate research.

[4] N. Murakami,et al. Enzymatic transformation of glyceroglycolipids into sn-1 and sn-2 lysoglyceroglycolipids by use of Rhizopus arrhizus lipase , 1994 .

[5] E. Fattorusso,et al. Isolation of five-membered cyclitol glycolipids, crasserides: unique glycerides from the sponge Pseudoceratina crassa , 1993 .

[6] H. Uzawa. Determination of the absolute configuration of a natural glycerol derivative. , 1991 .

[7] T. Yamakawa,et al. Chapter 2 - Glycoglycerolipids , 1985 .

[8] C. Watanabe,et al. Gas-liquid chromatographic resolution of sugar enantiomers as diastereoisomeric methylbenzylaminoalditols , 1983 .

[9] K. Bock,et al. Assignment of anomeric structure to carbohydrates through geminal13C-H coupling constants , 1973 .