Excitation-Rate Determines Product Stoichiometry in Photochemical Ammonia Production by CdS Quantum Dot-Nitrogenase MoFe Protein Complexes

The reduction of dinitrogen (N2) to ammonia (NH3) by nitrogenase MoFe protein is coupled to chemically driven electron transfer by nitrogenase Fe protein, where H2 is an obligatory side product. Di...

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