High Photorefractive Gain in Nematic Liquid Crystals Doped with Electron Donor and Acceptor Molecules

Liquid crystalline composite materials have been prepared that are strongly photorefractive. Nematic liquid crystals were doped with both electron donor and electron acceptor molecules that undergo facile, photoinduced, electron transfer reactions to yield mobile ions. A photorefractive gain ratio of 1.88 was observed. This gain ratio was achieved with low applied electric fields (0.4 kilovolts per centimeter) requiring only a 1.5-volt battery and low light intensities (100 milliwatts per square centimeter) in samples 37 to 88 micrometers thick that showed no loss in gain over a 6-month period.

[1]  G. Wiederrecht,et al.  Femtosecond Transient Grating Studies of Chlorophylls and a Chlorophyll-Based Electron Donor-Acceptor Molecule , 1995 .

[2]  I. Khoo,et al.  Observation of orientational photorefractive effects in nematic liquid crystals. , 1994, Optics letters.

[3]  N. Peyghambarian,et al.  A photorefractive polymer with high optical gain and diffraction efficiency near 100% , 1994, Nature.

[4]  W. E. Moerner,et al.  Polymeric Photorefractive Materials , 1994 .

[5]  W. E. Moerner,et al.  Orientationally enhanced photorefractive effect in polymers , 1994 .

[6]  Lei Zhang,et al.  High-Performance Photorefractive Polymers , 1994, Science.

[7]  Prasad,et al.  Observation of photorefractivity in a fullerene-doped polymer composite. , 1992, Physical review. B, Condensed matter.

[8]  D J Brady,et al.  Real-time holography in azo-dye-doped liquid crystals. , 1992, Optics letters.

[9]  Zhenan Bao,et al.  Synthesis and physical measurements of a photorefractive polymer , 1992 .

[10]  Scott,et al.  Observation of the photorefractive effect in a polymer. , 1991, Physical review letters.

[11]  David D. Nolte,et al.  Resonant photodiffractive effect in semi-insulating multiple quantum wells , 1990 .

[12]  I. Khoo,et al.  Thermal grating-mediated wave mixing and beam amplification in nematic liquid crystal thin films , 1989 .

[13]  J. Feinberg Photorefractive Nonlinear Optics , 1988 .

[14]  D M Lininger,et al.  Optical tracking novelty filter. , 1987, Optics letters.

[15]  S. Roy,et al.  Birefringence and order parameter of some alkyl and alkoxycyanobiphenyl liquid crystals , 1983 .

[16]  J. Feinberg,et al.  Phase-conjugating mirror with continuous-wave gain. , 1980, Optics letters.

[17]  Amnon Yariv,et al.  Real‐time image processing via four‐wave mixing in a photorefractive medium , 1980 .

[18]  M. Wasielewski,et al.  Electrochemical Production of Chlorophyll a and Pheophytin a Excited States , 1980 .

[19]  W. Helfrich,et al.  Erratum: Conduction‐Induced Alignment of Nematic Liquid Crystals: Basic Model and Stability Considerations , 1969 .