Characterization of atmospheric corrosion in Al/Ag lap joints

Lap joints fabricated using Al2024T3/commercially pure Ag sheet couples with nylon fasteners were exposed to standard field tests in a tropical marine atmosphere for a total period of six months. Atmospheric conditions were recorded using a weather monitoring station. Simultaneously, samples were also exposed in a salt spray chamber according to ASTM B117 and GM 9540P standards. Corrosion data was obtained for monthly intervals for both field and laboratory samples. Weight loss, pitting characteristics and the nature of the corrosion products were evaluated. Corrosion mechanisms based on the observed atmospheric corrosion phenomena are proposed.

[1]  M. Faller,et al.  Environmental effects on materials: The effect of the air pollutants SO2, NO2, NO and O3 on the corrosion of copper, zinc and aluminium. A short literature survey and results of laboratory exposures , 1997 .

[2]  N. Palaniswamy,et al.  Kinetics of atmospheric corrosion of mild steel, zinc, galvanized iron and aluminium at 10 exposure stations in India , 2006 .

[3]  Xiang-Rong Yu,et al.  Auger parameters for sulfur-containing compounds using a mixed aluminum-silver excitation source , 1990 .

[4]  Atmospheric corrosion of clad palladium and palladium-silver alloys: film growth and contamination effects☆ , 1982 .

[5]  J. Svensson,et al.  The influence of CO2, AlCl3·6H2O, MgCl2·6H2O, Na2SO4 and NaCl on the atmospheric corrosion of aluminum , 2006 .

[6]  Thomas E. Graedel,et al.  Corrosion Mechanisms for Nickel Exposed to the Atmosphere , 1989 .

[7]  Sebastián Feliu,et al.  The prediction of atmospheric corrosion from meteorological and pollution parameters—I. Annual corrosion , 1993 .

[8]  Sebastián Feliu,et al.  THE PREDICTION OF ATMOSPHERIC CORROSION FROM METEOROLOGICAL AND POLLUTION PARAMETERS--II. LONG-TERM FORECASTS , 1993 .

[9]  G. A. El-Mahdy,et al.  AC impedance study on the atmospheric corrosion of aluminum under periodic wet–dry conditions , 2004 .

[10]  M. Faller,et al.  Environmental Effects on Materials: The Effect of the Air Pollutants SO2, NO2, NO and O3 on the Corrosion of Copper, Zinc and Aluminum. A Short Literature Survey and Results of Laboratory Exposures. , 1997 .

[11]  J. P. Franey,et al.  The corrosion of silver by atmospheric sulfurous gases , 1985 .

[12]  J. Rodriguez,et al.  The effect of environmental and meteorological variables on atmospheric corrosion of carbon steel, copper, zinc and aluminium in a limited geographic zone with different types of environment , 2003 .

[13]  J. Svensson,et al.  The Effect of CO 2 on the NaCl-Induced Atmospheric Corrosion of Aluminum , 2001 .

[14]  Francisco Corvo,et al.  Outdoor and indoor atmospheric corrosion of non-ferrous metals , 2000 .

[15]  R. P. Frankenthal,et al.  Atmospheric Corrosion of Aluminum in the Presence of Ammonium Sulfate Particles , 1996 .

[16]  P. J. Peterson,et al.  The atmospheric sulfidation of silver in a tubular corrosion reactor , 1989 .

[17]  M. Morcillo,et al.  Studies of long-term weathering of aluminium in the atmosphere , 2007 .

[18]  Thomas E. Graedel,et al.  Corrosion Mechanisms for Aluminum Exposed to the Atmosphere , 1989 .

[19]  J. R. Vilche,et al.  A survey of Argentinean atmospheric corrosion: I—Aluminium and zinc samples , 1995 .

[20]  W. Stickle,et al.  Handbook of X-Ray Photoelectron Spectroscopy , 1992 .

[21]  J. Friel Atmospheric Corrosion Products on Al, Zn, and AlZn Metallic Coatings , 1986 .